Donor–Acceptor Segregated Paracyclophanes Composed of Naphthobipyrrole and Stacked Fluoroarenes
Abstract
The expeditious synthesis of donor–acceptor segregated paracyclophanes has been achieved by a selective S<sub>N</sub>Ar reaction of hexafluorobenzene with <i>o</i>-dipyrrolylbenzenes and subsequent cyclodehydrogenation. An orthogonally arranged D–A segregated structure was confirmed by X-ray crystallography. The combined results of DFT calculations and absorption spectra revealed the charge transfer (CT) nature from the naphthobipyrrole (donor) to the stacked fluoroarene moiety (acceptor)- Dataset
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- Biophysics
- Biochemistry
- Medicine
- Cell Biology
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- Physical Sciences not elsewhere classified
- fluoroarene moiety
- Stacked FluoroarenesThe
- naphthobipyrrole
- Donor
- cyclodehydrogenation
- crystallography
- DFT calculations
- acceptor
- Paracyclophane
- donor
- synthesis
- charge transfer
- Segregated
- nature
- absorption spectra
- paracyclophane
- orthogonally
- CT
- Composed
- SNAr reaction
- hexafluorobenzene
- Naphthobipyrrole
Similar works
This paper was published in FigShare.
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