10,270 research outputs found
Misfit strain dependence of ferroelectric and piezoelectric properties of clamped (001) epitaxial Pb(Zr0.52,Ti0.48)O3 thin films \ud
A study on the effects of the residual strain in Pb(Zr0.52Ti0.48)O3 (PZT) thin films on the ferroelectric and piezoelectric properties is presented. Epitaxial (001)-oriented PZT thin film capacitors are sandwiched between SrRuO3 electrodes. The thin film stacks are grown on different substrate-buffer-layer combinations by pulsed laser deposition. Compressive or tensile strain caused by the difference in thermal expansion of the PZT film and substrate influences the ferroelectric and piezoelectric properties. All the PZT stacks show ferroelectric and piezoelectric behavior that is consistent with the theoretical model for strained thin films in the ferroelectric r-phase. We conclude that clamped (001) oriented Pb(Zr0.52Ti0.48)O3 thin films strained by the substrate always show rotation of the polarization vecto
Piezoelectric properties of polyamide 11/NaNbO3nanowire composites
Polyamide 11(PA 11)/sodium niobate nanowire (NW) 0–3 composites with different volume fractions of NWs were synthesized. The electric polarization (P) was measured as a function of the applied electric field (E). The P–E hysteresis loop was used to work out the remanent polarization Pr of these materials. The dielectric permittivity and the piezoelectric strain constant were determined. Good impedance matching between inorganic and organic phases leads to higher electroactivity than conventional lead-free 0–3 composites. The piezoelectric voltage of the PA 11/NaNbO3 NW composites is of the same order as those obtained for fluorinated piezoelectric polymers. These composites could have some applications in flexible, low-cost, environmentally friendly piezoelectric sensors and actuators
Improving the dielectric and piezoelectric properties of screen-printed low temperature PZT/polymer composite using cold isostatic pressing
This paper reports an improvement in dielectric and piezoelectric properties of screen-printed PZT/polymer films for flexible electronics applications using Cold Isostatic Pressing (CIP). The investigation involved half and fully cured PZT/polymer composite pastes with weight ratio of 12:1 to investigate the effect of the CIP process on the piezoelectric and dielectric properties. It was observed that the highest dielectric and piezoelectric properties are achieved at pressures of 5 and 10 MPa for half and fully cured films respectively. The relative dielectric constants were 300 and 245 measured at 1 kHz for the half and fully cured samples. Using unoptimised poling conditions, the initial d33 values were 30 and 35 pC/N for the half and fully cured films, respectively. The fully cured sample was then poled using optimized conditions and demonstrated a d33 of approximately 44 pC/N which is an increase of 7% compared with non-CIP processed material
Optimal configuration of microstructure in ferroelectric materials by stochastic optimization
An optimization procedure determining the ideal configuration at the
microstructural level of ferroelectric (FE) materials is applied to maximize
piezoelectricity. Piezoelectricity in ceramic FEs differ significantly from
that of single crystals because of the presence of crystallites (grains)
possessing crystallographic axes aligned imperfectly. The piezoelectric
properties of a polycrystalline (ceramic) FE is inextricably related to the
grain orientation distribution (texture). The set of combination of variables,
known as solution space, which dictates the texture of a ceramic is unlimited
and hence the choice of the optimal solution which maximizes the
piezoelectricity is complicated. Thus a stochastic global optimization combined
with homogenization is employed for the identification of the optimal granular
configuration of the FE ceramic microstructure with optimum piezoelectric
properties. The macroscopic equilibrium piezoelectric properties of
polycrystalline FE is calculated using mathematical homogenization at each
iteration step. The configuration of grains characterised by its orientations
at each iteration is generated using a randomly selected set of orientation
distribution parameters. Apparent enhancement of piezoelectric coefficient
is observed in an optimally oriented BaTiO single crystal. A
configuration of crystallites, simultaneously constraining the orientation
distribution of the c-axis (polar axis) while incorporating ab-plane
randomness, which would multiply the overall piezoelectricity in ceramic
BaTiO is also identified. The orientation distribution of the c-axes is
found to be a narrow Gaussian distribution centred around . The
piezoelectric coefficient in such a ceramic is found to be nearly three times
as that of the single crystal.Comment: 11 pages, 7 figure
Domain Size Dependence of Piezoelectric Properties of Ferroelectrics
The domain size dependence of piezoelectric properties of ferroelectrics is
investigated using a continuum Ginzburg-Landau model that incorporates the
long-range elastic and electrostatic interactions. Microstructures with desired
domain sizes are created by quenching from the paraelectric phase by biasing
the initial conditions. Three different two-dimensional microstructures with
different sizes of the domains are simulated. An electric field is
applied along the polar as well as non-polar directions and the piezoelectric
response is simulated as a function of domain size for both cases. The
simulations show that the piezoelectric coefficients are enhanced by reducing
the domain size, consistent with recent experimental results of Wada and
Tsurumi (Brit. Ceram. Trans. {\bf 103}, 93, 2004) on domain engineered
Comment: submitted to Physical Review
Electronic, Mechanical, and Piezoelectric Properties of ZnO Nanowires
Hexagonal [0001] nonpassivated ZnO nanowires are studied with density
functional calculations. The band gap and Young's modulus in nanowires which
are larger than those in bulk ZnO increase along with the decrease of the
radius of nanowires. We find ZnO nanowires have larger effective piezoelectric
constant than bulk ZnO due to their free boundary. In addition, the effective
piezoelectric constant in small ZnO nanowires doesn't depend monotonously on
the radius due to two competitive effects: elongation of the nanowires and
increase of the ratio of surface atoms
Improving the functional properties of (K0.5Na0.5)NbO3 piezoceramics by acceptor doping
ZrO2 and TiO2 modified lead-free (K0.5Na0.5)NbO3 (KNN) piezoelectric ceramics are prepared by a conventional solid-state reaction. The effect of acceptor doping on structural and functional properties is investigated. A decrease in the Curie temperature and an increase in the dielectric constant values are observed when doping. More interestingly, an increase in the coercive field E-c and remanent polarization P-r is observed. The piezoelectric properties are greatly increased when doping with small concentrations dopants. ZrO2 doped ceramic exhibits good piezoelectric properties with piezoelectric coefficient d(33) = 134 pC/N and electromechanical coupling factor k(p) = 35%. It is verified that nonlinearity is significantly reduced. Thus, the creation of complex defects capable of pinning the domain wall motion is enhanced with doping, probably due to the formation of oxygen vacancies. These results strongly suggest that compositional engineering using low concentrations of acceptor doping is a good means of improving the functional properties of KNN lead-free piezoceramic system. (C) 2014 Elsevier Ltd. All rights reserved.Postprint (published version
Extending device performance in photonic devices using piezoelectric properties
This study focuses on the influence of epi-layer strain and piezoelectric effects in asymmetric GaInAs/GaAlAs action regions that potentially lead to intra-cavity frequency mixing. The theoretical limits for conduction and valence band offsets in lattice-matched semiconductor structures have resulted in the deployment of non-traditional approaches such as strain compensation to extend wavelength in intersubband devices, where strain limits are related to misfit dislocation generation. Strain and piezoelectric effects have been studied and verified using select photonic device designs. Metrics under this effort also included dipole strength, oscillator strength, and offset of energy transitions, which are strongly correlated with induced piezoelectric effects. Unique photonic designs were simulated, modeled, and then fabricated using solid-source molecular beam epitaxy into photonic devices. The initial designs produce lambda wavelength, and the introduction of the piezoelectric effect resulted in lambda/2 wavelength. More importantly, this work demonstrates that the theoretical cutoff wavelength in intersubband lasers can be overcome
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