Laboratory Investigations of Hydraulic Fractures in Naturally Fractured Formations

Researchers have recently realized that hydraulic fracture networks are significant for the exploitation of unconventional reservoirs (tight gas, shale gas, coalbed methane, etc.). Laboratory experiments are proposed to study the evolution of fracture networks in natural fractures. The density of natural fractures and injection rate were selected as the primary dominating factors. It was concluded that the interaction between reopening and connecting of natural fractures led to hydraulic fracture networks, which can be detected by pressure fluctuations. The fracture network is composed of multiple fractures, resembling an ellipsoid with the major axis different from the maximum horizontal stress direction. The treatment pressure will be substantially raised by both the great natural fracture density and high injection rates

Effect of gas atmosphere on carbothermal reduction and nitridation of titanium dioxide

This article examined the reduction/nitridation of rutile in the He-N2, Ar-N2, and He (Ar)-H2- N2 gas mixtures, as well as pure nitrogen, in the temperature-programmed and isothermal experiments in a fixed-bed reactor. The extents of reduction and nitridation were determined from the off gas composition and LECO analysis. The off-gas composition was monitored using the infrared sensor (CO, CO2, and CH4) and dew point analyzer (H2O). The phase composition of the reduced samples was analyzed using X-ray diffraction (XRD). The temperature and gas composition had a strong effect on the rutile reduction. The reduction was the fastest in the H2- N2 gas mixture, followed by a reduction in nitrogen; the rate of reduction/nitridation in the He- N2 gas mixture was marginally higher than in the Ar-N2 gas. The rate of titania reduction/ nitridation in the He (Ar)-H2-N2 gas increased with the replacement of He (Ar) with hydrogen. The article also discusses the mechanisms of reduction/nitridation in different gas atmospheres

Gasoline Prices and Their Relationship to Drunk-Driving Crashes

his study investigates the relationship between changing gasoline prices and drunk-driving crashes. Specifically, we examine the effects of gasoline prices on drunk-driving crashes in Mississippi by age, gender, and race from 2004Ð2008, a period experiencing great fluctuation in gasoline prices. An exploratory visualization by graphs shows that higher gasoline prices are generally associated with fewer drunk-driving crashes. Higher gasoline prices depress drunk- driving crashes among younger and older drivers, among male and female drivers, and among white, black, and Hispanic drivers. The statistical results suggest that higher gasoline prices lead to lower drunk-driving crashes for female and black drivers. However, alcohol consumption is a better predictor of drunk-driving crashes, especially for male, white, and older drivers.Drunk-driving crashes, gasoline prices, alcohol consumption, Mississippi

Research Progress in Anaerobic Digestion of High Moisture

High moisture organic waste constitutes a large fraction of municipal solid waste and caused a nuisance. Anaerobic digestion of this high degradable fraction has been developed during the past 20 years. Parameters such as characteristic of substrates, temperature, organic loading rate and hydraulic retention time were studied. The most important conversion of intermediate of volatile fatty acid was observed as a indicator of digestion efficiency. One stage and two stage system are based on the stage separated into acidogenic phase and methnogenis phase. Two stage digestion of this kind of wastes were proved a better efficiency than single stage digestion. Batch system and continuous system are conducted in single stage and two-stage system. One stage system are split between wet system(Total solid less than 15%) and dry system( total solid higher than 15%) according to the characteristics of feedstock. Two-stage solid bed system are observed more and more popular in the digestion of solid state VFW and food waste experimental studies, however the large majority of industrial application use single stage systems. Two stage digestion of HMOW will be applied to industrial scale due to its larger resistance to high loading rate, high and stable gas production

Effects of annealing on microstructure and microstrength of metallurgical coke

Two metallurgical cokes were heat treated at 1673 K to 2273 K (1400 degrees celsius to 2000 degrees celsius) in a nitrogen atmosphere. The effect of heat treatment on the microstructure and microstrength of metallurgical cokes was characterized using X-ray diffraction, Raman spectroscopy, and ultramicroindentation. In the process of heat treatment, the microstructure of the metallurgical cokes transformed toward the graphite structure. Raman spectroscopy of reactive maceral-derived component (RMDC) and inert maceral-derived component (IMDC) indicated that the graphitisation degree of the RMDC was slightly lower than that of the IMDC in the original cokes; however graphitisation of the RMDC progressed faster than that of the IMDC during annealing, and became significantly higher after annealing at 2273 K (2000 degrees celsius). The microstrength of cokes was significantly degraded in the process of heat treatment. The microstrength of the RMDC was lower, and of its deterioration caused by heat treatment was more severe than IMDC. The degradation of the microstrength of cokes was attributed to their increased graphitisation degree during the heat treatment

A feasibility study of recycling of manganese furnace dust

This paper presents results of a feasibility study of recycling manganese furnace dust generated in production of ferromanganese and silicomanganese at Tasmanian Electrometallurgical Company, Australia. Dried manganese furnace dust contains about 20 wt% of carbon, in average 33.4 wt% of manganese and 1.3 wt% of zinc. Manganese in the dust is in the form of MnO, Mn3O4 and MnCO3; zinc is mainly in the form of ZnO and ZnSO4. Analysis of the zinc balance with dust recycling showed that to keep zinc intake at the acceptable level, it should be partly removed from the dust. In the reduction laboratory experiments, zinc oxide was reduced to zinc vapour by tar of the dust. Reduction of zinc oxide started at 800oC and zinc removal rate increased with increasing temperature; removal of zinc was close to completion at 1100oC. Optimal conditions for removing zinc from the dust include temperature in the range 1000-1150oC, inert gas atmosphere and furnace dust fraction in the furnace dust-manganese ore mixture above 60%. In the sintering of manganese ore with addition of manganese dust in the sintering pot, zinc was reoxidised and deposited in the sinter bed. Removal of zinc in the sintering pot tests was in the range 4-17%. Up to 30% zinc removal was achieved from the bottom layer of the sinter bed. It can be concluded that zinc removal will be low during the processing of manganese furnace dust in the sinter plant. The zinc removal rate will be the highest when pelletised manganese furnace dust is added to the bottom layer of the sintering bed

Microstrength, strength and microstructure of carbonaceous materials

The effect of heat treatment at 700-1500 ºC on the mechanical strength, micro strength and pore structure of carbonaceous materials, including coke, char and coals, were studied using tensile test, ultra micro indentation and image analysis. Strength of chars and pyrolysed coals was strongly enhanced by heat treatment at temperature below 1100 °C; strength of cokes was slightly degraded after heat treatment at 1500 °C. Mechanical strength of carbonaceous materials was demonstrated to be significantly affected by micro strength and porosity. Micro strength of chars and coals was significantly enhanced by heat treatment, whereas micro strength of cokes was only marginally increased by heat treatment. The major growth in the micro strength of chars and coals took place at annealing temperature below 1100 °C. Porosity of chars and coals significantly increased during annealing at temperatures below 1100 °C. Further increasing annealing temperature from 1100-1500 °C caused marginal porosity evolution in pyrolysed coals and chars. Porosity of cokes increased slightly in the temperature range of 1300-1500 °C

Synthesis and Biological Activity of Trolox Amide Derivatives

A series of Trolox amide derivatives were synthesized by modifying the carboxyl groups of Trolox. Thirty target compounds were obtained and characterized through nuclear magnetic resonance and mass spectrometry. Trolox derivatives were employed to explore the potential structure-antioxidant activity relationships. The antioxidant activities of these compounds were evaluated using 1,1-diphenyl-2-picrylhydrazyl (DPPH), 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), ferric reducing antioxidant power (FRAP) and hydroxyl radical assays. DPPH scavenging activity test results illustrated that compounds exhibited scavenging activities similar to L-ascorbic acid and Trolox, with compounds 14a, 18a, 24a and 26a in particular exhibiting higher scavenging activities than L-ascorbic acid. The results demonstrated that compounds displayed ABTS scavenging activities similar to L-ascorbic acid and Trolox, with compounds 26a and 29a in particular having potency twofold higher. FRAP assay results indicated that compounds 11a, 19a, 25a, 29a and 30a had activity similar to Trolox. The results revealed that compounds 6a and 19a had similarly high hydroxyl radical-scavenging activities as Trolox. The results of α-glucosidase experiments uncovered that compounds 10a, 25a, 28a and 29a had excellent inhibitory activity, which was similar to that of acarbose and different from Trolox. The results of acetylcholinesterase and butyrylcholinesterase experiments demonstrated that some compounds had weak anticholinesterase activities. 26a and 29a are important Trolox derivatives with better biological activity profiles and deserve further study

Behaviour of New Zealand ironsand during iron ore sintering

Titanium-bearing burdens are commonly introduced into blast furnaces to protect the hearlh because the so-called titanium bear which is a precipitate of carbide, nitride and carbonitride of titanium may form in the blast furnace hearth if Ti02 is present in the feed [1 , 2J. New Zealand ironsand is a titanomagnetite, containing around 60 wt.% iron, 8 wt.% titanium and other substances such as silica, phosphorus and lime [3, 4]. Since it is competitive in price, introduction of the ironsand into the ferrous feed can reduce the production cost and potentially increase blast furnace campaign life. An appropriate method of inlroduction of ironsand is as a component of the sinter as the small size of ironsand precludes direct charging into the blast furnace. Although the effect of introducing titanomagnetite into iron ore blends has been investigated [1,,2, §],little is known about the detailed sintering mechanism. The present study is aimed at identifying the sintering behaviour of New Zealand ironsand as well as the interaction between New Zealand ironsand and CaO to gain better understanding of sintering mechanism of titanomagnetite