Biodegradation kinetics of acenphtylene, flourene and phenantrene : a comparative study

Polycyclic Aromatic Hydrocarbons (PAH) are environmental contaminants produced in many human activities and presents toxic and carcinogenic characteristics. Their low solubility in water leads to slow biodegradation rates and consequently environmental persistence. The present work intends to determine the degradation rates of three aqueous phase PAH’s (acenphtylene, flourene and phenantrene) by a mixed culture of microorganisms. The three PAH were dissolved in water at a concentration approximately of 1 mg Lˉ¹. A mixed culture taken from contaminated site was used to inoculate the samples. Batch experiments were performed at room temperature (∼20°C) and PAH consume was measured during the experiment time. PAH samples were extracted and concentrated by solid phase micro extraction (SPME) and measured by GC-FID. Biomass was measured as volatile suspended solids at the beginning and at the end of experiment to ensure that no significant biomass was grown. The culture was able to degrade acenphtylene, flourene and phenantrene. The biokinetics parameters (k and Ks) were determined using a saturation type kinetics biodegradation model and the results were very similar for the three PAH’s. The main microorganisms identified (by API 20NE test) in the culture were Pseudomonas putida, Pseudomonas aeruginosa, Alcagenes faecalis and Xanthomonas maltophilia

Renormalization, duality, and phase transitions in two- and three-dimensional quantum dimer models

We derive an extended lattice gauge theory type action for quantum dimer models and relate it to the height representations of these systems. We examine the system in two and three dimensions and analyze the phase structure in terms of effective theories and duality arguments. For the two-dimensional case we derive the effective potential both at zero and finite temperature. The zero-temperature theory at the Rokhsar-Kivelson (RK) point has a critical point related to the self-dual point of a class of $Z_N$ models in the $N\to\infty$ limit. Two phase transitions featuring a fixed line are shown to appear in the phase diagram, one at zero temperature and at the RK point and another one at finite temperature above the RK point. The latter will be shown to correspond to a Kosterlitz-Thouless (KT) phase transition, while the former will be governed by a KT-like universality class, i.e., sharing many features with a KT transition but actually corresponding to a different universality class. On the other hand, we show that at the RK point no phase transition happens at finite temperature. For the three-dimensional case we derive the corresponding dual gauge theory model at the RK point. We show in this case that at zero temperature a first-order phase transition occurs, while at finite temperatures both first- and second-order phase transitions are possible, depending on the relative values of the couplings involved.Comment: 16 pages, 3 figure

Mechanical Thrombectomy for Isolated M2 Occlusions: A Post Hoc Analysis of the STAR, SWIFT, and SWIFT PRIME Studies

ABSTRACT BACKGROUND AND PURPOSE: Mechanical thrombectomy is beneficial for patients with acute ischemic stroke and a proximal anterior occlusion, but it is unclear if these results can be extrapolated to patients with an M2 occlusion. The purpose of this study was to examine the technical aspects, safety, and outcomes of mechanical thrombectomy with a stent retriever in patients with an isolated M2 occlusion who were included in 3 large multicenter prospective studies

Three-loop \beta-functions for top-Yukawa and the Higgs self-interaction in the Standard Model

We analytically compute the dominant contributions to the \beta-functions for the top-Yukawa coupling, the strong coupling and the Higgs self-coupling as well as the anomalous dimensions of the scalar, gluon and quark fields in the unbroken phase of the Standard Model at three-loop level. These are mainly the QCD and top-Yukawa corrections. The contributions from the Higgs self-interaction which are negligible for the running of the top-Yukawa and the strong coupling but important for the running of the Higgs self-coupling are also evaluated.Comment: 22 pages, 7 figures. Few extra citations are added; the plots are improved. Results in computer readable form can be retrieved from http://www-ttp.particle.uni-karlsruhe.de/Progdata/ttp12/ttp12-012

Quantum magnetism and criticality

Magnetic insulators have proved to be fertile ground for studying new types of quantum many body states, and I survey recent experimental and theoretical examples. The insights and methods transfer also to novel superconducting and metallic states. Of particular interest are critical quantum states, sometimes found at quantum phase transitions, which have gapless excitations with no particle- or wave-like interpretation, and control a significant portion of the finite temperature phase diagram. Remarkably, their theory is connected to holographic descriptions of Hawking radiation from black holes.Comment: 39 pages, 10 figures, review article for non-specialists; (v2) added clarifications and references; (v3) minor corrections; (v4) added footnote on hydrodynamic long-time tail

Critical properties of the topological Ginzburg-Landau model

We consider a Ginzburg-Landau model for superconductivity with a Chern-Simons term added. The flow diagram contains two charged fixed points corresponding to the tricritical and infrared stable fixed points. The topological coupling controls the fixed point structure and eventually the region of first order transitions disappears. We compute the critical exponents as a function of the topological coupling. We obtain that the value of the $\nu$ exponent does not vary very much from the XY value, $\nu_{XY}=0.67$. This shows that the Chern-Simons term does not affect considerably the XY scaling of superconductors. We discuss briefly the possible phenomenological applications of this model.Comment: RevTex, 7 pages, 8 figure

Protein profiling in hepatocellular carcinoma by label-free quantitative proteomics in two west african populations.

Background Hepatocellular Carcinoma is the third most common cause of cancer related death worldwide, often diagnosed by measuring serum AFP; a poor performance stand-alone biomarker. With the aim of improving on this, our study focuses on plasma proteins identified by Mass Spectrometry in order to investigate and validate differences seen in the respective proteomes of controls and subjects with LC and HCC. Methods Mass Spectrometry analysis using liquid chromatography electro spray ionization quadrupole time-of-flight was conducted on 339 subjects using a pooled expression profiling approach. ELISA assays were performed on four significantly differentially expressed proteins to validate their expression profiles in subjects from the Gambia and a pilot group from Nigeria. Results from this were collated for statistical multiplexing using logistic regression analysis. Results Twenty-six proteins were identified as differentially expressed between the three subject groups. Direct measurements of four; hemopexin, alpha-1-antitrypsin, apolipoprotein A1 and complement component 3 confirmed their change in abundance in LC and HCC versus control patients. These trends were independently replicated in the pilot validation subjects from Nigeria. The statistical multiplexing of these proteins demonstrated performance comparable to or greater than ALT in identifying liver cirrhosis or carcinogenesis. This exercise also proposed preliminary cut offs with achievable sensitivity, specificity and AUC statistics greater than reported AFP averages. Conclusions The validated changes of expression in these proteins have the potential for development into high-performance tests usable in the diagnosis and or monitoring of HCC and LC patients. The identification of sustained expression trends strengthens the suggestion of these four proteins as worthy candidates for further investigation in the context of liver disease. The statistical combinations also provide a novel inroad of analyses able to propose definitive cut-offs and combinations for evaluation of performance

Entanglement Entropy from a Holographic Viewpoint

The entanglement entropy has been historically studied by many authors in order to obtain quantum mechanical interpretations of the gravitational entropy. The discovery of AdS/CFT correspondence leads to the idea of holographic entanglement entropy, which is a clear solution to this important problem in gravity. In this article, we would like to give a quick survey of recent progresses on the holographic entanglement entropy. We focus on its gravitational aspects, so that it is comprehensible to those who are familiar with general relativity and basics of quantum field theory.Comment: Latex, 30 pages, invited review for Classical and Quantum Gravity, minor correction