Phase behaviour of binary mixtures of diamagnetic colloidal platelets in an external magnetic field

Using fundamental measure density functional theory we investigate paranematic-nematic and nematic-nematic phase coexistence in binary mixtures of circular platelets with vanishing thicknesses. An external magnetic field induces uniaxial alignment and acts on the platelets with a strength that is taken to scale with the platelet area. At particle diameter ratio lambda=1.5 the system displays paranematic-nematic coexistence. For lambda=2, demixing into two nematic states with different compositions also occurs, between an upper critical point and a paranematic-nematic-nematic triple point. Increasing the field strength leads to shrinking of the coexistence regions. At high enough field strength a closed loop of immiscibility is induced and phase coexistence vanishes at a double critical point above which the system is homogeneously nematic. For lambda=2.5, besides paranematic-nematic coexistence, there is nematic-nematic coexistence which persists and hence does not end in a critical point. The partial orientational order parameters along the binodals vary strongly with composition and connect smoothly for each species when closed loops of immiscibility are present in the corresponding phase diagram.Comment: 9 pages, to appear in J.Phys:Condensed Matte

Bulk phase behaviour of binary hard platelet mixtures from density functional theory

We investigate isotropic-isotropic, isotropic-nematic and nematic-nematic phase coexistence in binary mixtures of circular platelets with vanishing thickness, continuous rotational degrees of freedom and radial size ratios $\lambda$ up to 5. A fundamental measure density functional theory, previously used for the one-component model, is proposed and results are compared against those from Onsager theory as a benchmark. For $\lambda \leq 1.7$ the system displays isotropic-nematic phase coexistence with a widening of the biphasic region for increasing values of $\lambda$. For size ratios $\lambda \geq 2$, we find demixing into two nematic states becomes stable and an isotropic-nematic-nematic triple point can occur. Fundamental measure theory gives a smaller isotropic-nematic biphasic region than Onsager theory and locates the transition at lower densities. Furthermore, nematic-nematic demixing occurs over a larger range of compositions at a given value of $\lambda$ than found in Onsager theory. Both theories predict the same topologies of the phase diagrams. The partial nematic order parameters vary strongly with composition and indicate that the larger particles are more strongly ordered than the smaller particles

Phases and Transitions in Phantom Nematic Elastomer Membranes

Motivated by recently discovered unusual properties of bulk nematic elastomers, we study a phase diagram of liquid-crystalline polymerized phantom membranes, focusing on in-plane nematic order. We predict that such membranes should enerically exhibit five phases, distinguished by their conformational and in-plane orientational properties, namely isotropic-crumpled, nematic-crumpled, isotropic-flat, nematic-flat and nematic-tubule phases. In the nematic-tubule phase, the membrane is extended along the direction of {\em spontaneous} nematic order and is crumpled in the other. The associated spontaneous symmetries breaking guarantees that the nematic-tubule is characterized by a conformational-orientational soft (Goldstone) mode and the concomitant vanishing of the in-plane shear modulus. We show that long-range orientational order of the nematic-tubule is maintained even in the presence of harmonic thermal luctuations. However, it is likely that tubule's elastic properties are ualitatively modified by these fluctuations, that can be studied using a nonlinear elastic theory for the nematic tubule phase that we derive at the end of this paper.Comment: 12 pages, 4 eps figures. To appear in PR

Long-range Casimir interactions between impurities in nematic liquid crystals and the collapse of polymer chains in such solvents

The elastic interactions between objects embedded in a nematic liquid crystal are usually caused by the average distorsion-rather than by the fluctuations-of the nematic orientational field. We argue that for sufficiently small particles, the nematic-mediated interaction originates purely from the fluctuations of the nematic director. This Casimir interaction decays as d^(-6), d being the distance between the particles, and it dominates van der Waals interactions close to the isotropic-to-nematic transition. Considering the nematic as a polymer solvent, we show that the onset of this Casimir interaction at the isotropic-to-nematic transition can discontinuously induce the collapse of a flexible polymer chain from the swollen state to the globular state, without crossing the Theta-point.Comment: 6 pages, 1 figur

Electronic nematic susceptibility of iron-based superconductors

We review our recent experimental results on the electronic nematic phase in electron- and hole-doped BaFe$_2$As$_2$ and FeSe. The nematic susceptibility is extracted from shear-modulus data (obtained using a three-point-bending method in a capacitance dilatometer) using Landau theory and is compared to the nematic susceptibility obtained from elastoresistivity and Raman data. FeSe is particularly interesting in this context, because of a large nematic, i.e., a structurally distorted but paramagnetic, region in its phase diagram. Scaling of the nematic susceptibility with the spin lattice relaxation rate from NMR, as predicted by the spin-nematic theory, is found in both electron- and hole-doped BaFe$_2$As$_2$, but not in FeSe. The intricate relationship of the nematic susceptibility to spin and orbital degrees of freedom is discussed.Comment: Invited review article for a special issue on Fe-based superconductors in Comptes Rendus Physiqu

Nematic twist-bend phase with nanoscale modulation of molecular orientation

A state of matter in which molecules show a long-range orientational order and no positional order is called a nematic liquid crystal. The best known and most widely used (for example, in modern displays) is the uniaxial nematic, with the rod-like molecules aligned along a single axis, called the director. When the molecules are chiral, the director twists in space, drawing a right-angle helicoid and remaining perpendicular to the helix axis; the structure is called a chiral nematic. Here using transmission electron and optical microscopy, we experimentally demonstrate a new nematic order, formed by achiral molecules, in which the director follows an oblique helicoid, maintaining a constant oblique angle with the helix axis and experiencing twist and bend. The oblique helicoids have a nanoscale pitch. The new twist-bend nematic represents a structural link between the uniaxial nematic (no tilt) and a chiral nematic (helicoids with right-angle tilt)

Some properties of membranes in nematic solvents

The fluctuation spectrum of membranes in nematic solvents is altered by the boundary condition imposed on the bulk nematic director by the curved membrane. We discuss some properties of single and multi-membrane systems in nematic solvents, primarily based on the Berreman-de~Gennes model. We show that: membranes in nematic solvents are more rigid and less rough than in their isotropic counterparts; have a different Helfrich steric stabilization energy, proportional to $d^{-3}$, and hence a different compression modulus in the lamellar state; and can exhibit phase separation via unbinding during a quench into the nematic state. We also discuss the preparation and possible experimental effects of nematic-mediated surfactant membrane system

Topological Defects and Interactions in Nematic Emulsions

Inverse nematic emulsions in which surfactant-coated water droplets are dispersed in a nematic host fluid have distinctive properties that set them apart from dispersions of two isotropic fluids or of nematic droplets in an isotropic fluid. We present a comprehensive theoretical study of the distortions produced in the nematic host by the dispersed droplets and of solvent mediated dipolar interactions between droplets that lead to their experimentally observed chaining. A single droplet in a nematic host acts like a macroscopic hedgehog defect. Global boundary conditions force the nucleation of compensating topological defects in the nematic host. Using variational techniques, we show that in the lowest energy configuration, a single water droplet draws a single hedgehog out of the nematic host to form a tightly bound dipole. Configurations in which the water droplet is encircled by a disclination ring have higher energy. The droplet-dipole induces distortions in the nematic host that lead to an effective dipole-dipole interaction between droplets and hence to chaining.Comment: 17 double column pages prepared by RevTex, 15 eps figures included in text, 2 gif figures for Fig. 1

Meta-nematic transitions in a bilayer system: Application to the bilayer ruthenate

It was suggested that the two consecutive metamagnetic transitions and the large residual resistivity discovered in Sr$_3$Ru$_2$O$_7$ can be understood via the nematic order and its domains in a single layer system. However, a recently reported anisotropy between two longitudinal resistivities induced by tilting the magnetic field away from the c-axis cannot be explained within the single layer nematic picture. To fill the gap in our understanding within the nematic order scenario, we investigate the effects of bilayer coupling and in-plane magnetic field on the electronic nematic phases in a bilayer system. We propose that the in-plane magnetic field in the bilayer system modifies the energetics of the domain formation, since it breaks the degeneracy of two different nematic orientations. Thus the system reveals a pure nematic phase with a resistivity anisotropy in the presence of an in-plane magnetic field. In addition to the nematic phase, the bilayer coupling opens a novel route to a hidden nematic phase that preserves the x-y symmetry of the Fermi surfaces.Comment: 8 pages, 6 figure