Large-area flexible electronics based on low-temperature solution-processed oxide semiconductors

Due to their high charge carrier mobility, optical transparency and mechanical flexibility, thin-film transistors (TFTs) based on metal oxide semiconductors represent an emerging technology that offers the potential to revolutionise the next-generations of large-area electronics. This thesis focuses on the development of high-performance TFTs based on low-temperature, solution-processed metal oxide semiconductors that are compatible with inexpensive flexible plastic substrates. The first part of the dissertation describes an ultraviolet light assisted processing method suitable for room-temperature activation of ZnO nanoparticles and their application as semiconducting channels in TFTs. The impact of the semiconductor/dielectric interface on electrical performance is studied using different device configurations and dielectric surface-passivation methods. Furthermore, a nanocomposite concept is proposed in order to assist electron transport between different crystalline domains. Using this approach, TFTs with electron mobilities of ~3 cm2/Vs are demonstrated. The second part of this work explores a carbon-free, aqueous-based Zn-ammine complex route for the synthesis of polycrystalline ZnO thin-films at low temperature and their subsequent use in TFTs. Concurrently, the development of a complementary high-κ oxide dielectric system enables the demonstration of high-performance ZnO TFTs with electron mobilities >10 cm2/Vs and operation voltage down to ~1.2 V. This low-temperature aqueous chemistry is further explored using a facile n-type doping approach. Enhancement in electrical performance is attributed to the different crystallographic properties of the Al-doped ZnO layers. The final part of the thesis introduces a novel TFT concept that exploits the enhanced electron transport properties of low-dimensional polycrystalline quasi-superlattices (QSLs), consisting of sequentially spin-cast layers of In2O3, Ga2O3 and ZnO deposited at temperatures 40 cm2/Vs - an order of magnitude higher than devices based on single binary oxide layers. Based on temperature dependent electron transport and capacitance-voltage measurements, it is reasoned that the enhanced electrical performance arises from the presence of quasi two-dimensional electron gas-like systems formed at the carefully engineered oxide heterointerfaces buried within the QSLs.Open Acces

Virtual Integration Platforms (VIP) –A Concept for Integrated and Interdisciplinary Air Transportation Research and Assessment

The paper descibes a new methodology for a holistic development of air transportation concepts. The Virtual Integration Plattform (VIP) concept is based on an IT tool chain as well as human collaborative methods to deal with complex systems. As a result the definitions of future air transportation concepts for short range "Quiet and Clean", long range "Comfortable and Clean" and individual transport "Fast and Flexible" are presente

Photo-FETs: phototransistors enabled by 2D and 0D nanomaterials

The large diversity of applications in our daily lives that rely on photodetection technology requires photodetectors with distinct properties. The choice of an adequate photodetecting system depends on its application, where aspects such as spectral selectivity, speed, and sensitivity play a critical role. High-sensitivity photodetection covering a large spectral range from the UV to IR is dominated by photodiodes. To overcome existing limitations in sensitivity and cost of state-of-the-art systems, new device architectures and material systems are needed with low-cost fabrication and high performance. Low-dimensional nanomaterials (0D, 1D, 2D) are promising candidates with many unique electrical and optical properties and additional functionalities such as flexibility and transparency. In this Perspective, the physical mechanism of photo-FETs (field-effect transistors) is described and recent advances in the field of low-dimensional photo-FETs and hybrids thereof are discussed. Several requirements for the channel material are addressed in view of the photon absorption and carrier transport process, and a fundamental trade-off between them is pointed out for single-material-based devices. We further clarify how hybrid devices, consisting of an ultrathin channel sensitized with strongly absorbing semiconductors, can circumvent these limitations and lead to a new generation of highly sensitive photodetectors. Recent advances in the development of sensitized low-dimensional photo-FETs are discussed, and several promising future directions for their application in high-sensitivity photodetection are proposed.Peer ReviewedPostprint (author's final draft

Why do demand responsive transport systems fail?

In developed countries, Demand Responsive Transport (DRT) (loosely termed 'paratransit' in US parlance) emerged in the 1970s to serve the specialist niche market of people with mobility difficulties. DRT systems are starting become a mainstream public transport mode and this paper examines mainstream public transport DRT schemes from around the world that have failed, in order to identify the reasons for failure, and draw lessons to help prevent similar outcomes occurring. Research for the Intermode study developed detailed cases of 72 DRT projects. A number of key failed cases are reported together with a note of the lessons that each provides. This is followed by a generic analysis of failure factors based on a marketing approach. It is concluded that DRT projects are often not realistically costed or designed with a full understanding of the market they are to serve. There is a very dangerous temptation to offer too flexible a service and to include costly technological systems, when they may not be needed. An incremental approach, if possible, appears sensible. DRT also requires more marketing effort and skills than is traditional in conventional bus operations, but above all, it requires new skills in working in partnership. It is concluded that the latter area is where the root of DRT failure is often to be found

Sustainable seabed mining: guidelines and a new concept for Atlantis II Deep

The feasibility of exploiting seabed resources is subject to the engineering solutions, and economic prospects. Due to rising metal prices, predicted mineral scarcities and unequal allocations of resources in the world, vast research programmes on the exploration and exploitation of seabed minerals are presented in 1970s. Very few studies have been published after the 1980s, when predictions were not fulfilled. The attention grew back in the last decade with marine mineral mining being in research and commercial focus again and the first seabed mining license for massive sulphides being granted in Papua New Guinea’s Exclusive Economic Zone.Research on seabed exploitation and seabed mining is a complex transdisciplinary field that demands for further attention and development. Since the field links engineering, economics, environmental, legal and supply chain research, it demands for research from a systems point of view. This implies the application of a holistic sustainability framework of to analyse the feasibility of engineering systems. The research at hand aims to close this gap by developing such a framework and providing a review of seabed resources. Based on this review it identifies a significant potential for massive sulphides in inactive hydrothermal vents and sediments to solve global resource scarcities. The research aims to provide background on seabed exploitation and to apply a holistic systems engineering approach to develop general guidelines for sustainable seabed mining of polymetallic sulphides and a new concept and solutions for the Atlantis II Deep deposit in the Red Sea.The research methodology will start with acquiring a broader academic and industrial view on sustainable seabed mining through an online survey and expert interviews on seabed mining. In addition, the Nautilus Minerals case is reviewed for lessons learned and identification of challenges. Thereafter, a new concept for Atlantis II Deep is developed that based on a site specific assessment.The research undertaken in this study provides a new perspective regarding sustainable seabed mining. The main contributions of this research are the development of extensive guidelines for key issues in sustainable seabed mining as well as a new concept for seabed mining involving engineering systems, environmental risk mitigation, economic feasibility, logistics and legal aspects

Modular System for Shelves and Coasts (MOSSCO v1.0) - a flexible and multi-component framework for coupled coastal ocean ecosystem modelling

Shelf and coastal sea processes extend from the atmosphere through the water column and into the sea bed. These processes are driven by physical, chemical, and biological interactions at local scales, and they are influenced by transport and cross strong spatial gradients. The linkages between domains and many different processes are not adequately described in current model systems. Their limited integration level in part reflects lacking modularity and flexibility; this shortcoming hinders the exchange of data and model components and has historically imposed supremacy of specific physical driver models. We here present the Modular System for Shelves and Coasts (MOSSCO, http://www.mossco.de), a novel domain and process coupling system tailored---but not limited--- to the coupling challenges of and applications in the coastal ocean. MOSSCO builds on the existing coupling technology Earth System Modeling Framework and on the Framework for Aquatic Biogeochemical Models, thereby creating a unique level of modularity in both domain and process coupling; the new framework adds rich metadata, flexible scheduling, configurations that allow several tens of models to be coupled, and tested setups for coastal coupled applications. That way, MOSSCO addresses the technology needs of a growing marine coastal Earth System community that encompasses very different disciplines, numerical tools, and research questions.Comment: 30 pages, 6 figures, submitted to Geoscientific Model Development Discussion