Technical and economic analysis of the reconversion of an existing biogas plant to biomethane production: a case study.

The paper deals with the technical and economic analysis of a project aimed at transforming an existing plant, used for the anaerobic digestion of zoo-technical and agroforest biomass and including a CHP system of about 1 MW of electric capacity, into a facility producing bio-methane for automotive and/or stationary power applications. A comparison of different biogas upgrading technologies is performed, aimed at selecting the technology most appropriate to the size and typology of application under evaluation. Similarly, an analysis is performed to evaluate the opportunity of installing a bio-methane liquefaction facility, to simplify the management and transportation of the fuel, to be used in vehicles. The economic analysis is performed by considering the incentives presently available in Italy for bio-methane producers. Different scenarios are analyzed and discussed, and it was concluded that the conversion of the existing plant into a facility to produce bio-methane to be liquified and sold as fuel for vehicles represents at this moment a very attractive and profitable option

Recent achievements in the production of biogas from microalgae

The final publication is available at Springer via http://dx.doi.org/10.1007/s12649-016-9604-3Microalgae are nowadays regarded as a potential biomass feedstock to help reducing our dependence on fossil fuels for transportation, electricity and heat generation. Besides, microalgae have been widely investigated as a source of chemicals, cosmetics and health products, as well as animal and human feed. Among the cutting-edge applications of microalgae biomass, anaerobic digestion has shown promising results in terms of (bio)methane production. The interest of this process lies on its potential integration within the microalgae biorefinery concept, providing on the one hand a source of bioenergy, and on the other hand nutrients (nitrogen, phosphorus and CO2) and water for microalgae cultivation. This article reports the main findings in the field, highlighting the options to increase the (bio)methane production of microalgae (i.e. pretreatment and co-digestion) and bottlenecks of the technology. Finally, energy, economic and environmental aspects are considered.Peer ReviewedPostprint (author's final draft

Prospects of microalgal biodiesel production in Pakistan – a review

Biodiesel is an alternative, renewable, biodegradable and environmentally friendly fuel for transportation, with properties like petroleum-derived diesel, and can be used directly in a compression ignition engine without any modifications. The world's fossil fuel and crude oil reserves are going to dry up in the next few decades, but, contrariwise, an attractive, high quality, readily available and economically extractable oil from microalgae is a substitute feedstock to produce alternative biodiesel fuel for the transportation sector in the future. Microalgae have a higher biomass productivity (tons/hectare/year) and lipid yield (kg/kg of algal biomass) as compared to vegetable oil crops. To overcome the problem of energy deficiency in developing countries, like Pakistan, and boost their economic growth, alternative fuels are proving very important for environment-friendly and sustainable development, especially in the last few decades. Different research studies on microalgae cultivation, characterization of microalgae oil (lipids), and evaluations of its socio-economic feasibility to produce renewable biodiesel have been conducted in the past in Pakistan for its future prospects. This review paper includes the overall summary and compilation of the microalgae research conducted in Pakistan on biodiesel production and includes the algal biodiesel production cost analysis. The studies showed promising results for harnessing microalgae and using its lipids to produce biodiesel with favourable properties that were comparable to the conventional diesel in Pakistan. The information related to the microalgae research will help stakeholders and governmental organisations working in the renewable energy sector to consider its cultivation on a large scale, using waste water as a feedstock to produce biodiesel to meet the target set by the Government of Pakistan of using 10% blended biodiesel by the year 2025 in Pakistan

Upgrading biogas with novel composite carbon molecular sieve (CCMS) membranes: Experimental and techno-economic assessment

The use of biogas as feedstock for hydrogen production was widely proposed in the literature in the last years as a strategy to reduce anthropogenic carbon emissions. However, its lower heating value compared to natural gas hampers the revamping of existing reforming plants. The use of composite carbon molecular sieve membranes for biogas upgrading (CO2 removal from biogas) was investigated experimentally in this work. In particular, ideal perm-selectivities and permeabilities above the Robeson plot for CO2/CH4 mixtures have been obtained. These membranes show better performances compared to polymeric membranes, which are nowadays commercialized for CO2 separation in natural gas streams. Compared to polymeric membranes, carbon membranes do not show deactivation by plasticization when exposed to CO2, and thus can find industrial application. This work was extended with a techno-economic analysis where carbon membranes are installed in a steam methane reforming plant. Results have been first validated with data from literature and show that the use of biogas increases the costs of hydrogen production to a value of 0.25 €/Nm3 compared to the benchmark technology (0.21 €/Nm3). On the other hand, the use of biogas leads to a decrease in carbon emissions up to 95%, thus the use of biogas for hydrogen production is foreseen as a very interesting alternative to conventional technologies in view of the reduction in the carbon footprint in the novel technologies that are to be installed in the near future

Optimal Technology Selection and Operation of Bio-methane CHP Units for Commercial Buildings

This paper explores the optimal implementation of bio-methane fuelled combined heat and power (CHP) systems to satisfy heat and electricity demands of commercial buildings; with the overarching goal of making cost-effective investments and decarbonizing building operations. The research work consisted in the development of a CHP technology selection and operation (TSO) optimization model. Its results can be utilized to develop a strategy for investment in bio-methane CHP projects for a portfolio of buildings. The TSO model enables a new approach for the selection and operation of CHP units that encompasses whole life costing, carbon emissions as well as real-time energy prices and demands, providing a more comprehensive result than current methods. Utilizing historic metered energy demands, projected energy prices and a portfolio of available CHP technologies, the mathematical model simultaneously solves for an optimal CHP unit selection and operational strategy for a determined building based on a preferred objective: minimizing cost, minimizing GHG emissions, or a mix of both. Results of this model prove that attractive cost and emissions savings are possible through the optimal selection and operation of CHP technologies fuelled by bio-methan

Biofuel as an alternative shipping fuel : technological, environmental and economic assessment

© Royal Society of Chemistry 2019Fossil derived fuels available for application within the maritime sector have been dominated by heavy fuel oil (HFO), which is conventionally used in low speed (main) engines, and more refined fuels such as marine diesel oil (MDO), which is consumed in fast or medium speed engines. However, increasing fuel costs and regulatory pressure such as the restrictions placed on sulphur content have increased interest in the use of alternative fuels. A number of alternative fuels have been identified and may be viable for use within the maritime sector including straight vegetable oil (SVO) as an alternative to HFO in low speed engines, biodiesel to replace MDO/MGO in low to medium speed engines and bio-liquefied natural gas (bio-LNG) in gas engines using LNG. The potential sources of biomass feedstocks, conversion pathways and technologies are identified. The key parameters limiting their potential application are examined, in particular, availability, technological development, technical integration, and operational consequences. A proposed solution to overcome these limitations is recommended. The effective implementation of these strategies will enable the more widespread use of biofuels in marine applications, significantly reducing emissions from ships and improving global air quality and also protecting the ecological environment.Peer reviewe

Evaluation of maize and hemp cultivars as bioenergy crop

We are cultivating annual and perennial crops as monoculture and as mixed culture to investigate plant biomass use for production of renewable energy sources in northern latitudes. We have grown different hemp (Cannabis sativa L.) and bioenergy maize (Zea mays L.) cultivars in 2007-2009 at Viikki Experimental Farm, University of Helsinki

Integrating microalgae production with anaerobic digestion: a biorefinery approach

This is the peer reviewed version of the following article: [Uggetti, E. , Sialve, B. , Trably, E. and Steyer, J. (2014), Integrating microalgae production with anaerobic digestion: a biorefinery approach. Biofuels, Bioprod. Bioref, 8: 516-529. doi:10.1002/bbb.1469], which has been published in final form at https://doi.org/10.1002/bbb.1469. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-ArchivingIn the energy and chemical sectors, alternative production chains should be considered in order to simultaneously reduce the dependence on oil and mitigate climate change. Biomass is probably the only viable alternative to fossil resources for production of liquid transportation fuels and chemicals since, besides fossils, it is one of the only available sources of carbon-rich material on Earth. Over recent years, interest in microalgae biomass has grown in both fundamental and applied research fields. The biorefinery concept includes different technologies able to convert biomass into added-value chemicals, products (food and feed) and biofuels (biodiesel, bioethanol, biohydrogen). As in oil refinery, a biorefinery aims at producing multiple products, maximizing the value derived from differences in biomass components, including microalgae. This paper provides an overview of the various microalgae-derived products, focusing on anaerobic digestion for conversion of microalgal biomass into methane. Special attention is paid to the range of possible inputs for anaerobic digestion (microalgal biomass and microalgal residue after lipid extraction) and the outputs resulting from the process (e.g. biogas and digestate). The strong interest in microalgae anaerobic digestion lies in its ability to mineralize microalgae containing organic nitrogen and phosphorus, resulting in a flux of ammonium and phosphate that can then be used as substrate for growing microalgae or that can be further processed to produce fertilizers. At present, anaerobic digestion outputs can provide nutrients, CO2 and water to cultivate microalgae, which in turn, are used as substrate for methane and fertilizer generation.Peer ReviewedPostprint (author's final draft