Alumina reinforced eucryptite ceramics: Very low thermal expansion material with improved mechanical properties

[EN] Composite materials formed by a LAS matrix reinforced with second phases are promising materials in many applications where better mechanical properties than those corresponding to conventional low thermal expansion coefficient materials are required. In this study we will show the capability of the design of a LAS-alumina submicron composite. The main scope of this work is to test the sinterability of the composites and to design a composition for a very low thermal expansion submicron composite. For this purpose, Taimei alumina (TM-DAR) powders and an ad hoc synthesized beta-eucryptite phase were used to fabricate the composite. XRD phase compositions and microstructures are discussed together with data from dilatometries in a wide temperature range. The results obtained show the possibility of designing a submicron composite with a very low thermal expansion coefficient and improved mechanical properties that can be used in oxidizing conditions. (C) 2011 Elsevier Ltd. All rights reserved.We would like to thank Prof. Salvador de Aza and Prof. Serafin Moya for the thorough discussion of LAS-Al2O3 solid state compatibility and comments on a first version of the manuscript. The authors greatly appreciate the support of the EU for the IP-Nanoker NMP3-CT-2005-515784 in the frame of the 6th Framework Program. Garcia-Moreno is working for CSIC under a JAE-Doc contract co-funded by the ESF. A. Borrell is working with financial support of National Plan Project MAT2006-01783 under FPI contract.García-Moreno, O.; Borrell Tomás, MA.; Bittmann, B.; Fernández-Valdés, A.; Torrecillas San Millán, R. (2011). Alumina reinforced eucryptite ceramics: Very low thermal expansion material with improved mechanical properties. Journal of the European Ceramic Society. 31(9):1641-1646. https://doi.org/10.1016/j.jeurceramsoc.2011.03.033S1641164631