Anharmonic effect on lattice distortion, orbital ordering and magnetic properties in Cs2AgF4

We develop the cluster self-consistent field method incorporating both electronic and lattice degrees of freedom to study the origin of ferromagnetism in Cs$_{2}$AgF$_{4}$. After self-consistently determining the harmonic and anharmonic Jahn-Teller distortions, we show that the anharmonic distortion stabilizes the staggered x$^{2}$-z$^{2}$/y$^{2}$-z$^{2}$ orbital and ferromagnetic ground state, rather than the antiferromagnetic one. The amplitudes of lattice distortions, Q$_{2}$ and Q$_{3}$, the magnetic coupling strengthes, J$_{x,y}$, and the magnetic moment, are in good agreement with the experimental observation.Comment: 13 pages, 5 figure

Slip Failure of Embankment on Soft Marine Clay

The results of an investigation carried out at a site before and after the slip failure of an embankment on soft marine clay are presented. An evaluation of the possible causes for the slip failure and the remedial measures taken after the failure are also included. It appears that overstressing of the ground might have led to the movement of the soft soil. The compressible soils were subjected to an increase in stress without a comparable increase in foundation shear strength. This increase in horizontal stress resulted in the horizontal displacement of the soil as evident by the presence of the tension cracks in the fill just before slip failure occurred

Biocompatible Mesoporous Hollow Carbon Nanocapsules for High Performance Supercapacitors.

A facile and general method for the controllable synthesis of N-doped hollow mesoporous carbon nanocapsules (NHCNCs) with four different geometries has been developed. The spheres (NHCNC-1), low-concaves (NHCNC-2), semi-concaves (NHCNC-3) and wrinkles (NHCNC-4) shaped samples were prepared and systematically investigated to understand the structural effects of hollow particles on their supercapacitor performances. Compared with the other three different shaped samples (NHCNC-1, NHCNC-2, and NHCNC-4), the as-synthesized semi-concave structured NHCNC-3 demonstrated excellent performance with high gravimetric capacitance of 326 F g-1 (419 F cm-3) and ultra-stable cycling stability (96.6% after 5000 cycles). The outstanding performances achieved are attributed to the unique semi-concave structure, high specific surface area (1400 m2 g-1), hierarchical porosity, high packing density (1.41 g cm-3) and high nitrogen (N) content (up to 3.73%) of the new materials. These carbon nanocapsules with tailorable structures and properties enable them as outstanding carriers and platforms for various emerging applications, such as nanoscale chemical reactors, catalysis, batteries, solar energy harvest, gas storage and so on. In addition, these novel carbons have negligible cytotoxicity and high biocompatibility for human cells, promising a wide range of bio applications, such as biomaterials, drug delivery, biomedicine, biotherapy and bioelectronic devices

Characterisation of Bidor Kaolinite and Illite

Two types of commercial clay minerals from the Bidor region of Perak were studied. From the X-ray diffraction study, these clays were identified as disordered kaolinite and 2 M polymorph of illite. The morphologies, the surface properties, the pore structures and the infrared absorption properties were examined. The basis for the identification of these clays is discussed

Projectile Δ\Delta Excitations in p(p,n)Nπp(p,n)N\pi Reactions

It has recently been proven from measurements of the spin-transfer coefficients $D_{xx}$ and $D_{zz}$ that there is a small but non-vanishing $\Delta S=0$ component $\sigma_{0}$, in the inclusive $p(p,n)N\pi\,$ reaction cross section $\sigma\,$. It is shown that the dominant part of the measured $\sigma_{0}$ can be explained in terms of the projectile $\Delta$ excitation mechanism. An estimate is further made of contributions to $\sigma_{0}$ from s-wave rescattering process. It is found that s-wave rescattering contribution is much smaller than the contribution coming from projectile $\Delta$ excitation mechanism. The addition of s-wave rescattering contribution to the dominant part, however, improves the fit to the data.Comment: 9 pages, Revtex, figures can be obtained upon reques

Simulation studies of permeation through two-dimensional ideal polymer networks

We study the diffusion process through an ideal polymer network, using numerical methods. Polymers are modeled by random walks on the bonds of a two-dimensional square lattice. Molecules occupy the lattice cells and may jump to the nearest-neighbor cells, with probability determined by the occupation of the bond separating the two cells. Subjected to a concentration gradient across the system, a constant average current flows in the steady state. Its behavior appears to be a non-trivial function of polymer length, mass density and temperature, for which we offer qualitative explanations.Comment: 8 pages, 4 figure

Correlation between 3:2 QPO pairs and Jets in Black Hole X-ray Binaries

We argue, following our earlier works (the "CEBZMC model"), that the phenomenon of twin peak high frequency quasi-periodic oscillations (QPOs) observed in black hole X-ray binaries is caused by magnetic coupling (MC) between accretion disk and black hole (BH). Due to MC, two bright spots occur at two separate radial locations r_{in} and r_{out} at the disk surface, energized by a kind of the Blandford-Znajek mechanism (BZ). We assume, following the Kluzniak-Abramowicz QPO resonance model, that Keplerian frequencies at these two locations are in the 3:2 ratio. With this assumption, we estimate the BH spins in several sources, including GRO J1655-40, GRS 1915+105, XTE J1550-564, H1743-322 and Sgr A*. We give an interpretation of the "jet line" in the hardness-intensity plane discussing the parameter space consisting of the BH spin and the power-law index for the variation of the large-scale magnetic field in the disk. Furthermore, we propose a new scenario for the spectral state transitions in BH X-ray binaries based on fluctuation in densities of accreting plasma from a companion star.Comment: 17 pages, 6 figures, accepted by AP

Robustness of the Berezinskii-Kosterlitz-Thouless Transition in Ultrathin NbN Films near the Superconductor-Insulator Transition

Occurrence of the Berezinskii-Kosterlitz-Thouless (BKT) transition is investigated by superfluid density measurements for two-dimensional (2D) disordered NbN films with disorder level very close to a superconductor-insulator transition (SIT). Our data show a robust BKT transition even near this 2D disorder-tuned quantum critical point (QCP). This observation is in direct contrast with previous data on deeply underdoped quasi-2D cuprates near the SIT. As our NbN films approach the QCP, the vortex-core energy, an important energy scale in the BKT transition, scales with the superconducting gap, not with the superfluid density, as expected within the standard 2D-XY model description of BKT physics.Comment: 8 pages, 6 figure