textjournal article
Synthesis of Molybdenum Alkylidene Complexes That Contain the 2,6-Dimesitylphenylimido Ligand
Abstract
Compounds that have the formula M(NR)(CHR′)(OR″)(Pyrrolide), where OR″ is “large” relative to NR and M = Mo or W, have been shown to be Z-selective olefin metathesis catalysts. In this communication we report a new route to Mo complexes in which the relationship between NR and OR″ has been reversed; i.e., the imido ligand is the sterically demanding 2,6-dimesitylphenylimido ligand (NAr*)- Text
- Journal contribution
- Biophysics
- Biochemistry
- Cell Biology
- Molecular Biology
- Pharmacology
- Biotechnology
- Marine Biology
- Biological Sciences not elsewhere classified
- Chemical Sciences not elsewhere classified
- Information Systems not elsewhere classified
- sterically
- communication
- Mo complexes
- metathesi
- imido ligand
- relationship
- NAr
- dimesitylphenylimido
- Molybdenum Alkylidene Complexes
- formula
- NR
- Synthesi
- olefin
- catalyst
- Contain
- i.e
- Dimesitylphenylimido
- LigandCompound
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Last time updated on 16/03/2018
This paper was published in The Francis Crick Institute.
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