Revealing Nanoscale Solid-Solid Interfacial Phenomena for Long-Life and High-Energy All-Solid-State Batteries.

Enabling long cyclability of high-voltage oxide cathodes is a persistent challenge for all-solid-state batteries, largely because of their poor interfacial stabilities against sulfide solid electrolytes. While protective oxide coating layers such as LiNbO3 (LNO) have been proposed, its precise working mechanisms are still not fully understood. Existing literature attributes reductions in interfacial impedance growth to the coating's ability to prevent interfacial reactions. However, its true nature is more complex, with cathode interfacial reactions and electrolyte electrochemical decomposition occurring simultaneously, making it difficult to decouple each effect. Herein, we utilized various advanced characterization tools and first-principles calculations to probe the interfacial phenomenon between solid electrolyte Li6PS5Cl (LPSCl) and high-voltage cathode LiNi0.85Co0.1Al0.05O2 (NCA). We segregated the effects of spontaneous reaction between LPSCl and NCA at the interface and quantified the intrinsic electrochemical decomposition of LPSCl during cell cycling. Both experimental and computational results demonstrated improved thermodynamic stability between NCA and LPSCl after incorporation of the LNO coating. Additionally, we revealed the in situ passivation effect of LPSCl electrochemical decomposition. When combined, both these phenomena occurring at the first charge cycle result in a stabilized interface, enabling long cyclability of all-solid-state batteries

Unusual high-pT jet events at HERA

We calculate the cross-section for events at HERA where the proton loses only a minute fraction of its initial energy, all of which goes into producing a single pair of transverse jets.Comment: 4 pages plus figure

A dark energy multiverse

We present cosmic solutions corresponding to universes filled with dark and phantom energy, all having a negative cosmological constant. All such solutions contain infinite singularities, successively and equally distributed along time, which can be either big bang/crunchs or big rips singularities. Classicaly these solutions can be regarded as associated with multiverse scenarios, being those corresponding to phantom energy that may describe the current accelerating universe

Stodolsky's Theorem and Neutrino Oscillation Phases -- for pedestrians

Neutrino oscillations are experimentally observable only as a result of interference between neutrino states with different masses and THE SAME ENERGY. All interference effects between neutrino states having different energies are destroyed by the intereaction between the incident neutrino and the neutrino detector. Erroneous results are frequently obtained by neglecting the neutrino-detector interactions.Comment: 6 pages, Two paragraphs of discussion on possible time measurements added at en

Theory of single-particle properties of the Hubbard model

It is shown that it is possible to quantitatively explain quantum Monte Carlo results for the Green's function of the two-dimensional Hubbard model in the weak to intermediate coupling regime. The analytic approach includes vertex corrections in a paramagnon-like self-energy. All parameters are determined self-consistently. This approach clearly shows that in two dimensions Fermi-liquid quasiparticles disappear in the paramagnetic state when the antiferromagnetic correlation length becomes larger than the electronic thermal de Broglie wavelength.Comment: 5 pages, latex, uuencoded figures, REVTEX Also available by direct request to [email protected]

Spin filtering by a periodic nanospintronic devices

For a linear chain of diamond-like elements, we show that the Rashba spin-orbit interaction (which can be tuned by a perpendicular gate voltage) and the Aharonov-Bohm flux (due to a perpendicular magnetic field) can combine to select only one propagating ballistic mode, for which the electronic spins are fully polarized along a direction that can be tuned by the electric and magnetic fields and by the electron energy. All the other modes are evanescent. For a wide range of parameters, this chain can serve as a spin filter.Comment: Published versio