Type-B Energetic Processes and Their Associated Scientific Implications

Recently, our work has identified two thermodynamically distinct types (A and B) of energetic processes naturally occurring on Earth. Type-A energy processes such as the classical heat engines, ATP hydrolysis, and many of the known chemical, electrical, and mechanical processes apparently follow well the second law of thermodynamics; Type-B energy processes, for example, the newly discovered thermotropic function that isothermally utilizes environmental heat energy to do useful work in driving ATP synthesis, follow the first law of thermodynamics (conservation of mass and energy) but do not have to be constrained by the second law, owing to its special asymmetric functions. In mitochondria, special asymmetric functions associated with Type-B processes comprise: 1) Transmembrane-electrostatic proton localization; 2) The transmembrane asymmetry of inner mitochondrial membrane structure with the protonic outlets of redox-driven proton-pumping protein complexes protruded away from the membrane surface by about 1–3 nm into the bulk liquid p-phase while the protonic inlet of the F0F1-ATP synthase located at the transmembrane-electrostatically localized proton (TELP) layer; and 3) The lateral asymmetry of mitochondrial cristae with an ellipsoidal shape that enhances the density of TELP at the cristae tips where the F0F1-ATP synthase enzymes are located in support of the TELP-associated thermotrophic function. The identification of Type-B energy processes indicates that there is an entirely new world of physical and energy sciences yet to be fully explored. Innovative efforts exploring Type-B processes to enable isothermally utilizing endless environmental heat energy could help liberate all people from their dependence on fossil fuel energy, thus helping to reduce greenhouse gas CO2 emissions and control climate change, with the goal of a sustainable future for humanity on Earth

Transformation Thermotics and Extended Theories

This open access book describes the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. This monograph consists of two parts, i.e., inside and outside metamaterials, and covers the basic concepts and mathematical methods, which are necessary to understand the thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied by computer simulations and laboratory experiments. This monograph can not only be a bridge linking three first-class disciplines, i.e., physics, thermophysics, and materials science, but also contribute to interdisciplinary development

Transformation Thermotics and Extended Theories

This open access book describes the theory of transformation thermotics and its extended theories for the active control of macroscopic thermal phenomena of artificial systems, which is in sharp contrast to classical thermodynamics comprising the four thermodynamic laws for the passive description of macroscopic thermal phenomena of natural systems. This monograph consists of two parts, i.e., inside and outside metamaterials, and covers the basic concepts and mathematical methods, which are necessary to understand the thermal problems extensively investigated in physics, but also in other disciplines of engineering and materials. The analyses rely on models solved by analytical techniques accompanied by computer simulations and laboratory experiments. This monograph can not only be a bridge linking three first-class disciplines, i.e., physics, thermophysics, and materials science, but also contribute to interdisciplinary development

Controlling mass and energy diffusion with metamaterials

Diffusion driven by temperature or concentration gradients is a fundamental mechanism of energy and mass transport, which inherently differs from wave propagation in both physical foundations and application prospects. Compared with conventional schemes, metamaterials provide an unprecedented potential for governing diffusion processes, based on emerging theories like the transformation and the scattering cancellation theory, which enormously expanded the original concepts and suggest innovative metamaterial-based devices. We hereby use the term ``diffusionics'' to generalize these remarkable achievements in various energy (e.g., heat) and mass (e.g., particles and plasmas) diffusion systems. For clarity, we categorize the numerous studies appeared during the last decade by diffusion field (i.e., heat, particles, and plasmas) and discuss them from three different perspectives: the theoretical perspective, to detail how the transformation principle is applied to each diffusion field; the application perspective, to introduce various intriguing metamaterial-based devices, such as cloaks and radiative coolers; and the physics perspective, to connect with concepts of recent concern, such as non-Hermitian topology, nonreciprocal transport, and spatiotemporal modulation. We also discuss the possibility of controlling diffusion processes beyond metamaterials. Finally, we point out several future directions for diffusion metamaterial research, including the integration with artificial intelligence and topology concepts.Comment: This review article has been accepted for publication in Rev. Mod. Phy

Isothermal Environmental Heat Energy Utilization by Transmembrane Electrostatically Localized Protons at the Liquid-Membrane Interface

This study employing the latest theory on transmembrane electrostatic proton localization has now, for the first time, consistently elucidated a decades-longstanding bioenergetic conundrum in alkalophilic bacteria and more importantly discovered an entirely new feature: isothermal environmental heat utilization by electrostatically localized protons at the liquid-membrane interface. It was surprisingly revealed that the protonic motive force (equivalent to Gibbs free energy) from the isothermal environmental heat energy utilization through the electrostatically localized protons is not constrained by the overall energetics of the redox-driven proton pump system because of the following: (a) the transmembrane electrostatically localized protons are not free to move away from the membrane surface as a protonic capacitor feature; (b) the proton pumps embedded in the cell membrane extend beyond the localized proton layer apparently as an asymmetric property of the biological membrane; and (c) the protonic inlet mouth of the ATP synthase that accepts protons is located within this layer as another natural property of the asymmetric biological membrane. This work has now, for the first time, shown a novel thermotrophic feature where biological systems can isothermally utilize environmental heat energy through transmembrane electrostatically localized protons to help drive ATP synthesis

Energy Renewal: Isothermal Utilization of Environmental Heat Energy with Asymmetric Structures

Through the research presented herein, it is quite clear that there are two thermodynamically distinct types (A and B) of energetic processes naturally occurring on Earth. Type A, such as glycolysis and the tricarboxylic acid cycle, apparently follows the second law well; Type B, as exemplified by the thermotrophic function with transmembrane electrostatically localized protons presented here, does not necessarily have to be constrained by the second law, owing to its special asymmetric function. This study now, for the first time, numerically shows that transmembrane electrostatic proton localization (Type-B process) represents a negative entropy event with a local protonic entropy change (Δ SL) in a range from −95 to −110 J/K∙mol. This explains the relationship between both the local protonic entropy change (ΔSL) and the mitochondrial environmental temperature (T) and the local protonic Gibbs free energy (ΔGL=TΔSL) in isothermal environmental heat utilization. The energy efficiency for the utilization of total protonic Gibbs free energy (ΔGT including ΔGL=TΔSL) in driving the synthesis of ATP is estimated to be about 60%, indicating that a significant fraction of the environmental heat energy associated with the thermal motion kinetic energy (kBT) of transmembrane electrostatically localized protons is locked into the chemical form of energy in ATP molecules. Fundamentally, it is the combination of water as a protonic conductor, and thus the formation of protonic membrane capacitor, with asymmetric structures of mitochondrial membrane and cristae that makes this amazing thermotrophic feature possible. The discovery of energy Type-B processes has inspired an invention (WO 2019/136037 A1) for energy renewal through isothermal environmental heat energy utilization with an asymmetric electron-gated function to generate electricity, which has the potential to power electronic devices forever, including mobile phones and laptops. This invention, as an innovative Type-B mimic, may have many possible industrial applications and is likely to be transformative in energy science and technologies for sustainability on Earth

Geometric manipulation of light : from nonlinear optics to invisibility cloaks

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Mathematics, 2012.Cataloged from PDF version of thesis.Includes bibliographical references (p. 189-203).In this work, we study two different manipulations of electromagnetic waves governed by macroscopic Maxwell's equations. One is frequency conversion of such waves using small intrinsic material nonlinearities. We study conversion of an input signal at frequency w1 to frequency Wk due to second or third harmonic generation or four-wave mixing using coupled-mode theory. Using this framework, we show there is a critical input power at which maximum frequency conversion is possible. We study in depth the case of third harmonic generation, its solutions, and their stability analysis. Based on the dynamics of the system, we propose a regime of parameters that 100%- efficient frequency conversion is possible and propose a way of exciting this solution. We also look at same analysis for the case of degenerate four-wave mixing and come up with 2d and 3d designs of a device that exhibits high-efficiency second-harmonic generation. Second, we consider proposals for invisibility cloaks to change the path of electromagnetic waves in a certain way so that the object appears invisible at a certain frequency or a range of frequencies. Transformation-based invisibility cloaks make use of the coordinate invariance of Maxwell's Equations and require complex material configuration e and p in the cloak. We study the practical limitations of cloaking as a function of the size of the object being cloaked. Specifically, we study the bandwidth, loss, and scattering limitations of cloaking as the object gets larger and show that cloaking of objects many times larger than the wavelength in size becomes practically impossible.by Hila Hashemi.Ph.D

Spherical inhomogeneous solutions of Einstein and scalar-tensor gravity: a map of the land

We review spherical and inhomogeneous analytic solutions of the field equations of Einstein and of scalar-tensor gravity, including Brans-Dicke theory, non-minimally (possibly conformally) coupled scalar fields, Horndeski, and beyond Horndeski/DHOST gravity. The zoo includes both static and dynamic solutions, asymptotically flat, and asymptotically Friedmann-Lema\^itre-Robertson-Walker ones. We minimize overlap with existing books and reviews and we place emphasis on scalar field spacetimes and on geometries that are "general" within certain classes. Relations between various solutions, which have largely emerged during the last decade, are pointed out.Comment: 140 pages, one figure. Explanation text and bibliography expanded, typographical errors corrected. Matches version to appear in Physics Report

Metamaterial

In-depth analysis of the theory, properties and description of the most potential technological applications of metamaterials for the realization of novel devices such as subwavelength lenses, invisibility cloaks, dipole and reflector antennas, high frequency telecommunications, new designs of bandpass filters, absorbers and concentrators of EM waves etc. In order to create a new devices it is necessary to know the main electrodynamical characteristics of metamaterial structures on the basis of which the device is supposed to be created. The electromagnetic wave scattering surfaces built with metamaterials are primarily based on the ability of metamaterials to control the surrounded electromagnetic fields by varying their permeability and permittivity characteristics. The book covers some solutions for microwave wavelength scales as well as exploitation of nanoscale EM wavelength such as visible specter using recent advances of nanotechnology, for instance in the field of nanowires, nanopolymers, carbon nanotubes and graphene. Metamaterial is suitable for scholars from extremely large scientific domain and therefore given to engineers, scientists, graduates and other interested professionals from photonics to nanoscience and from material science to antenna engineering as a comprehensive reference on this artificial materials of tomorrow

Antennas and Electromagnetics Research via Natural Language Processing.

Advanced techniques for performing natural language processing (NLP) are being utilised to devise a pioneering methodology for collecting and analysing data derived from scientific literature. Despite significant advancements in automated database generation and analysis within the domains of material chemistry and physics, the implementation of NLP techniques in the realms of metamaterial discovery, antenna design, and wireless communications remains at its early stages. This thesis proposes several novel approaches to advance research in material science. Firstly, an NLP method has been developed to automatically extract keywords from large-scale unstructured texts in the area of metamaterial research. This enables the uncovering of trends and relationships between keywords, facilitating the establishment of future research directions. Additionally, a trained neural network model based on the encoder-decoder Long Short-Term Memory (LSTM) architecture has been developed to predict future research directions and provide insights into the influence of metamaterials research. This model lays the groundwork for developing a research roadmap of metamaterials. Furthermore, a novel weighting system has been designed to evaluate article attributes in antenna and propagation research, enabling more accurate assessments of impact of each scientific publication. This approach goes beyond conventional numeric metrics to produce more meaningful predictions. Secondly, a framework has been proposed to leverage text summarisation, one of the primary NLP tasks, to enhance the quality of scientific reviews. It has been applied to review recent development of antennas and propagation for body-centric wireless communications, and the validation has been made available for comparison with well-referenced datasets for text summarisation. Lastly, the effectiveness of automated database building in the domain of tunable materials and their properties has been presented. The collected database will use as an input for training a surrogate machine learning model in an iterative active learning cycle. This model will be utilised to facilitate high-throughput material processing, with the ultimate goal of discovering novel materials exhibiting high tunability. The approaches proposed in this thesis will help to accelerate the discovery of new materials and enhance their applications in antennas, which has the potential to transform electromagnetic material research