From carbon nanotubes and silicate layers to graphene platelets for polymer nanocomposites

In spite of extensive studies conducted on carbon nanotubes and silicate layers for their polymer-based nanocomposites, the rise of graphene now provides a more promising candidate due to its exceptionally high mechanical performance and electrical and thermal conductivities. The present study developed a facile approach to fabricate epoxy–graphene nanocomposites by thermally expanding a commercial product followed by ultrasonication and solution-compounding with epoxy, and investigated their morphologies, mechanical properties, electrical conductivity and thermal mechanical behaviour. Graphene platelets (GnPs) of 3.5

Evaluation of the Effects of Predicted Associativity on the Reliability and Performance of Mobile Ad Hoc Networks

Routing in Mobile Ad Hoc Networks (MANETs) presents unique challenges not encountered in conventional networks. Predicted Associativity Routing (PAR) is a protocol designed to address reliability in MANETs. Using associativity information, PAR calculates the expected lifetime of neighboring links. Nodes use this expected lifetime, and their neighbor\u27s connectivity to determine a residual lifetime. The routes are selected from those with the longest residual lifetimes. In this way, PAR attempts to improve the reliability of discovered routes. PAR is compared to AODV using a variety of reliability and performance metrics. Despite its focus on reliability, PAR does not provide more reliable routes. Rather, AODV produces routes which last as much as three times longer than PAR. However, PAR delivers more data and has greater throughput. Both protocols are affected most by the node density of the networks. Node density accounts for 48.62% of the variation in route lifetime in AODV, and 70.66% of the variation in PAR. As node density increases from 25 to 75 nodes route lifetimes are halved, while throughput increases drastically with the increased routing overhead. Furthermore, PAR increases end-to-end delay, while AODV displays better efficiency

Performance Assessment of Routing Protocols for IoT/6LoWPAN Networks

The Internet of Things (IoT) proposes a disruptive communication paradigm that allows smart objects to exchange data among themselves to reach a common goal. IoT application scenarios are multiple and can range from a simple smart home lighting system to fully controlled automated manufacturing chains. In the majority of IoT deployments, things are equipped with small devices that can suffer from severe hardware and energy restrictions that are responsible for performing data processing and wireless communication tasks. Thus, due to their features, communication networks that are used by these devices are generally categorized as Low Power and Lossy Networks (LLNs). The considerable variation in IoT applications represents a critical issue to LLN networks, which should offer support to different requirements as well as keeping reasonable quality-of-service (QoS) levels. Based on this challenge, routing protocols represent a key issue in IoT scenarios deployment. Routing protocols are responsible for creating paths among devices and their interactions. Hence, network performance and features are highly dependent on protocol behavior. Also, based on the adopted protocol, the support for some specific requirements of IoT applications may or may not be provided. Thus, a routing protocol should be projected to attend the needs of the applications considering the limitations of the device that will execute them. Looking to attend the demand of routing protocols for LLNs and, consequently, for IoT networks, the Internet Engineering Task Force (IETF) has designed and standardized the IPv6 Routing Protocol for Low Power and Lossy Networks (RPL). This protocol, although being robust and offering features to fulfill the need of several applications, still presents several faults and weaknesses (mainly related to its high complexity and memory requirement), which limits its adoption in IoT scenarios. An alternative to RPL, the Lightweight On-demand Ad Hoc Distancevector Routing Protocol – Next Generation (LOADng) has emerged as a less complicated routing solution for LLNs. However, the cost of its simplicity is paid for with the absence of adequate support for a critical set of features required for many IoT environments. Thus, based on the challenging open issues related to routing in IoT networks, this thesis aims to study and propose contributions to better attend the network requirements of IoT scenarios. A comprehensive survey, reviewing state-of-the-art routing protocols adopted for IoT, identified the strengths and weaknesses of current solutions available in the literature. Based on the identified limitations, a set of improvements is designed to overcome these issues and enhance IoT network performance. The novel solutions are proposed to include reliable and efficient support to attend the needs of IoT applications, such as mobility, heterogeneity, and different traffic patterns. Moreover, mechanisms to improve the network performance in IoT scenarios, which integrate devices with different communication technologies, are introduced. The studies conducted to assess the performance of the proposed solutions showed the high potential of the proposed solutions. When the approaches presented in this thesis were compared with others available in the literature, they presented very promising results considering the metrics related to the Quality of Service (QoS), network and energy efficiency, and memory usage as well as adding new features to the base protocols. Hence, it is believed that the proposed improvements contribute to the state-of-the-art of routing solutions for IoT networks, increasing the performance and adoption of enhanced protocols.A Internet das Coisas, do inglês Internet of Things (IoT), propõe um paradigma de comunicação disruptivo para possibilitar que dispositivos, que podem ser dotados de comportamentos autónomos ou inteligentes, troquem dados entre eles buscando alcançar um objetivo comum. Os cenários de aplicação do IoT são muito variados e podem abranger desde um simples sistema de iluminação para casa até o controle total de uma linha de produção industrial. Na maioria das instalações IoT, as “coisas” são equipadas com um pequeno dispositivo, responsável por realizar as tarefas de comunicação e processamento de dados, que pode sofrer com severas restrições de hardware e energia. Assim, devido às suas características, a rede de comunicação criada por esses dispositivos é geralmente categorizada como uma Low Power and Lossy Network (LLN). A grande variedade de cenários IoT representam uma questão crucial para as LLNs, que devem oferecer suporte aos diferentes requisitos das aplicações, além de manter níveis de qualidade de serviço, do inglês Quality of Service (QoS), adequados. Baseado neste desafio, os protocolos de encaminhamento constituem um aspecto chave na implementação de cenários IoT. Os protocolos de encaminhamento são responsáveis por criar os caminhos entre os dispositivos e permitir suas interações. Assim, o desempenho e as características da rede são altamente dependentes do comportamento destes protocolos. Adicionalmente, com base no protocolo adotado, o suporte a alguns requisitos específicos das aplicações de IoT podem ou não ser fornecidos. Portanto, estes protocolos devem ser projetados para atender as necessidades das aplicações assim como considerando as limitações do hardware no qual serão executados. Procurando atender às necessidades dos protocolos de encaminhamento em LLNs e, consequentemente, das redes IoT, a Internet Engineering Task Force (IETF) desenvolveu e padronizou o IPv6 Routing Protocol for Low Power and Lossy Networks (RPL). O protocolo, embora seja robusto e ofereça recursos para atender às necessidades de diferentes aplicações, apresenta algumas falhas e fraquezas (principalmente relacionadas com a sua alta complexidade e necessidade de memória) que limitam sua adoção em cenários IoT. Em alternativa ao RPL, o Lightweight On-demand Ad hoc Distance-vector Routing Protocol – Next Generation (LOADng) emergiu como uma solução de encaminhamento menos complexa para as LLNs. Contudo, o preço da simplicidade é pago com a falta de suporte adequado para um conjunto de recursos essenciais necessários em muitos ambientes IoT. Assim, inspirado pelas desafiadoras questões ainda em aberto relacionadas com o encaminhamento em redes IoT, esta tese tem como objetivo estudar e propor contribuições para melhor atender os requisitos de rede em cenários IoT. Uma profunda e abrangente revisão do estado da arte sobre os protocolos de encaminhamento adotados em IoT identificou os pontos fortes e limitações das soluções atuais. Com base nas debilidades encontradas, um conjunto de soluções de melhoria é proposto para superar carências existentes e melhorar o desempenho das redes IoT. As novas soluções são propostas para incluir um suporte confiável e eficiente capaz atender às necessidades das aplicações IoT relacionadas com suporte à mobilidade, heterogeneidade dos dispositivos e diferentes padrões de tráfego. Além disso, são introduzidos mecanismos para melhorar o desempenho da rede em cenários IoT que integram dispositivos com diferentes tecnologias de comunicação. Os vários estudos realizados para mensurar o desempenho das soluções propostas mostraram o grande potencial do conjunto de melhorias introduzidas. Quando comparadas com outras abordagens existentes na literatura, as soluções propostas nesta tese demonstraram um aumento do desempenho consistente para métricas relacionadas a qualidade de serviço, uso de memória, eficiência energética e de rede, além de adicionar novas funcionalidades aos protocolos base. Portanto, acredita-se que as melhorias propostas contribuiem para o avanço do estado da arte em soluções de encaminhamento para redes IoT e aumentar a adoção e utilização dos protocolos estudados

A Hybrid Model to Extend Vehicular Intercommunication V2V through D2D Architecture

In the recent years, many solutions for Vehicle to Vehicle (V2V) communication were proposed to overcome failure problems (also known as dead ends). This paper proposes a novel framework for V2V failure recovery using Device-to-Device (D2D) communications. Based on the unified Intelligent Transportation Systems (ITS) architecture, LTE-based D2D mechanisms can improve V2V dead ends failure recovery delays. This new paradigm of hybrid V2V-D2D communications overcomes the limitations of traditional V2V routing techniques. According to NS2 simulation results, the proposed hybrid model decreases the end to end delay (E2E) of messages delivery. A complete comparison of different D2D use cases (best & worst scenarios) is presented to show the enhancements brought by our solution compared to traditional V2V techniques.Comment: 6 page