The Effect of Cure Rate on Glassy Polymer Networks

The formation of glassy polymer networks such as epoxy-amine systems may be altered by varying the temperature ramp rate that is used to cure the system. As a result, the physical and mechanical properties of the network may be changed. This work synthesized the epoxy resins diglycidyl ether of bisphenol A (DGEBA) with the amine curing agent 4,4-diaminodiphenyl sulfone (4,4’-DDS) from 35°C to 180°C using varying temperature ramp rates. Mechanical and structural properties of these samples were then analyzed to determine the effect the different temperature ramp rates had on the formation and properties of the thermoset matrix. These aspects were analyzed using Dynamic Mechanical Analysis (DMA), Differential Scanning Calorimetry (DSC) and real-time Fourier Transform Near-Inferred (NIR) Spectroscopy. It was found that higher temperature ramp rates during the cure cause the epoxide function groups to be consumed more rapidly. Also, these faster rates create materials that are less homogenized and have a lower glass transition temperature

Molecular Scale Cure Rate Dependence of Thermoset Matrix Polymers

This manuscript demonstrates the molecular scale cure rate dependence of di-functional epoxide based thermoset polymers cured with amines. A series of cure heating ramp rates were used to determine the influence of ramp rate on the glass transition temperature (Tg) and sub-Tg transitions and the average free volume hole size in these systems. The networks were comprised of 3,3′-diaminodiphenyl sulfone (33DDS) and diglycidyl ether of bisphenol F (DGEBF) and were cured at ramp rates ranging from 0.5 to 20 °C/min. Differential scanning calorimetry (DSC) and NIR spectroscopy were used to explore the cure ramp rate dependence of the polymer network growth, whereas broadband dielectric spectroscopy (BDS) and free volume hole size measurements were used to interrogate networks’ molecular level structural variations upon curing at variable heating ramp rates. It was found that although the Tg of the polymer matrices was similar, the NIR and DSC measurements revealed a strong correlation for how these networks grow in relation to the cure heating ramp rate. The free volume analysis and BDS results for the cured samples suggest differences in the molecular architecture of the matrix polymers due to cure heating rate dependence

Analysis of the dynamic power requirements for controllable energy storage on photovoltaic microgrid

A dissertation submitted to the Facaulty of Engineering and the Built Environment, University of the Witwatersrand in ful lment of the requirements of the degree of Master of science in Engineering September 2016Standalone microgrid studies are being done because an expansion of the existing utility grids to supply power to remote communities is not feasible. Standalone microgrids can be considered as one of the solutions for remote communities because power can be generated close to these communities and it minimizes cost related to power transmission. Renewable energy sources with large uctuations are frequently the source of power for these standalone microgrids. The uctuating nature of these renewable sources can often lead to frequent blackouts. This research is aimed at minimizing power uctuations using controllable energy storage systems. This MSc focuses on the analysis of the ramp rate and delay time requirements for controllable energy storage system used in standalone PV microgrids. Measured insolation data and recorded load demand data for typical domestic appliances are used in this study to analyze ramp rates present. The ramp rates are then used to determine the range of energy storage ramp rate and delay time required to maintain the microgrid voltage within the standardized range of 1pu 5%. From the recorded data it has been observed that PV power can be sampled from at least 1-second intervals without losing important information. The 1 second averaged ramp rates obtained from the insolation data measurements have been found to have the highest value of 0.12pu/sec. However, this ramp rate increases to 0.3pu/sec when the allowable microgrid voltage band is narrow (1pu 5%). These insolation ramp rates are very low compared to the ramp rates of typical loads that can be connected to a microgrid. This means that, if the energy storage system is speci ed to meet the load ramp rate requirements, it will be able to respond to the uctuating PV power. The results obtained from the simulations con rm that energy storage system ramp rate plays an important role in the stability of a standalone microgrid. The minimum allowable energy storage ramp rate was found to be 8.15pu/sec for load transients with a ramp time of 20ms. This value is 28 times the energy storage ramp rate required to cancel out insolation uctuations. This further con rms that energy storage system ramp rates must be speci ed using the load demand data. The maximum allowable delay time was also found to be 0.53s to maintain the microgrid voltage within the standardized range of 1pu 5%. This delay time is applicable when canceling out only the insolation uctuations. To cancel out load transient power uctuations, there should be no delay time.MT201

Maximum expected ramp rates using cloud speed sensor measurements

Large ramps and ramp rates in photovoltaic (PV) power output are of concern and sometimes even explicitly restricted by grid operators. Battery energy storage systems can smooth the power output and maintain ramp rates within permissible limits. To enable PV plant and energy storage system design and planning, a method to estimate the largest expected ramps for a given location is proposed. Because clouds are the dominant source of PV power output variability, an analytical relationship between the worst expected ramp rate, cloud motion vector, and the geometrical layout of the PV plant is developed. The ability of the proposed method to bracket actual ramp rates is assessed over 10 months under different meteorological conditions, demonstrating an average compliance rate of 98.9% for a 2 min evaluation time window. The largest observed ramp of 29.7% s(-1)is contained with the worst case estimate of 34.3% s(-1). This method provides a convenient yet economical approach to worst-case PV ramp rate modeling and is compatible with solar irradiance measured at coarse temporal resolution.Juan Bosch was financed in part by Project No. PID2019-108953RB-C21, funded by the Ministerio de Ciencia e Innovación and co-financed by the European Regional Development Fund. In addition, Iñigo de la Parra was partially supported by the Spanish State Research Agency (AEI) and FEDER-UE under Grant Nos. DPI2016-80641-R and DPI2016-80642-R

Analysis of the Mechanical Properties of DGEBF/4,4’-DDS Thermoset Systems as a Function of Cure Rate

The relationship between macroscopic mechanical and thermal properties and ramp rate during cure of epoxy-amine systems consisting of the epoxide resin digylcidyl ether of bisphenol F (DGEBF, provided Hexion specialty chemicals) and 4,4-diaminodiphenyl sulfone (4,4-DDS, provided by Atul Sulpho) were probed using Dynamic Mechanical Analysis (DMA), Positron Annihilation Lifetime Spectroscopy (PALS), and compression testing. These systems were cured in a programmable oven; the samples were heated from 35°C to 180°C at ramp rates of 0.5, 1.0, 1.5, 2.0, 2.5, 5.0, 10, and 15°C/min. Even as the ramp rates during the cure of these materials was changed, there was very little in properties such as crosslink density, glass transition temperature (Tg), free hole volume, or modulus in the samples

Molecular scale cure rate dependence of thermoset matrix polymers

This manuscript demonstrates the molecular scale cure rate dependence of di-functional epoxide based thermoset polymers cured with amines. A series of cure heating ramp rates were used to determine the influence of ramp rate on the glass transition temperature (Tg) and sub-Tg transitions and the average free volume hole size in these systems. The networks were comprised of 3,3′-diaminodiphenyl sulfone (33DDS) and diglycidyl ether of bisphenol F (DGEBF) and were cured at ramp rates ranging from 0.5 to 20°C/min. Differential scanning calorimetry (DSC) and NIR spectroscopy were used to explore the cure ramp rate dependence of the polymer network growth, whereas broadband dielectric spectroscopy (BDS) and free volume hole size measurements were used to interrogate networks’ molecular level structural variations upon curing at variable heating ramp rates. It was found that although the Tg of the polymer matrices was similar, the NIR and DSC measurements revealed a strong correlation for how these networks grow in relation to the cure heating ramp rate. The free volume analysis and BDS results for the cured samples suggest differences in the molecular architecture of the matrix polymers due to cure heating rate dependence.Qatar University’s Center for Advanced Materials’ Start-Up grant. AFOSR Award Number FA9550-13-1-0103; and Dr. Gregg Bogucki and Dr. Stephen Heinz from Boeing Research and Technology for their kind financial support and collaboration

Aerodynamic Response of a Hovering Rotor to Ramp Changes in Pitch Input

Under transient conditions, a helicopter rotor generates a complex, time-dependent pattern of shed and trailed vorticity in its wake that has profound eects on its loading. To examine these eects, the response of a two-bladed hovering rotor to a ramp change in collective pitch is investigated using three dierent computational approaches. Solutions obtained using a Compressible Reynolds Averaged Navier{Stokes ap- proach are compared to results obtained from lifting-line theory coupled to an Eulerian Vorticity Transport Model, and from a simple single-state dynamic in ow model. The dierent numerical approaches yield very similar predictions of the thrust response of the rotor to ramp changes in collective pitch, as long as the ramp rates are small. This suggests that the basic underlying ow physics is properly represented by all the approaches. For more rapid ramp rates, an additional delay in the aerodynamic response of the rotor, that is related to the nite extent of the wake during its early history, is predicted by the Navier{Stokes and Vorticity Transport approaches. Even though the evolution of the wake of the rotor is strongly three dimensional and highly unsteady, the predictions of the Navier{Stokes and lifting-line models agree very closely as long as the blades of the rotor do not stall. In the pre-stall regime, a quasi two-dimensional representation of the blade aerodynamics thus appears adequate for predicting the performance of such systems even under highly transient conditions. When ow separation occurs, the resulting three dimen- sionality of the blade aerodynamics forces the predictions of the Navier{Stokes and lifting-line approaches to diverge, however. The characterization of the wake interactions and stall propagation mechanisms that are presented in this study oers some insight into the fundamental uid dynamic mechanisms that govern the transient aerodynamic response of a rotor to control inputs, and provides some quantication of the limits of applicability of some popular current approaches to rotor aerodynamic analysis

Aerodynamic response of a hovering rotor to ramp change in pitch input

Under transient conditions, a helicopter rotor generates a complex, time-dependent pattern of shed and trailed vorticity in its wake that has profound effects on its loading. To examine these effects, the response of a two-bladed hovering rotor to a ramp change in collective pitch is investigated using three different computational approaches. Solutions obtained using a Compressible Reynolds Averaged Navier-Stokes approach are compared to results obtained from lifting-line theory coupled to an Eulerian Vorticity Transport Model, and from a simple single-state dynamic inflow model. The different numerical approaches yield very similar predictions of the thrust response of the rotor to ramp changes in collective pitch, as long as the ramp rates are small. This suggests that the basic underlying flow physics is properly represented by all the approaches. For more rapid ramp rates, an additional delay in the aerodynamic response of the rotor, that is related to the finite extent of the wake during its early history, is predicted by the Navier-Stokes and Vorticity Transport approaches. Even though the evolution of the wake of the rotor is strongly three dimensional and highly unsteady, the predictions of the Navier-Stokes and lifting-line models agree very closely as long as the blades of the rotor do not stall. In the pre-stall regime, a quasi two-dimensional representation of the blade aerodynamics thus appears adequate for predicting the performance of such systems even under highly transient conditions. When flow separation occurs, the resulting three dimensionality of the blade aerodynamics forces the predictions of the Navier-Stokes and lifting-line approaches to diverge, however. The characterization of the wake interactions and stall propagation mechanisms that are presented in this study offers some insight into the fundamental fluid dynamic mechanisms that govern the transient aerodynamic response of a rotor to control inputs, and provides some quantication of the limits of applicability of some popular current approaches to rotor aerodynamic analysis