Fabrication and life cycle assessment of organic photovoltaics

Increasing demand for renewable energy has resulted in a new interest for alternative technologies such as organic photovoltaics. With efficiencies exceeding 8% for both polymer and small molecule photovoltaics, organic photovoltaics are now being commercialized due to their flexibility and low weight which allow for their adoption in new applications such as portable electronics, smart fabrics, and building-integrated photovoltaics. To date, most research efforts have been focused on increasing power efficiency with little assessment of potential negative impacts associated with their large scale production. It is generally assumed that organic photovoltaics have low environmental impacts and are by nature inexpensive to produce since they are often solution processed. In the present work, a comprehensive analysis of the life cycle embodied energy for C60 and C70 fullerenes which are the most common acceptor molecules in organic photovoltaics, has been performed from cradle-to-gate, including the relative contributions from synthesis, separation, purification, and functionalization processes. The embodied energy of all fullerenes was calculated to be an order of magnitude higher than most bulk chemicals. These results have enabled the life cycle impact associated with the production of various types of organic photovoltaics to be calculated, including polymer, small molecule and multi-junction devices. An outcome of the life cycle assessment for organic photovoltaics shows that small molecule devices require significant fabrication energy from high vacuum processing and their efficiency is limited by poor absorption in the near-infrared (NIR). Therefore, a solution processing approach with novel NIR absorbing molecules in multi-junction devices has been developed in order to minimize the total cumulative energy. The combined efforts have led to the first demonstration of a spray-coated small molecule photovoltaic NIR device, using a combination of ZnPc and AlPc which is projected to have an embodied energy similar to single junction polymer devices

Technologies to develop technology: the impact of new technologies on the organisation of the innovation process.

Companies are under increasing pressure to develop new product more effectively and efficiently. In order to meet this challenge, the organisation of the new product development process has received ample attention both in the academic literature and in the practitioner literature. As a consequence, a myriad of methods to design new products has been developed. These methods aim at facilitating concurrent product design and engineering. However, it is only recently, through the advent of families of new design technologies, that concurrency really becomes possible. In this paper, research on the impact of new design technologies on the product development process is reported and discussed. It is demonstrated that these technologies can have a significant impact on the organisation of innovation processes.Processes;

Weather and Climate Information for Tourism

The tourism sector is one of the largest and fastest growing global industries and is a significant contributor to national and local economies around the world. The interface between climate and tourism is multifaceted and complex, as climate represents both a vital resource to be exploited and an important limiting factor that poses risks to be managed by the tourism industry and tourists alike. All tourism destinations and operators are climate-sensitive to a degree and climate is a key influence on travel planning and the travel experience. This chapter provides a synopsis of the capacities and needs for climate services in the tourism sector, including current and emerging applications of climate services by diverse tourism end-users, and a discussion of key knowledge gaps, research and capacity-building needs and partnerships that are required to accelerate the application of climate information to manage risks to climate variability and facilitate successful adaptation to climate change

Weather and Climate Information for Tourism

The tourism sector is one of the largest and fastest growing global industries and is a significant contributor to national and local economies around the world. The interface between climate and tourism is multifaceted and complex, as climate represents both a vital resource to be exploited and an important limiting factor that poses risks to be managed by the tourism industry and tourists alike. All tourism destinations and operators are climate-sensitive to a degree and climate is a key influence on travel planning and the travel experience. This chapter provides a synopsis of the capacities and needs for climate services in the tourism sector, including current and emerging applications of climate services by diverse tourism end-users, and a discussion of key knowledge gaps, research and capacity-building needs and partnerships that are required to accelerate the application of climate information to manage risks to climate variability and facilitate successful adaptation to climate change

Weather and Climate Information for Tourism

The tourism sector is one of the largest and fastest growing global industries and is a significant contributor to national and local economies around the world. The interface between climate and tourism is multifaceted and complex, as climate represents both a vital resource to be exploited and an important limiting factor that poses risks to be managed by the tourism industry and tourists alike. All tourism destinations and operators are climate-sensitive to a degree and climate is a key influence on travel planning and the travel experience. This chapter provides a synopsis of the capacities and needs for climate services in the tourism sector, including current and emerging applications of climate services by diverse tourism end-users, and a discussion of key knowledge gaps, research and capacity-building needs and partnerships that are required to accelerate the application of climate information to manage risks to climate variability and facilitate successful adaptation to climate change

Bridges Structural Health Monitoring and Deterioration Detection Synthesis of Knowledge and Technology

INE/AUTC 10.0

Hyperspectral imaging applied to WEEE plastic recycling. A methodological approach

In this study, the possibility of applying the hyperspectral imaging (HSI) technique in the Short-Wave InfraRed (SWIR) spectral range to characterize polymeric parts coming from Waste from Electric and Electronic Equipment (WEEE) is explored. Different case studies are presented referring to the identification of (i) plastic flakes inside a mixed waste stream coming from a recycling plant of monitors and flat screens, (ii) different polymers inside a mixed plastic waste stream coming from End-Of-Life (EOL) electronic device housings and trims, (iii) contaminants (i.e., metals) in a mix of shredded plastic particles coming from a recycling line of electrical cables, and (iv) brominated plastics in mixed streams constituted by small appliances (i.e., cathode-ray tube televisions and monitors). The application of chemometric techniques to hyperspectral data demonstrated the potentiality of this approach for systematic utilization for material characterization, quality control and sorting purposes. The experimental findings highlight the feasibility of employing this method due to its user-friendly nature and quick detection response. To increase and optimize WEEE valorization avoiding disposal in landfills or incineration, recycling-oriented characterization and/or quality control of the processed products are fundamental to identify and quantify substances to be recovered

Integration of e-business strategy for multi-lifecycle production systems

Internet use has grown exponentially on the last few years becoming a global communication and business resource. Internet-based business, or e-Business will truly affect every sector of the economy in ways that today we can only imagine. The manufacturing sector will be at the forefront of this change. This doctoral dissertation provides a scientific framework and a set of novel decision support tools for evaluating, modeling, and optimizing the overall performance of e-Business integrated multi-lifecycle production systems. The characteristics of this framework include environmental lifecycle study, environmental performance metrics, hyper-network model of integrated e-supply chain networks, fuzzy multi-objective optimization method, discrete-event simulation approach, and scalable enterprise environmental management system design. The dissertation research reveals that integration of e-Business strategy into production systems can alter current industry practices along a pathway towards sustainability, enhancing resource productivity, improving cost efficiencies and reducing lifecycle environmental impacts. The following research challenges and scholarly accomplishments have been addressed in this dissertation: Identification and analysis of environmental impacts of e-Business. A pioneering environmental lifecycle study on the impact of e-Business is conducted, and fuzzy decision theory is further applied to evaluate e-Business scenarios in order to overcome data uncertainty and information gaps; Understanding, evaluation, and development of environmental performance metrics. Major environmental performance metrics are compared and evaluated. A universal target-based performance metric, developed jointly with a team of industry and university researchers, is evaluated, implemented, and utilized in the methodology framework; Generic framework of integrated e-supply chain network. The framework is based on the most recent research on large complex supply chain network model, but extended to integrate demanufacturers, recyclers, and resellers as supply chain partners. Moreover, The e-Business information network is modeled as a overlaid hypernetwork layer for the supply chain; Fuzzy multi-objective optimization theory and discrete-event simulation methods. The solution methods deal with overall system parameter trade-offs, partner selections, and sustainable decision-making; Architecture design for scalable enterprise environmental management system. This novel system is designed and deployed using knowledge-based ontology theory, and XML techniques within an agent-based structure. The implementation model and system prototype are also provided. The new methodology and framework have the potential of being widely used in system analysis, design and implementation of e-Business enabled engineering systems