Tuning of competing magnetic and superconducting phase volumes in LaFeAsO$_0.945F_0.055 by hydrostatic pressure

The interplay between magnetism and superconductivity in LaFeAsO_0.945F_0.055 was studied as a function of hydrostatic pressure up to p~2.4GPa by means of muon-spin rotation (\muSR) and magnetization measurements. The application of pressure leads to a substantial decrease of the magnetic ordering temperature T_N and a reduction of the magnetic phase volume and, at the same time, to a strong increase of the superconducting transition temperature T_c and the diamagnetic susceptibility. From the volume sensitive \muSR measurements it can be concluded that the superconducting and the magnetic areas which coexist in the same sample are inclined towards spatial separation and compete for phase volume as a function of pressure.Comment: 4 pages, 4 figure

QED peripheral mechanism of pair production at colliders

Cross section of the processes of neutral pion production as well as pairs of charged fermions and bosons in peripherical interaction of leptons, photons are calculated in main logarithmical approximation. We investigate the phase volumes and differential cross sections. The differential cross section of few neutral pions and a few pairs production are written down explicitly. Considering the academic problem of summation on the number of pairs for the case of massless particles we reproduce the known results obtained in seventies of last century. The possibility to construct the generator for Monte-Carlo modeling of this processes basing of this results are discussed.Comment: 25 pages, 5 figure

HILIC characterization: estimation of phase volumes and composition for a zwitterionic column

A methodology for the estimation of the different phase volumes in HILIC is presented. For a ZIC-HILIC column the mobile phase volume (hold-up volume) is determined in several acetonitrile- and methanol-water compositions by a Linear Free Energy Relationships (LFER) homologous series approach involving n-alkyl-benzenes, -phenones, and -ketones. We demonstrate that the column works as a HILIC column when the mobile phase contains high and medium proportions of methanol or acetonitrile. However, for acetonitrile contents below 20%, or 40% for methanol, same column works in RPLC. In between, a mixed HILIC-RPLC behavior is observed, and solutes of low molecular volume are retained as in HILIC mode, but the largest ones show RPLC retention. From the homologous series retention data and pycnometric measurements involving the pure organic solvents and their mixtures with water, the mean solvent composition of the water-rich transition layers between column functionalization and the bulk mobile phase, which act as stationary phase, is estimated. Finally, the phase ratio between stationary and mobile phases is also estimated for each eluent composition, allowing the calculation of the corresponding stationary phase volumes. All volumes are strongly dependent on the water content in the eluent, especially when acetonitrile is selected as mobile phase constituent. In HILIC mode, when the water content in the hydroorganic mobile phase increases, the volumes of mobile phase decrease, but the volumes of stationary phase (mainly the water layer adsorbed onto the bonded-phase and the water-enriched interface) increase. However, at high water concentrations, where the column works in RPLC mode, the mobile phase volume increases and the stationary phase (which is now the bonded zwitterion) volume decreases when increasing the water percentage in the mobile phase

Phase Volume Changes in Multicomponent Extraction Systems Containing Diisopropyl Ether

There are appreciable changes in the phase volumes and the influence of composition and temperature on these changes is very pronounced. Benzene was used as the inert diluent and pentyl alcohol was the active component of the mixed solvent. In all the above mentioned systems, except systems A and B, the third phase (heavy organic phase) was observed at room temperature. The addition of alcohols to some systems suppresses the formation of the third phase

The limit behavior of the evolution of Tsallis entropy in self-gravitating systems

In this letter, we study the limit behavior of the evolution of Tsallis entropy in self-gravitating systems. The study is carried out under two different situations, drawing the same conclusion. No matter in the energy transfer process or in the mass transfer process inside the system, when nonextensive parameter q is more than unity, the total entropy is bounded; on the contrary, when this parameter is less than unity, the total entropy is unbounded. There are proofs in both theory and observation that the q is always more than unity. So the Tsallis entropy in self-gravitating system generally exhibits a bounded property. This indicates the existence of global maximum of Tsallis entropy. It is possible for self-gravitating systems to evolve to thermodynamically stable states