996 research outputs found
Statistical switching kinetics in ferroelectrics
By assuming a more realistic nucleation and polarization reversal scenario we
build a new statistical switching model for ferroelectrics, which is different
from either the Kolmogorov-Avrami-Ishibashi (KAI) model or the
Nucleation-Limited-Switching (NLS) model. After incorporating a time-dependent
depolarization field this model gives a good description about the retardation
behavior in polycrystalline thin films at medium or low fields, which can not
be described by the traditional KAI model. This model predicts correctly n=1
for polycrystalline thin films at high Eappl or ceramic bulks in the ideal
case
Resistive Switching in Memristive Electrochemical Metallization Devices
We report on resistive switching of memristive electrochemical metallization
devices using 3D kinetic Monte Carlo simulations describing the transport of
ions through a solid state electrolyte of an Ag/TiO/Pt thin layer
system. The ion transport model is consistently coupled with solvers for the
electric field and thermal diffusion. We show that the model is able to
describe not only the formation of conducting filaments but also its
dissolution. Furthermore, we calculate realistic current-voltage
characteristics and resistive switching kinetics. Finally, we discuss in detail
the influence of both the electric field and the local heat on the switching
processes of the device
Polarization switching at the nanoscale in ferroelectric copolymer thin films
The polarization switching kinetics were measured at the nanoscale in continuous thin films of a ferroelectric copolymer of vinylidene fluoride and trifluoroethylene. The dependence of the switching rate on voltage for a 54-nm thick film exhibits extrinsic nucleation and domain-growth type kinetics with no true threshold coercive field, and is qualitatively different from the behavior of an 18-nm thick film, which exhibits intrinsic switching kinetics, and a true threshold field. The results are consistent with studies of thin film capacitors of much larger area and with a recent refinement of the theory of the critical size for intrinsic switching
Unifying thermodynamic and kinetic descriptions of single-molecule processes: RNA unfolding under tension
We use mesoscopic non-equilibrium thermodynamics theory to describe RNA
unfolding under tension. The theory introduces reaction coordinates,
characterizing a continuum of states for each bond in the molecule. The
unfolding considered is so slow that one can assume local equilibrium in the
space of the reaction coordinates. In the quasi-stationary limit of high
sequential barriers, our theory yields the master equation of a recently
proposed sequential-step model. Non-linear switching kinetics is found between
open and closed states. Our theory unifies the thermodynamic and kinetic
descriptions and offers a systematic procedure to characterize the dynamics of
the unfolding processComment: 13 pages, 3 figure
Switching kinetics of ferroelectric polymer nanomesas
The switching dynamics and switching time of ferroelectric nanomesas grown from the paraelectric phase of ultrathin Langmuir–Blodgett vinylidene fluoride and trifluoroethylene copolymer films are investigated. Ferroelectric nanomesas are created through heat treatment and self-organization and have an average height of 10 nm and an average diameter of 100 nm. Ferroelectric nanomesas are highly crystalline and are in the ferroelectric phase and switch faster than 50 μs. The dependence of switching time on applied voltage implies an extrinsic switching nature
Switching kinetics of ferroelectric polymer nanomesas
The switching dynamics and switching time of ferroelectric nanomesas grown from the paraelectric phase of ultrathin Langmuir–Blodgett vinylidene fluoride and trifluoroethylene copolymer films are investigated. Ferroelectric nanomesas are created through heat treatment and self-organization and have an average height of 10 nm and an average diameter of 100 nm. Ferroelectric nanomesas are highly crystalline and are in the ferroelectric phase and switch faster than 50 μs. The dependence of switching time on applied voltage implies an extrinsic switching nature
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