Corrosion and Protection of Metals

Introduction and Scope—During the last few decades, an enormous effort has been made to understand corrosion phenomena and their mechanisms, and to elucidate the causes that dramatically influence the service lifetime of metal materials. The performance of metal materials in aggressive environments is critical for a sustainable society. The failure of the material in service impacts the economy, the environment, health, and society. In this regard, corrosion-based economic losses due to maintenance, repair, and the replacement of existing structures and infrastructure account for up to 4% of gross domestic product (GDP) in well developed countries. One of the biggest issues in corrosion engineering is estimating service lifetime. Corrosion prediction has become very difficult, as there is no direct correlation with service lifetime and experimental lab results, usually as a result of discrepancies between accelerated testing and real corrosion processes. It is of major interest to forecast the impact of corrosion-based losses on society and the global economy, since existing structures and infrastructure are becoming old, and crucial decisions now need to be made to replace them. On the other hand, environmental protocols seek to reduce greenhouse effects. Therefore, low emission policies, in force, establish regulations for the next generation of materials and technologies. Advanced technologies and emergent materials will enable us to get through the next century. Great advances are currently in progress for the development of corrosion-resistant metal materials for different sectors, such as energy, transport, construction, and health. This Special Issue on the corrosion and protection of metals is focused on current trends in corrosion science, engineering, and technology, ranging from fundamental to applied research, thus covering subjects related to corrosion mechanisms and modelling, protection and inhibition processes, and mitigation strategies

SPATIAL TRANSFORMATION PATTERN DUE TO COMMERCIAL ACTIVITY IN KAMPONG HOUSE

ABSTRACT Kampung houses are houses in kampung area of the city. Kampung House oftenly transformed into others use as urban dynamics. One of the transfomation is related to the commercial activities addition by the house owner. It make house with full private space become into mixused house with more public spaces or completely changed into full public commercial building. This study investigate the spatial transformation pattern of the kampung houses due to their commercial activities addition. Site observations, interviews and questionnaires were performed to study the spatial transformation. This study found that in kampung houses, the spatial transformation pattern was depend on type of commercial activities and owner perceptions, and there are several steps of the spatial transformation related the commercial activity addition. Keywords: spatial transformation pattern; commercial activity; owner perception, kampung house; adaptabilit

Planet Earth 2011

The failure of the UN climate change summit in Copenhagen in December 2009 to effectively reach a global agreement on emission reduction targets, led many within the developing world to view this as a reversal of the Kyoto Protocol and an attempt by the developed nations to shirk out of their responsibility for climate change. The issue of global warming has been at the top of the political agenda for a number of years and has become even more pressing with the rapid industrialization taking place in China and India. This book looks at the effects of climate change throughout different regions of the world and discusses to what extent cleantech and environmental initiatives such as the destruction of fluorinated greenhouse gases, biofuels, and the role of plant breeding and biotechnology. The book concludes with an insight into the socio-religious impact that global warming has, citing Christianity and Islam

Design of a COTS MST distributed sensor suite system for planetary surface exploration

The aim of this project is To bring together current commercially available technology and relevant Microsystems Technology (MST) into a small, standardised spacecraft primary systems architecture, multiple units of which can demonstrate collaboration… Distributed “lab-on-a-chip” sensor networks are a possible option for the surface exploration of both Earth and Mars, and as such have been chosen as a model small spacecraft architecture. This project presents a systems approach to the design of a collection of collaborative MST sensor suites for use in a variety of environments. Based on a set of derived objectives, the main features of the study are: What are the fundamental limits to miniaturisation? What are the hardware issues raised using both standard and MST components? What is the optimum deployment pattern of the network to locate various shaped targets? What are the strategic and economic challenges of MST and the development of a sensor suite network? In general, there are few fundamental physical laws that limit the size of the sensor system. Limits tend to be driven by other factors including user requirements and the external environment. A simple breadboard model of the sensor suite consisting current COTS MST components raised practical issues such as circuit layouts, power requirements and packaging. A grid illustrating features of the Martian surface was created. Various patterns of target and sensor clusters were simulated. Overall, for larger target areas, clusters of sensors produced the best “hit rate”. The overall system utilises both wired and wireless communications methods. The I2C protocol has been investigated for intersuite communications. A link has been made between bacteria pools found on Glaciers (Cryoconites) and the possible conditions for life at the Polar Ice Caps of Mars. The investigation of Arctic Cryoconites has been selected as a representative case study that will incorporate all aspects of the project and demonstrate the system design. A comprehensive mission baseline based on this application has been produced, however the system has been designed to enable its use in a variety of situations whilst requiring only minimal modification to the overall design.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Spatial variability of aircraft-measured surface energy fluxes in permafrost landscapes

Arctic ecosystems are undergoing a very rapid change due to global warming and their response to climate change has important implications for the global energy budget. Therefore, it is crucial to understand how energy fluxes in the Arctic will respond to any changes in climate related parameters. However, attribution of these responses is challenging because measured fluxes are the sum of multiple processes that respond differently to environmental factors. Here, we present the potential of environmental response functions for quantitatively linking energy flux observations over high latitude permafrost wetlands to environmental drivers in the flux footprints. We used the research aircraft POLAR 5 equipped with a turbulence probe and fast temperature and humidity sensors to measure turbulent energy fluxes along flight tracks across the Alaskan North Slope with the aim to extrapolate the airborne eddy covariance flux measurements from their specific footprint to the entire North Slope. After thorough data pre-processing, wavelet transforms are used to improve spatial discretization of flux observations in order to relate them to biophysically relevant surface properties in the flux footprint. Boosted regression trees are then employed to extract and quantify the functional relationships between the energy fluxes and environmental drivers. Finally, the resulting environmental response functions are used to extrapolate the sensible heat and water vapor exchange over spatio-temporally explicit grids of the Alaskan North Slope. Additionally, simulations from the Weather Research and Forecasting (WRF) model were used to explore the dynamics of the atmospheric boundary layer and to examine results of our extrapolation

58th Annual Rocky Mountain Conference on Magnetic Resonance

Final program, abstracts, and information about the 58th annual meeting of the Rocky Mountain Conference on Magnetic Resonance, co-endorsed by the Colorado Section of the American Chemical Society and the Society for Applied Spectroscopy. Held in Breckenridge, Colorado, July 17-21, 2016

Investigation of Volatile Organic Compounds (VOCs) released as a result of spoilage in whole broccoli, carrots, onions and potatoes with HS-SPME and GC-MS

Vegetable spoilage renders a product undesirable due to changes in sensory characteristics. The aim of this study was to investigate the change in the fingerprint of VOC composition that occur as a result of spoilage in broccoli, carrots, onions and potatoes. SPME and GC-MS techniques were used to identify and determine the relative abundance of VOC associated with both fresh and spoilt vegetables. Although a number of similar compounds were detected in varying quantities in the headspace of fresh and spoilt samples, certain compounds which were detected in the headspace of spoilt vegetables were however absent in fresh samples. Analysis of the headspace of fresh vegetables indicated the presence of a variety of alkanes, alkenes and terpenes. Among VOCs identified in the spoilt samples were dimethyl disulphide and dimethyl sulphide in broccoli; Ethyl propanoate and Butyl acetate in carrots; 1-Propanethioland 2-Hexyl-5-methyl-3(2H)-furanone in onions; and 2, 3-Butanediol in potatoes. The overall results of this study indicate the presence of VOCs that can serve as potential biomarkers for early detection of quality deterioration and in turn enhance operational and quality control decisions in the vegetable industry

Improved Analytical Technologies for the Detection of Natural Toxins and Their Metabolites in Food

Food, by nature, is a biological substrate and is therefore capable of supporting the growth of microbials that are potential producers of toxic compounds. Among them mycotoxins, marine biotoxins, plant toxins, cyanogenic glycosides, and toxins occurring in poisonous mushrooms pose not only a risk to both human and animal health but also impact food security and nutrition by reducing people’s access to healthy food. This book collects some of the recent key improvements of analytical methodologies for the detection of natural toxins and their metabolites in food, and highlights the challenges yet to be resolved. Special emphasis is given to emerging or less-investigated toxins, to provide the scientific community with new tools and/or data supporting a better understanding of related food safety issues