PVDF-TrFE Electroactive Polymer Mechanical-to-Electrical Energy Harvesting Experimental Bimorph Structure

Research of electrostrictive polymers has generated new opportunities for harvesting energy from the surrounding environment and converting it into usable electrical energy. Electroactive polymer (EAP) research is one of the new opportunities for harvesting energy from the natural environment and converting it into usable electrical energy. Piezoelectric ceramic based energy harvesting devices tend to be unsuitable for low-frequency mechanical excitations such as human movement. Organic polymers are typically softer and more flexible therefore translated electrical energy output is considerably higher under the same mechanical force. In addition, cantilever geometry is one of the most used structures in piezoelectric energy harvesters, especially for mechanical energy harvesting from vibrations. In order to further lower the resonance frequency of the cantilever microstructure, a proof mass can be attached to the free end of the cantilever. Mechanical analysis of an experimental bimorph structure was provided and led to key design rules for post-processing steps to control the performance of the energy harvester. In this work, methods of materials processing and the mechanical to electrical conversion of vibrational energy into usable energy were investigated. Materials such as polyvinyledenedifluoridetetra-fluoroethylene P(VDF-TrFE) copolymer films (1um thick or less) were evaluated and presented a large relative permittivity and greater piezoelectric β-phase without stretching. Further investigations will be used to identify suitable micro-electromechanical systems (MEMs) structures given specific types of low-frequency mechanical excitations (10-100Hz)

Electrostrictive Polymers for Mechanical-to-Electrical Energy Harvesting

Research of electrostrictive polymers has generated new opportunities for harvesting energy from the surrounding environment and converting it into usable electrical energy. Piezoelectric ceramic based devices have long been used in energy harvesting for converting mechanical motion to electrical energy. Nevertheless, those materials tend to be unsuitable for low-frequency mechanical excitations such as human movement. Since organic polymers are typically softer and more flexible, the translated electrical energy output is considerably higher under the same mechanical force. Currently, investigations in using electroactive polymers for energy harvesting, and mechanical-to-electrical energy conversion, are beginning to show potential for this application. In this paper we discuss methods of energy harvesting using membrane structures and various methods used to convert it into usable energy. Since polymers are typically used in capacitive energy harvesting designs, the uses of polymer materials with large relative permittivities have demonstrated success for mechanical to electrical energy conversion. Further investigations will be used to identify suitable micro-electro mechanical systems (MEMs) structures given specific types of low-frequency mechanical excitations (10-100Hz)

Piezoelectric/Triboelectric Nanogenerators for Biomedical Applications

Bodily movements can be used to harvest electrical energy via nanogenerators and thereby enable self-powered healthcare devices. In this chapter, first we summarize the requirements of nanogenerators for the applications in biomedical fields. Then, the current applications of nanogenerators in the biomedical field are introduced, including self-powered sensors for monitoring body activities; pacemakers; cochlear implants; stimulators for cells, tissues, and the brain; and degradable electronics. Remaining challenges to be solved in this field and future development directions are then discussed, such as increasing output performance, further miniaturization, encapsulation, and improving stability. Finally, future outlooks for nanogenerators in healthcare electronics are reviewed

Material Processing for Edible Electronics

abstract: A new type of electronics was envisioned, namely edible electronics. Edible electronics are made by Food and Drug Administration (FDA) certified edible materials which can be eaten and digested by human body. Different from implantable electronics, test or treatment using edible electronics doesn’t require operations and perioperative complications. This dissertation bridges the food industry, material sciences, device fabrication, and biomedical engineering by demonstrating edible supercapacitors and electronic components and devices such as pH sensor. Edible supercapacitors were fabricated using food materials from grocery store. 5 of them were connected in series to power a snake camera. Tests result showed that the current generated by supercapacitor have the ability to kill bacteria. Next more food, processed food and non-toxic level electronic materials were investigated. A “preferred food kit” was created for component fabrication based on the investigation. Some edible electronic components, such as wires, resistor, inductor, etc., were developed and characterized utilizing the preferred food kit. These components make it possible to fabricate edible electronic/device in the future work. Some edible electronic components were integrated into an edible electronic system/device. Then edible pH sensor was introduced and fabricated. This edible pH sensor can be swallowed and test pH of gastric fluid. PH can be read in a phone within seconds after the pH sensor was swallowed. As a side project, an edible double network gel electrolyte was synthesized for the edible supercapacitor.Dissertation/ThesisDoctoral Dissertation Chemical Engineering 201

Impressão 3D de sensores flexíveis baseados em polímeros para aplicações biomédicas

Flexible self-powered sensors have great potential in the medical field, offering a means of continuous monitoring of patients, helping to prevent and diagnose diseases. The present work explores biodegradable and low-cost alternatives to produce flexible sensors, from polylactic acid, for biomedical applications. Flexible sensors are composed of 3 main parts: transducers, electrodes, and substrate. In this work, the flexible sensors object of study are constituted by an incapsulating substrate of transparent adhesive tape, electrodes produced by 3D printing of a conductive composite of polylactic acid doped with carbon black and by 2 types of transducers; poly-L-lactic (PLLA) and commercial polylactic acid (PLA) To produce the poly-L-lactic acid (PLLA) and polylactic acid (PLA) transducers, two production methods were used: solvent cast and electrospinning, corona pooling methodology was used to change its electrical state. The response of sensors to mechanical and electrical stimuli was investigated and compared. The results show that both PLA and PLLA work based on the principle of piezoelectricity and triboelectricity and respond to mechanical deformation, the best results were obtained by transducers produced by solvent casting treated by corona pooling.Sensores flexíveis autoalimentados têm grande potencial no campo da medicina, podendo oferecer meios de monotorização continua de pacientes ajudando na prevenção e diagnóstico de doenças. O presente trabalho explora alternativas biodegradáveis e de baixo custo para produção de sensores flexíveis, a partir de ácido poliláctico, destinados a aplicações biomédicas. De uma forma geral os sensores flexíveis são compostos por 3 partes principais: transdutores, elétrodos e substrato, Neste trabalho os sensores flexíveis objeto de estudo são constituídos por um substrato incapsulante de fita cola transparente, elétrodos produzidos por impressão 3D de um compósito condutor de ácido poliláctico dopado com negro de fumo e por 2 tipos de transdutores; poli-L-láctico (PLLA) e ácido poliláctico (PLA). Para produzir os transdutores de ácido poli-L-láctico (PLLA) e ácido poliláctico (PLA) foram usados dois métodos de produção: solvent cast e electrospinnig e recorreu-se à metodologia de corona pooling para alteração do seu estado elétrico. A resposta dos sensores a estímulos mecânicos e elétricos foi investigada e comparada. Os resultados mostram que tanto o PLA quanto o PLLA funcionam com base no princípio da piezoeletricidade e triboeletricidade e respondem a deformação mecânica, os melhores resultados foram obtidos pelos transdutores produzidos por solvent casting tratados por corona pooling.Mestrado em Materiais e Dispositivos Biomédico

A Review on Sustainable Inks for Printed Electronics: Materials for Conductive, Dielectric and Piezoelectric Sustainable Inks

In the last decades, the demand for electronics and, therefore, electronic waste, has increased. To reduce this electronic waste and the impact of this sector on the environment, it is necessary to develop biodegradable systems using naturally produced materials with low impact on the environment or systems that can degrade in a certain period. One way to manufacture these types of systems is by using printed electronics because the inks and the substrates used are sustainable. Printed electronics involve different methods of deposition, such as screen printing or inkjet printing. Depending on the method of deposition selected, the developed inks should have different properties, such as viscosity or solid content. To produce sustainable inks, it is necessary to ensure that most of the materials used in the formulation are biobased, biodegradable, or not considered critical raw materials. In this review, different inks for inkjet printing or screen printing that are considered sustainable, and the materials that can be used to formulate them, are collected. Printed electronics need inks with different functionalities, which can be mainly classified into three groups: conductive, dielectric, or piezoelectric inks. Materials need to be selected depending on the ink’s final purpose. For example, functional materials such as carbon or biobased silver should be used to secure the conductivity of an ink, a material with dielectric properties could be used to develop a dielectric ink, or materials that present piezoelectric properties could be mixed with different binders to develop a piezoelectric ink. A good combination of all the components selected must be achieved to ensure the proper features of each ink.This publication is supported by the SUINK project funded by the European Union’s Horizon Europe research and innovation programme under Grant Agreement No. 101070112. Funded by the Basque Government ELKARTEK2021 (KK-2021/00040) and ELKARTEK2023 KK-2023/0005

Piezoelectric and magnetically responsive biodegradable composites with tailored porous morphology for biotechnological applications

The biomedical area in the scope of tissue regeneration pursues the development of advanced materials that can target biomimetic approaches and, ideally, have an active role in the environment they are placed in. This active role can be related to or driven by morphological, mechanical, electrical, or magnetic stimuli, among others. This work reports on the development of active biomaterials based on poly(3-hydroxybutyric acid-co-3-hydroxyvaleric acid), PHBV, a piezoelectric and biodegradable polymer, for tissue regeneration application by tailoring its morphology and functional response. PHBV films with different porosities were obtained using the solvent casting method, resorting to high-boiling-point solvents, as N,N-dimethylformamide (DMF) and dimethylsulfoxide (DMSO), and the combination of chloroform (CF) and DMF for polymer dissolution. Furthermore, magnetoelectric biomaterials were obtained through the combination of the piezoelectric PHBV with magnetostrictive iron oxide (Fe3O4) nanoparticles. Independently of the morphology or filler content, all biomaterials proved to be suitable for biomedical applications.This work was supported by national funds through the Fundação para a Ciência e Tecnologia (FCT) and by ERDF through COMPETE2020 - Programa Operacional Competitividade e Internacionalização (POCI) in the framework of the Strategic Programs UID/FIS/04650/2020, and project PTDC/BTM-MAT/28237/2017. TMA thank FCT for the research grant: SFRH/BD/141136/2018, VC for the junior researcher contract (DL57/2016) and CR for the contract under the Stimulus of Scientific Employment, Individual Support (CEECIND) – 3 rd Edition (2020.04163.CEECIND). Finally, the authors acknowledge funding by Spanish State Research Agency (AEI) and the European Regional Development Fund (ERFD) through the project PID2019-106099RBC43/AEI/10.13039/501100011033 and from the Basque Government Industry Departments under the ELKARTEK program

Research progress of flexible wearable stress sensor

Flexible wearable pressure sensors are widely used in health diagnosis, sports monitoring, rehabilitation medicine, entertainment, and other fields due to some factors such as the stretch ability, bendability, light weight, portability, and excellent electrical properties. In recent years, significant progress has been made in flexible pressure sensors, and a variety of flexible pressure sensors that able to measure health status have been applied to the pulse wave, movement, respiration, and electrocardiogram (ECG) detection. However, there are still many problems to be solved in the development of flexible pressure sensors. This article summarizes the development of flexible pressure sensors in recent years, from the working principle to the structural design of the flexible pressure sensors; designs to build a high-performance flexible pressure sensors; discusses the problems existing in current flexible pressure sensors and envisions the development trend of flexible pressure sensors in the future. Flexible pressure sensors with excellent flexibility, good biocompatibility, rapid response, high sensitivity, and multifunctional integration have shown a broad application prospects

Fabrication and studying the dielectric properties of (polystyrene-copper oxide) nanocomposites for piezoelectric application

The preparation of (polystyrene-copper oxide) nanocomposites have been investigated for piezoelectric application. The copper oxide nanoparticles were added to polystyrene by different concentrations are (0, 4, 8 and 12) wt.%. The structural and A.C electrical properties of (PS-CuO) nanocomposites were studied.The results showed that the dielectric constant and dielectric loss of (PS-CuO) nanocomposites decrease with increase in frequency. The A.C electrical conductivity increases with increase in frequency. The dielectric constant, dielectric loss and A.C electrical conductivity of polystyrene increase with increase in copper oxide nanoparticles concentrations. The results of piezoelectric application showed that the electrical resistance of (PS-CuO) nanocomposites decreases with increase in pressure

Bioresorbable Materials on the Rise: From Electronic Components and Physical Sensors to In Vivo Monitoring Systems

Over the last decade, scientists have dreamed about the development of a bioresorbable technology that exploits a new class of electrical, optical, and sensing components able to operate in physiological conditions for a prescribed time and then disappear, being made of materials that fully dissolve in vivo with biologically benign byproducts upon external stimulation. The final goal is to engineer these components into transient implantable systems that directly interact with organs, tissues, and biofluids in real-time, retrieve clinical parameters, and provide therapeutic actions tailored to the disease and patient clinical evolution, and then biodegrade without the need for device-retrieving surgery that may cause tissue lesion or infection. Here, the major results achieved in bioresorbable technology are critically reviewed, with a bottom-up approach that starts from a rational analysis of dissolution chemistry and kinetics, and biocompatibility of bioresorbable materials, then moves to in vivo performance and stability of electrical and optical bioresorbable components, and eventually focuses on the integration of such components into bioresorbable systems for clinically relevant applications. Finally, the technology readiness levels (TRLs) achieved for the different bioresorbable devices and systems are assessed, hence the open challenges are analyzed and future directions for advancing the technology are envisaged