CO2 dissolution in formation water as dominant sink in natural gas fields

A primary concern facing Carbon Capture and Storage (CCS) technology is the proven ability to safely store and monitor injected CO2 in geological formations on a long-term basis. However, it is extremely challenging to assess the long-term consequences of CO2 injection into the subsurface from decadal observations of existing CO2 disposal sites.Noble gases are conservative tracers within the subsurface, and combined with carbon stable isotopes, have proved to be extremely useful in determining both the origin of CO2 and how the CO2 is stored within natural CO2 reservoirs from around the world [1,2]. This presentation will identify and quantify the principal mechanism of CO2 phase removal in nine natural gas fields in North America, China and Europe. These natural gas fields are dominated by a CO2 phase and provide a natural analogue for assessing the geological storage of CO2 over millennial timescales. Our study highlights that in seven gas fields with siliciclastic or carbonate-dominated reservoir lithologies, dissolution in formation water at a pH of 5–5.8 is the major sink for CO2 [2]. This pH range is obtained by modelling the carbon isotope fractionation that results from dissolution of CO2(g) to varying proportions of H2CO3(aq) and HCO3-(aq). This is a major breakthrough as accurate subsurface pH measurements are notoriously difficult to obtain. In two fields with siliciclastic reservoir lithologies, some CO2 loss through precipitation as carbonate minerals cannot be ruled out, but this is minor compared to the amount of CO2 lost to dissolution in the formation water within the same fields.Our findings imply mineral fixation is a minor CO2 trapping mechanism within natural reservoirs and hence suggests long-term models of geological CO2 storage should consider the potential mobility of CO2 dissolved in water.[1] Gilfillan et al., (2008) GCA 72, 1174-1198.[2] Gilfillan et al., (2009) Nature, doi:10.1038/nature07852<br/

Spatial and Temporal Variations in Active Layer Thawing and Their Implication on Runoff Generation in Peat-Covered Permafrost Terrain

The distribution of frost table depths on a peat-covered permafrost slope was examined in a discontinuous permafrost region in northern Canada over 4 consecutive years at a variety of spatial scales, to elucidate the role of active layer development on runoff generation. Frost table depths were highly variable over relatively short distances (0.25–1 m), and the spatial variability was strongly correlated to soil moisture distribution, which was partly influenced by lateral flow converging to frost table depressions. On an interannual basis, thaw rates were temporally correlated to air temperature and the amount of precipitation input. Simple simulations show that lateral subsurface flow is governed by the frost table topography having spatially variable storage that has to be filled before water can spill over to generate flow downslope, in a similar manner that bedrock topography controls subsurface flow. However, unlike the bedrock surface, the frost table is variable with time and strongly influenced by the heat transfer involving water. Therefore, it is important to understand the feedback between thawing and subsurface water flow and to properly represent the feedback in hydrological models of permafrost regions

Variability of in‐stream and riparian storage in a beaded arctic stream

The extent and variability of water storage and residence times throughout the open water season in beaded arctic streams are poorly understood. Data collected in Imnavait Creek, a beaded stream located north of the Brooks Range in Alaska, were used to better understand the effects of in‐pool and riparian storage on heat and mass movement through beaded streams. Temperature data of high spatial resolution within the pools and surrounding sediments were used with volumetric discharge and electrical conductivity to identify storage areas within the pools, banks, and other marshy areas within the riparian zone, including subsurface flow paths that connect the pools. These subsurface flows were found to alter water conductivity and the character of dissolved organic matter (DOM) in short reaches (10 s of m) while influencing the chemistry of downstream pools. During low flow periods, persistent stratification occurred within the pools due to absorption of solar radiation by DOM coupled with permafrost below and low wind stress at the pool surface. Additionally, one of the shallow pools (<0.5 m depth) remained stratified during higher flow periods and lower radiation inputs due to dense subsurface flows entering the bottom of the pools. This consistent separation of surface and bottom water masses in each pool will increase the travel times through this and similar arctic watersheds, and therefore will affect the evolution of water chemistry and material export. Copyright © 2011 John Wiley & Sons, Ltd.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/93522/1/hyp8323.pd

Evapotranspiration Mapping for Forest Management in California's Sierra Nevada

We assessed the response of densely forested watersheds with little apparent annual water limitation to forest disturbance and climate variability, by studying how past wildfires changed forest evapotranspiration, and what past evapotranspiration patterns imply for the availability of subsurface water storage for drought resistance. We determined annual spatial patterns of evapotranspiration using a top-down statistical model, correlating measured annual evapotranspiration from eddycovariance towers across California with NDVI (Normalized Difference Vegetation Index) measured by satellite, and with annual precipitation. The study area was the Yuba and American River watersheds, two densely forested watersheds in the northern Sierra Nevada. Wildfires in the 1985-2015 period resulted in significant post-fire reductions in evapotranspiration for at least 5 years, and in some cases for more than 20 years. The levels of biomass removed in medium-intensity fires (25- 75% basal area loss), similar to magnitudes expected from forest treatments for fuels reduction and forest health, reduced evapotranspiration by as much 150-200 mm yr-1 for the first 5 years. Rates of recovery in post-wildfire evapotranspiration confirm the need for follow-up forest treatments at intervals of 5-20 years to sustain lower evapotranspiration, depending on local landscape attributes and interannual climate. Using the metric of cumulative precipitation minus evapotranspiration (P-ET) during multi-year dry periods, we found that forests in the study area showed little evidence of moisture stress during the 1985-2018 period of our analysis, owing to relatively small reliance on interannual subsurface water storage to meet dry-year evapotranspiration needs of vegetation. However, more-severe or sustained drought periods will push some lower-elevation forests in the area studied toward the cumulative P-ET thresholds previously associated with widespread forest mortality in the southern Sierra Nevada

The Performance Analysis of Two Relatively Small Capacity Urban Retrofit Stormwater Controls

This paper details field investigations that were conducted on the performance of small capacity urban retrofit stormwater control measures. The objective of the two year study (2013–2015) was to provide performance data on stormwater retrofits that could not be fully sized according to conventional standards due to space constraints. In many states performance credits are not granted to stormwater management controls that are not designed to manage regionally derived water quality volumes. In retrofit applications there may exist numerous limitations to conventionally sized systems such as limited rights of way, setback distances or existing utilities. The larger scale objective of green infrastructure implementation is to improve receiving water quality and therefore even undersized systems, to some extent, meet this objective. This study introduces data on two systems: an innovative bioretention design with a water treatment residual amended filter media and an internal storage reservoir; and an undersized linear subsurface gravel wetland sized to optimize both phosphorus and nitrogen removal. The systems were retrofitted into existing developed areas and were sized at less than the water quality volume due to limited space at each location. The bioretention system (IBSC) was constructed in a commercial area in the town of Durham, NH in summer 2011 and the subsurface gravel wetland system (SGWSC) was constructed in a narrow drainage right of way in a residential neighbourhood of Durham, NH in the fall of 2013. Sediment and metal removals for both undersized systems were high with median removal efficiencies in the SGW of 75% for both total suspended solids (TSS) and total zinc (TZn). The Durham IBSC recorded median removal efficiency (RE) of 86% for TSS and TZn. Total phosphorus (TP) REs were higher than conventional bioretention systems with the subsurface gravel wetland system achieving a median RE of 53% and the Durham IBSC achieving a median RE of 40% for TP. Both systems reduced total nitrogen (TN) by approximately 20% (23% for SGWSC and 21% for Durham IBSC) with median effluent concentrations of 1.4 mg/L. This project was funded by the U.S. Environmental Protection Agency Region 1, Regional Applied Research Effort (RARE) Program. Additional information can be found in the full project report Performance Analysis of Two Relatively Small Capacity Urban Retrofit Stormwater Controls (Houle et al. 2015)