Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands
Abstract
N-Silylated benzoxazolin-2-one reacts with N−H and C−H acidic heterocycles (benzoxazolinone, 3,5-dimethylpyrazole, N-methylimidazole) under benzoxazolinone ring cleavage and formation of ortho-siloxyphenyl-substituted ureas and carbamides, respectively. These products were shown to serve as sources for tridentate (O′NO) and (N′NO) chelating ligands- Dataset
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- Biophysics
- Biochemistry
- Microbiology
- Molecular Biology
- Pharmacology
- Biotechnology
- Evolutionary Biology
- Immunology
- Computational Biology
- Chemical Sciences not elsewhere classified
- Benzoxazolinone
- tridentate
- ligand
- source
- Convenient Route
- acidic
- chelating
- urea
- heterocycle
- Carbamido
- formation
- carbamide
- Chelating Ureato
- benzoxazolinone ring cleavage
- dimethylpyrazole
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Last time updated on 16/03/2018
This paper was published in The Francis Crick Institute.
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