Silicon Derived from Glass Bottles as Anode Materials for Lithium Ion Full Cell Batteries.

Every year many tons of waste glass end up in landfills without proper recycling, which aggravates the burden of waste disposal in landfill. The conversion from un-recycled glass to favorable materials is of great significance for sustainable strategies. Recently, silicon has been an exceptional anode material towards large-scale energy storage applications, due to its extraordinary lithiation capacity of 3579 mAh g-1 at ambient temperature. Compared with other quartz sources obtained from pre-leaching processes which apply toxic acids and high energy-consuming annealing, an interconnected silicon network is directly derived from glass bottles via magnesiothermic reduction. Carbon-coated glass derived-silicon (gSi@C) electrodes demonstrate excellent electrochemical performance with a capacity of ~1420 mAh g-1 at C/2 after 400 cycles. Full cells consisting of gSi@C anodes and LiCoO2 cathodes are assembled and achieve good initial cycling stability with high energy density

Design criteria of a transcutaneous power delivery system for implantable devices.

Implantable cardiac assist devices such as artificial hearts and blood pumps are a rapidly growing therapy used for treating moderate to severe congestive heart failure. While current treatments offer improved heart failure survival and increased patient functionality with enhanced quality of life, powering these devices are still constraining. In practice, percutaneous cables passing through skin are used for power and control data transmission requiring patients to maintain a sterile dressing on the skin cable-exit site. This contact site limits patient movement as it is vulnerable to wound infection due to trauma and poor healing. As a result, a sterile dressing has to be maintained and nursed regularly for treating the wound. Complications from the exit site infections are a leading cause of death in long-term support with these devices. Wireless power and control transmission systems have been studied and developed over years in order to avoid percutaneous cables while supplying power efficiently to the implanted device. These power systems, commonly named Transcutaneous Energy Transfer (TET) systems, enable power transmission across the skin without direct electrical connectivity to the power source. TET systems use time-varying electromagnetic induction produced by a primary coil that is usually placed near skin outside the body. The induced voltage in an implanted secondary coil is then rectified and regulated to transfer energy to an implanted rechargeable battery in order to power the biomedical load device. Efficient and optimum energy transfer using such transcutaneous methods is more complex for mobile patients due to coupling discrepancies caused by variations in the alignment of the coil. The research studies equivalent maximum power transfer topologies for evaluating voltage gain and coupling link efficiency of TET system. Also, this research adds to previous efforts by generalizing different scenarios of misalignments of different coil size that affects the coupling link. As a whole, this study of geometric coil misalignments reconsiders potential anatomic location for coil placement to optimize TET systems performance in anticipated environment for efficient and safe operation.--Abstract

Structural vibration energy harvesting via bistable nonlinear attachments

A vibration-based bistable electromagnetic energy harvester coupled to a directly excited host structure is theoretically and experimentally examined. The primary goal of the study is to investigate the potential benet of the bistable element for harvesting broadband and low-amplitude vibration energy. The considered system consists of a grounded, weakly damped, linear oscillator (LO) coupled to a lightweight, damped oscillator by means of an element which provides for both cubic nonlinear and negative linear stiness components and electromechanical coupling elements. Single and repeated impulses with varying amplitude applied to the LO are the vibration energy sources considered. A thorough sensitivity analysis of the system's key parameters provides design insights for a bistable nonlinear energy harvesting (BNEH) device able to attain robust harvesting efficiency. Energy localization into the bistable attachment is achieved through the exploitation of three BNEH main dynamical regimes; namely, periodic cross-well, aperiodic (chaotic) cross-well, and in-well oscillations. For the experimental investigation on the performance of the bistable device, nonlinear and negative linear terms in the mechanical coupling are physically realized by exploiting the transverse displacement of a buckled slender steel beam; the electromechanical coupling is accomplished by an electromagnetic transducer

A Detail Based Method for Linear Full Reference Image Quality Prediction

In this paper, a novel Full Reference method is proposed for image quality assessment, using the combination of two separate metrics to measure the perceptually distinct impact of detail losses and of spurious details. To this purpose, the gradient of the impaired image is locally decomposed as a predicted version of the original gradient, plus a gradient residual. It is assumed that the detail attenuation identifies the detail loss, whereas the gradient residuals describe the spurious details. It turns out that the perceptual impact of detail losses is roughly linear with the loss of the positional Fisher information, while the perceptual impact of the spurious details is roughly proportional to a logarithmic measure of the signal to residual ratio. The affine combination of these two metrics forms a new index strongly correlated with the empirical Differential Mean Opinion Score (DMOS) for a significant class of image impairments, as verified for three independent popular databases. The method allowed alignment and merging of DMOS data coming from these different databases to a common DMOS scale by affine transformations. Unexpectedly, the DMOS scale setting is possible by the analysis of a single image affected by additive noise.Comment: 15 pages, 9 figures. Copyright notice: The paper has been accepted for publication on the IEEE Trans. on Image Processing on 19/09/2017 and the copyright has been transferred to the IEE

Selection of the key earth observation sensors and platforms focusing on applications for Polar Regions in the scope of Copernicus system 2020-2030

An optimal payload selection conducted in the frame of the H2020 ONION project (id 687490) is presented based on the ability to cover the observation needs of the Copernicus system in the time period 2020–2030. Payload selection is constrained by the variables that can be measured, the power consumption, and weight of the instrument, and the required accuracy and spatial resolution (horizontal or vertical). It involved 20 measurements with observation gaps according to the user requirements that were detected in the top 10 use cases in the scope of Copernicus space infrastructure, 9 potential applied technologies, and 39 available commercial platforms. Additional Earth Observation (EO) infrastructures are proposed to reduce measurements gaps, based on a weighting system that assigned high relevance for measurements associated to Marine for Weather Forecast over Polar Regions. This study concludes with a rank and mapping of the potential technologies and the suitable commercial platforms to cover most of the requirements of the top ten use cases, analyzing the Marine for Weather Forecast, Sea Ice Monitoring, Fishing Pressure, and Agriculture and Forestry: Hydric stress as the priority use cases.Peer ReviewedPostprint (published version

Spatial mode storage in a gradient echo memory

Three-level atomic gradient echo memory (lambda-GEM) is a proposed candidate for efficient quantum storage and for linear optical quantum computation with time-bin multiplexing. In this paper we investigate the spatial multimode properties of a lambda-GEM system. Using a high-speed triggered CCD, we demonstrate the storage of complex spatial modes and images. We also present an in-principle demonstration of spatial multiplexing by showing selective recall of spatial elements of a stored spin wave. Using our measurements, we consider the effect of diffusion within the atomic vapour and investigate its role in spatial decoherence. Our measurements allow us to quantify the spatial distortion due to both diffusion and inhomogeneous control field scattering and compare these to theoretical models.Comment: 11 pages, 9 figure

Evaluation of optimised flight trajectories for conventional and novel aircraft and engine integrated systems

Today, the air transport industry has become an essential element of global society by its great contributions to the wide exchanges of cultures/people and to the rapid growth in the world economy. However, on the other hand, the adverse impacts on the environment caused by air transport, such as air pollution, noise and climate change, are drawing, increasingly, growing public concern. In order to address the steady growth in air-travel demand in the next decades through an environmentally-friendly way and realise the ACARE 2020 environmental goals, The Clean Sky programme has been launched by European Union over the period 2008 – 2013. The project research, described in this thesis and sponsored by the Clean Sky programme, aims at evaluating the feasibility of reducing the environmental impact of commercial aviation through the introduction of changes in the aircraft operational rules and procedures, as well as the application of the new-generation propfan (open rotor) engine, based on flight trajectory multidisciplinary optimisation and analysis of commercial aircraft. In order to accomplish the above research objectives, a complete methodology to achieve and realise optimum flight trajectories has been initially proposed. Then, 12 component-level models which function as simulating different disciplines, such as aircraft performance, engine performance, engine gaseous emission, and flight noise, have been developed or selected/adopted. Further, nine system-level integration and optimisation models were built. These system-level models simulate flights from Amsterdam Schiphol airport in the Netherlands to Munich airport in Germany flown by different types of aircraft through different flight phases with different optimisation objectives. Finally, detailed investigations into the flight trajectory optimisations were performed, extensive optimisation results were achieved and corresponding description, analysis and comparisons were provided. The main contributions of this work to knowledge broadly comprise the following: 1) the further development regarding the methodology of flight trajectory multidisciplinary optimisation; 2) previous work on aircraft trajectory optimisation has often considered fixed objectives over the complete flight trajectory. This research focused on representative flight phases of a flight mission with different optimisation objectives, namely, noise impact and fuel burn during the departure phase; fuel burn and flight time during en route phase; and noise impact and NOx emission during the arrival phase; 3) this research has extended the current flight trajectory optimisations to turboprop and propfan equipped aircraft. As a result, a relative complete 2D flight trajectory multidisciplinary optimisation spectrum, spanned by primary commercial aircraft types, primary flight phases and primary optimisation objectives of interest, has been built. Although encouraging progress have been achieved, this project research, as with any other research activity, is also only ‘on the way’ rather than coming to the ‘end’ point. There are still many aspects which can be improved further and there is still much new research and exploration which can be investigated further. All these have also been suggested in this thesis

Assessing the Dissipative Capacity of Particle Impact Dampers Based on their Nonlinear Bandwidth Characteristics

The dissipative capacity as quantified by the nonlinear bandwidth measure of impulsively loaded primary structures (PSs) coupled to particle impact dampers (PIDs) is assessed. The considered PIDs are designed by initially placing different numbers of spherical, linearly viscoelastic granules at different 2D initial topologies and clearances. The strongly nonlinear and highly discontinuous dynamics of the PIDs are simulated via the discrete element method taking Hertzian interactions, slipping friction and granular rotations into account. The general definition of nonlinear bandwidth is used to evaluate the energy dissipation capacity of the integrated PS-PID systems. Moreover, the effect of the dynamics of the PIDs on the time-bandwidth product of these systems is studied, as a measure of their capacity to store or dissipate vibration energy. It is found that the initial topologies of the granules in the PID drastically affect the time-bandwidth product, which, depending on shock intensity, may break the classical limit of unity which holds for linear time-invariant dissipative resonators. The optimal PS-PID systems composed of multiple granules produce large nonlinear bandwidths, indicating strong dissipative capacity of broadband input energy by the PIDs. Additionally, in the optimal configurations, the time-bandwidth product, i.e., the measure of the frequency bandwidth of the input shock that is stored in the PS-PID system, in tandem with the amount of time it takes for the system to dissipate (1/e) of the initial energy, can be tuned either above or below unity by varying the applied shock intensity. The implications of these findings on the dissipative capacity of the system considered are discussed, showing that it can be predictively assessed so that PIDs can act as highly effective nonlinear energy sinks capable of rapid and efficient suppression of vibration induced by shocks

TERA for Rotating Equipment Selection

This thesis looks at creating a multidisciplinary simulation tool for rotating plant equipment selection, specifically gas turbines, for the liquefaction of natural gas (LNG). This is a collaborative project between Shell Global Solutions and Cranfield University in the UK. The TERA LNG tool uses a Techno-economic, Environmental and Risk Analysis (TERA) approach in order to satisfy the multidisciplinary nature of the investigation. The benefits of the tool are to act as an aid to selection, operations and maintenance planning and it also acts as a sensitivity tool for assessing the impact of changes in performance, environmental and financial parameters to the overall economic impact of technology selection. The aim is to not only select technology on the basis of techno-economics but also on the basis of risk analysis. The LNG TERA tool is composed of a number of modules starting with the performance simulation which calculates the thermodynamic conditions in the core of the engine. Next, life estimates of the hot gas path components are made using a mixture of parametric and probabilistic lifing models for the turbine first stage blades, coatings, and combustor liner. This allows for a risk analysis to be conducted before maintenance and economics issues are dealt with. In parallel, emissions estimations are made based on empirical correlations. The modelling exemplifies a methodology which is uniquely applied to this application and there are no studies previous to this which look at so many aspects before making conclusions on plant machinery selection. Comparisons have been done between industrial frame engines based on the General Electric Frame 9E (130 MW) and Frame 7EA (87 MW) engines as well as more complex cycles involving aero-derivation and inter-cooling such as the LM 6000 (42 MW) and LMS 100 (100 MW). Work has also been carried out to integrate the tool to Shell based systems in order to utilise the database of information on failure and maintenance of machinery as well as its performance. The results of the integrated TERA show a clear favour for the aero-derivative engines and the main benefit is the fuel saving, though the life of the hot gas path components is deteriorated much faster. The risk results show that the industrial frame engines have a wider variation in expected life compared to aero-derivatives, though the industrial frames have longer component lives. In the context of maintenance and economics, the aero-derivative engines are better suited to LNG applications. The modular change out design of the aero- derivatives also meant that time to repair was lower, thus reducing lost production. Application of the LNG TERA tool was extended to power generation whereby a series of 6 engines were simulated. The changes required to the modelling were minimal and it shows the flexibility of the TERA philosophy. This study was carried out assuming a given ratio of load split between the engines and hence is sensitive to the way an operator demands power of the engine as opposed to LNG application where the operator tries to drive the engine as hard as possible to get the most production out of the train. The study was limited in the modes of failure which were investigated, a major further work would be to extend the methodology to more components and incorporate fatigue failure. Further, the blade creep and probabilistic coating models were very sensitive to changes in their respective control parameters such as coating thickness allowances and firing temperature. The contribution to the project from the MBA is the statistical techniques used to conduct the risk analysis and data handling as well as financial management techniques such as the Net Present Value (NPV) methodology for project evaluations

Analysis of a 115MW, 3 shaft, helium Brayton cycle

This research theme is originated from a development project that is going on in South Africa, for the design and construction of a closed cycle gas turbine plant using gas-cooled reactor as the heat source to generate 115 MW of electricity. South African Power utility company, Eskom, promotes this developmental work through its subsidiary called PBMR (Pebble Bed Modular Reactor). Some of the attractive features of this plant are the inherent and passive safety features, modular geometry, small evacuation area, small infrastructure requirements for the installation and running of the plant, small construction time, quick starting and stopping and also low operational cost. This exercise is looking at the operational aspects of a closed cycle gas turbine, the finding of which will have a direct input towards the successful development and commissioning of the plant. A thorough understanding of the fluid dynamics in this three-shaft system and its transient performance analysis were the two main objectives of this research work. A computer programme called GTSI, developed by a previous Cranfield University research student, has been used in this as a base programme for the performance analysis. Some modifications were done on this programme to improve its control abilities. The areas covered in the performance analysis are Start-up, Shutdown and Load ramping. A detailed literature survey has been conducted to learn from the helium Turbo machinery experiences, though it is very limited. A critical analysis on the design philosophy of the PBMR is also carried out as part of this research work. The performance analysis has shown the advantage, disadvantage and impact of various power modulation methods suggested for the PBMR. It has tracked the effect of the operations of the various valves included in the PBMR design. The start-up using a hot gas injection has been analysed in detail and a successful start region has been mapped. A start-up procedure is also written based on this. The analysis on the normal and emergency load rejection using various power modulation devices has been done and it stress the importance of more control facilities during full load rejection due to generator faults. A computational fluid dynamics (CFD) analysis, using commercial software, has been carried out on some geometry of the PBMR design to find out whether its flow characteristic will have any serious impact on the performance on the cycle during the load control of the plant. The analysis has demonstrated that there will not be much impact on the performance, during load control using pressure level changes, from this geometry. However, some locations in the geometry have been identified as areas where the flow is experiencing comparatively high pressure losses. Recommendations, which include modification in the physical design, were made to improve this. The CFD analysis has extended to a cascade to compare the flow behaviour of Air and Helium with an objective of using air, being inexpensive, to test the helium flow characteristic in a test rig to simulate the behavioural pattern of helium in the PBMR pressure vessel. The specification of a hypothetical test rig and the necessary scaling parameters has been derived from this exercise. This will be useful for designing test rigs during the developmental and operational stage of the PBMR project