Galvanic corrosion of aluminium–copper model alloys

Galvanic coupling between different α and θ phase-containing model Al–Cu alloys, deposited by magnetron sputtering, has revealed that the anodic α phase did not suffer corrosion and remained in the passive state in sulphate solution. Conversely, sulphate ions induced pitting of the cathodic θ phase. Pitting susceptibility of the cathode increased when the difference between the copper content of the anode and cathode increased. Similar observations were made for all the galvanic couples; further, the higher the copper content of a phase, then the greater its susceptibility to pitting

Factors affecting rind pitting in the mandarin hybrids "fortune" and "nova". The influence of exogenous growth regulators

The commercialization of the mandarin hybrids "Fortune" and "Nova" is hindered by the development of cold-induced pitting in the fruit rind which may develop either in the orchard or during storage and transport. In the late cropping cultivar "Fortune", the pitting develops on tree during the winter months and affects mainly the exposed fruit from the north-west quadrant of the tree. The induction of symptoms under uniform conditions in the cold-room reveals differences in the susceptibility to chilling injury among the fruits and the fruit sides. The green fruit is not susceptible. Susceptibility develops as pigmentation progresses, and it is higher for the exposed than for the non-exposed (covered by the foliage) fruits. The application of GA3 at colour-break delays pigmentation and retards the development of susceptibility. The waxing of the fruit offers some protection to cold in the cold-room. However, the incidence of pitting is not related to the wax content of the fruit rind and the application of a wax coverage on tree had only a marginal protective effect. No pitting is usually found on tree in the fruit of the early ripening "Nova" cultivar, which is usually harvested before the winter chilling. The pitting develops during cold storage (8-10 C), and is reduced by GA3 application at colour break, an effect related to the delay in rind pigmentation.info:eu-repo/semantics/publishedVersio

Electrochemical noise generation during corrosion of stainless Steel-Type 316 in acid Chloride Environment.

The electrochemical noise generated during the pitting and general corrosion of austenitic stainless steel-Type 3.16 in acid chloride environment was studied under free corrosion potential and at ambient temperature. The electrochemical noise was observed as spontaneous fluctuation of potential. The observed corrosion behaviours as obtained from the results are related to the existing known pitting/general corrosion mechanism(s) of stain1ess steels. The clearest indication of results are given by the spectrum standard deviation (essentially the average noise power) the noise voltage density, and the roll-off slope parameters. All the noise amplitudes generally increase with decreasing frequency and the power spectral density is inversely proportional to some power of the frequency, thus indicating '1 /f' or 'flicker' noise. The SEM micrograph made from the plastic replicas of the surface of specimens, showed the occurrence 9f pitting and severe general corrosion

Geabacter species enhances pit depth on 304L stainless steel in a medium lacking with electron donor

Geobacter sulfurreducens bacteria increased the open circuit potential of 304L stainless steel by around 320 mV in only a few hours after inoculation. This represents a significant increase in the corrosion risk. In contrast, the oxidation of acetate, which is catalysed by well-established biofilms, shifted the pitting potential towards positive values. In acetate-lacking media, pitting occurred with and without bacteria in the same range of potential values, but the presence of bacteria drastically increased the size of pits. AFM showed pits more than 10 times broader and deeper due to the presence of bacteria. In the absence of acetate, the masking effect due to acetate oxidation disappeared and the full corrosive effect of the biofilm was revealed. This also fully explains why pitting was predominantly observed close to surface areas where bacterial settlement was the densest

Geobacter sulfurreducens can protect 304L stainless steel against pitting in conditions of low electron acceptor concentrations

The effect of Geobacter sulfurreducens cells was studied on the electrochemical behaviour of 304L stainless steel, emphasizing the role of the soluble electron acceptor (fumarate). In fumarate-lacking media, the presence of G. sulfurreducens induced free potential ennoblement in a few hours. This ennoblement has already been observed in standard media that contained fumarate. Our previous studies have shown that G. sulfurreducens shifted the pitting potential toward the positive values. The pits induced by the presence of the bacteria were wider and deeper than in the absence of bacteria. Here, in fumarate-lacking media, similar shift in pitting potential was observed, but the repassivation phase was strongly improved. AFM analysis showed that pits were identical with those observed in the absence of bacteria at lower potential. In contrast with all the previous work where G. sulfurreducens enhanced corrosion, here at a low concentration of electron acceptor, the presence of the bacteria protected the steel against pitting

Surface pitting fatigue life of noninvolute, low-contact-ratio gears

Spur gear endurance tests were conducted to investigate the surface pitting fatigue life of noninvolute gears with low numbers of teeth and low contact ratios for use in advanced applications. The results were compared with those for a standard involute design with a low number of teeth. The gear pitch diameter was 8.89 cm (3.50 in.) with 12 teeth on both gear designs. Test conditions were an oil inlet temperature of 320 K (116 F), an oil outlet temperature of 350 K (170 F), a maximum Hertz stress of 1.49 GPa (216 ksi), and a speed of 10 000 rpm. The following results were obtained: the noninvolute gear had a surface pitting fatigue life approximately 1.6 times that of the standard involute gear of a similar design; and the surface pitting fatigue life of the 3.43-pitch AISI 8620 noninvolute gear was approximately equal to the surface pitting fatigue life of an 8-pitch, 28-tooth AISI 9310 gear at the same load but at a considerably higher maximum Hertz stress

Direct observation of pitting corrosion evolutions on carbon steel surfaces at the nano-to-micro- scales.

The Cl--induced corrosion of metals and alloys is of relevance to a wide range of engineered materials, structures, and systems. Because of the challenges in studying pitting corrosion in a quantitative and statistically significant manner, its kinetics remain poorly understood. Herein, by direct, nano- to micro-scale observations using vertical scanning interferometry (VSI), we examine the temporal evolution of pitting corrosion on AISI 1045 carbon steel over large surface areas in Cl--free, and Cl--enriched solutions. Special focus is paid to examine the nucleation and growth of pits, and the associated formation of roughened regions on steel surfaces. By statistical analysis of hundreds of individual pits, three stages of pitting corrosion, namely, induction, propagation, and saturation, are quantitatively distinguished. By quantifying the kinetics of these processes, we contextualize our current understanding of electrochemical corrosion within a framework that considers spatial dynamics and morphology evolutions. In the presence of Cl- ions, corrosion is highly accelerated due to multiple autocatalytic factors including destabilization of protective surface oxide films and preservation of aggressive microenvironments within the pits, both of which promote continued pit nucleation and growth. These findings offer new insights into predicting and modeling steel corrosion processes in mid-pH aqueous environments

Pitting Corrosion Susceptibility of Super Austenitic Stainless Steels in Sea Water

Pitting corrosion susceptibility of some super austenitic stainless steel tubes exposed to flowing sea water in a specially designed test rig was investigated by field tests and laboratory analyses. The middle part of the steel tubes was put under elevated temperature in the steam chamber part of the rig. The tubes brought to the laboratory were examined with the Wild M3C Model optical macro/microscope after splitting and cleaning. The scanning electron microscopy, (S.E.M.) was used to examine and analyse the observed microscopic pits and microbiological. organisms. EDAX (Energy Dispersive X-ray spectrometer; and the X-ray Diffraction spectroscopy (XRD) analyses were performed on the biofilm at the outlet-portion of some of the tubes: This paper reports the observed pitting corrosion behavior of the tubes' alloys. Pitting ·corrosion susceptibility was found to be .generally very minimal except for the 316L alloy which was used for comparison purpos

Propagation of surface initiated rolling contact fatigue cracks in bearing Steel

Surface initiated rolling contact fatigue, leading to a surface failure known as pitting, is a life limiting failure mode in many modern machine elements, particularly rolling element bearings. Most research on rolling contact fatigue considers total life to pitting. Instead, this work studies the growth of rolling contact fatigue cracks before they develop into surface pits in an attempt to better understand crack propagation mechanisms. A triple-contact disc machine was used to perform pitting experiments on bearing steel samples under closely controlled contact conditions in mixed lubrication regime. Crack growth across the specimen surface is monitored and crack propagation rates extracted. The morphology of the generated cracks is observed by preparing sections of cracked specimens at the end of the test. It was found that crack initiation occurred very early in total life, which was attributed to high asperity stresses due to mixed lubrication regime. Total life to pitting was dominated by crack propagation. Results provide direct evidence of two distinct stages of crack growth in rolling contact fatigue: stage 1, within which cracks grow at a slow and relatively steady rate, consumed most of the total life; and stage 2, reached at a critical crack length, within which the propagation rate rapidly increases. Contact pressure and crack size were shown to be the main parameters controlling the propagation rate. Results show that crack propagation under rolling contact fatigue follows similar trends to those known to occur in classical fatigue. A log-log plot of measured crack growth rates against the product of maximum contact pressure and the square root of crack length, a parameter describing the applied stress intensity, produces a straight line for stage 2 propagation. This provides the first evidence that growth of hereby-identified stage 2 rolling contact fatigue cracks can be described by a Paris-type power law, where the rate of crack growth across the surface is proportional to the contact pressure raised to a power of approximately 7.5