2,758 research outputs found
Solvent Exfoliation of Electronic-Grade, Two-Dimensional Black Phosphorus
Solution dispersions of two-dimensional (2D) black phosphorus (BP), often
referred to as phosphorene, are achieved by solvent exfoliation. These
pristine, electronic-grade BP dispersions are produced with anhydrous, organic
solvents in a sealed tip ultrasonication system, which circumvents BP
degradation that would otherwise occur via solvated oxygen or water. Among
conventional solvents, n-methyl-pyrrolidone (NMP) is found to provide stable,
highly concentrated (~0.4 mg/mL) BP dispersions. Atomic force microscopy,
scanning electron microscopy, transmission electron microscopy, Raman
spectroscopy, and X-ray photoelectron spectroscopy show that the structure and
chemistry of solvent-exfoliated BP nanosheets are comparable to mechanically
exfoliated BP flakes. Additionally, residual NMP from the liquid-phase
processing suppresses the rate of BP oxidation in ambient conditions.
Solvent-exfoliated BP nanosheet field-effect transistors (FETs) exhibit
ambipolar behavior with current on/off ratios and mobilities up to ~10000 and
~50 cm^2/(V*s), respectively. Overall, this study shows that stable, highly
concentrated, electronic-grade 2D BP dispersions can be realized by scalable
solvent exfoliation, thereby presenting opportunities for large-area,
high-performance BP device applications.Comment: 6 figures, 31 pages, including supporting informatio
Multi-color Optical and NIR Light Curves of 64 Stripped-Envelope Core-Collapse Supernovae
We present a densely-sampled, homogeneous set of light curves of 64 low
redshift (z < 0.05) stripped-envelope supernovae (SN of type IIb, Ib, Ic and
Ic-bl). These data were obtained between 2001 and 2009 at the Fred L. Whipple
Observatory (FLWO) on Mt. Hopkins in Arizona, with the optical FLWO 1.2-m and
the near-infrared PAIRITEL 1.3-m telescopes. Our dataset consists of 4543
optical photometric measurements on 61 SN, including a combination of UBVRI,
UBVr'i', and u'BVr'i', and 2142 JHKs near-infrared measurements on 25 SN. This
sample constitutes the most extensive multi-color data set of stripped-envelope
SN to date. Our photometry is based on template-subtracted images to eliminate
any potential host galaxy light contamination. This work presents these
photometric data, compares them with data in the literature, and estimates
basic statistical quantities: date of maximum, color, and photometric
properties. We identify promising color trends that may permit the
identification of stripped-envelope SN subtypes from their photometry alone.
Many of these SN were observed spectroscopically by the CfA SN group, and the
spectra are presented in a companion paper (Modjaz et al. 2014). A thorough
exploration that combines the CfA photometry and spectroscopy of
stripped-envelope core-collapse SN will be presented in a follow-up paper.Comment: 26 pages, 17 figures, 8 tables. Revised version resubmitted to ApJ
Supplements after referee report. Additional online material is available
through http://cosmo.nyu.edu/SNYU
The Influence of a Biologically Relevant Substratum Topography on Human Aortic and Umbilical Vein Endothelial Cells
AbstractA topographically patterned substrate with stochastic surface order that closely mimics the topographic features of native basement membranes has been fabricated to investigate the influence of topographic biophysical cueing on human aortic and umbilical vein endothelial cells. The stochastic substrate was fabricated by first generating a highly porous polyelectrolyte multilayer film of poly(acrylic acid) and poly(allylamine hydrochloride) followed by replicate production of this biomimetic topography via soft lithography. These substrates, which are easy to prepare and replicate, possess a number of prominent features associated with in vivo vascular basement membrane (interwoven ridges and grooves, bumps, and pores), which have typically been studied as singular features that frequently possess anisotropic surface order (e.g., alternating ridges and grooves). When compared to a flat surface of identical chemistry, these biomimetic topographies influenced a number of important cellular behaviors associated with the homeostasis and degradation of vascular tissues. These include modulating cell migration rate and directional persistence, proliferation rate, and gene expression associated with regulation and remodeling of vascular tissues as well as inflammation
SPH Simulations of Direct Impact Accretion in the Ultracompact AM CVn Binaries
The ultracompact binary systems V407 Vul (RX J1914.4+2456) and HM Cnc (RX
J0806.3+1527) - a two-member subclass of the AM CVn stars - continue to pique
interest because they defy unambiguous classification. Three proposed models
remain viable at this time, but none of the three is significantly more
compelling than the remaining two, and all three can satisfy the observational
constraints if parameters in the models are tuned. One of the three proposed
models is the direct impact model of Marsh & Steeghs (2002), in which the
accretion stream impacts the surface of a rapidly-rotating primary white dwarf
directly but at a near-glancing angle. One requirement of this model is that
the accretion stream have a high enough density to advect its specific kinetic
energy below the photosphere for progressively more-thermalized emission
downstream, a constraint that requires an accretion spot size of roughly
1.2x10^5 km^2 or smaller. Having at hand a smoothed particle hydrodynamics code
optimized for cataclysmic variable accretion disk simulations, it was
relatively straightforward for us to adapt it to calculate the footprint of the
accretion stream at the nominal radius of the primary white dwarf, and thus to
test this constraint of the direct impact model. We find that the mass flux at
the impact spot can be approximated by a bivariate Gaussian with standard
deviation \sigma_{\phi} = 164 km in the orbital plane and \sigma_{\theta} = 23
km in the perpendicular direction. The area of the the 2\sigma ellipse into
which 86% of the mass flux occurs is roughly 47,400 km^2, or roughly half the
size estimated by Marsh & Steeghs (2002). We discuss the necessary parameters
of a simple model of the luminosity distribution in the post-impact emission
region.Comment: 24 pages, 5 figures, Accepted for publication in Ap
Ammonia decomposition catalysis using lithium–calcium imide
Lithium–calcium imide is explored as a catalyst for the decomposition of ammonia. It shows the highest ammonia decomposition activity yet reported for a pure light metal amide or imide, comparable to lithium imide–amide at high temperature, with superior conversion observed at lower temperatures. Importantly, the post-reaction mass recovery of lithium–calcium imide is almost complete, indicating that it may be easier to contain than the other amide–imide catalysts reported to date. The basis of this improved recovery is that the catalyst is, at least partially, solid across the temperature range studied under ammonia flow. However, lithium–calcium imide itself is only stable at low and high temperatures under ammonia, with in situ powder diffraction showing the decomposition of the catalyst to lithium amide–imide and calcium imide at intermediate temperatures of 200–460 °C.</p
LC-MS/MS Method for the determination of carbamathione in human plasma
Liquid chromatography-tandem mass spectrometry methodology is described for the determination of S-(N,N-diethylcarbamoyl)glutathione (carbamathione) in human plasma samples. Sample preparation consisted of a straightforward perchloric acid medicated protein precipitation, with the resulting supernatant containing the carbamathione (recovery ∼98%). For optimized chromatography/mass spec detection a carbamathione analog, S-(N,N-di-i-propylcarbamoyl)glutathione, was synthesized and used as the internal standard. Carbamathione was found to be stable over the pH 1-8 region over the timeframe necessary for the various operations of the analytical method. Separation was accomplished via reversed-phase gradient elution chromatography with analyte elution and re-equilibration accomplished within 8 minutes. Calibration was established and validated over the concentration range of 0.5-50 nM, which is adequate to support clinical investigations. Intra- and inter-day accuracy and precision determined and found to be < 4% and < 10%, respectively. The methodology was utilized to demonstrate the carbamathione plasma-time profile of a human volunteer dosed with disulfiram (250 mg/d). Interestingly, an unknown but apparently related metabolite was observed with each human plasma sample analyzed
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