56,994 research outputs found

    Effects of Compensation Strategy on Job Pay Decisions

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    Previous research has revealed wide variations in pay for the same job, even within a single locality. To date, however, the sources of such pay differentials are not well understood. The present research investigates how compensation managers from a wide variety of organizations combine infonnation about current job pay rates, market rates, and job evaluation points to arrive at new pay rates for jobs. In addition, it examines the role of two pay strategy variables (pay leadership position and external versus internal orientation) in job pay decisions, controlling for differences in organizational demographic characteristics (e.g., size, industry). Results suggest that pay strategies affect assigned pay levels, with higher pay being assigned by managers from fmns with market-leading strategies and internal pay orientations. In addition, pay strategies appear to influence the relative weights attached to market survey versus job evaluation infonnation in pay-setting for jobs. Specifically, although market survey information consistently explained more variance in assigned pay than did job evaluation, this effect was more pronounced among managers from finns having an external orientation. Organizational demographics also affected assigned pay levels, but to a lesser extent than pay strategies

    Stereoselective formation of a 2 prime (3 prime)- aminoacyl ester of a nucleotide

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    Reaction of DL-series and adenosine-5-phosphorimidazolide in the presence of adenosine-5'-(0-methylphosphate) and imidazole resulted in the stereoselective synthesis of the aminoacyl nucleotide ester, 2'(3')-0-seryl-adenosine-5'-(0-methylphosphate). The enantiomeric excess of D-serine incorporated into 2'(3')-0-seryl-adenosine-5'-(0-methylphosphate) was about 9%. Adenylyl-(5->N)-serine and an unknown product also incorporated an excess of D-serine, however, seryl-serine showed an excess of L-serine. The relationship of these results to the origin of the biological pairing of L-amino acids and nucleotides containing D-ribose is discussed

    Theory and Observation of Displacement Phenomena in Coadsorbed Films

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    Displacement refers to a surprising phenomenon observed in a number of adsorption systems. At low temperatures, some relatively inert gases, such as krypton (Kr) or methane ( CH4), are found to displace molecules from preadsorbed monolayer films of a more condensable species, such as carbon tetrachloride ( CCl4), from a graphite substrate. We present a simple thermodynamic model to explain displacement and make a prediction applicable to both first-order and continuous displacement processes. We also present measurements on CH4/CCl4 and Kr/CCl4 coadsorbed films from 77–112 K that verify our prediction and yield the CCl4 film spreading pressure

    Coadsorption phase diagram for Kr/CCl4 on graphite

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    We present the results of an extensive calorimetric study of krypton coadsorbed on graphite precoated with a saturated monolayer of carbon tetrachloride. Combining the heat capacity data with film equation of state measurements from a previous study [W. J. Weber and D. L. Goodstein, Phys. Rev. Lett. 83, 3888 (1999)] permits construction of the Kr/CCl4 coadsorption phase diagram between 77 and 130 K. Kr succeeds in displacing the CCl4 from the surface, by a continuous process which results, at lower temperatures, in a film indistinguishable from that of pure Kr adsorbed on graphite. At higher temperatures, a new first-order phase transition, unique to the coadsorption system, is observed and likely indicates a transition to a mixed Kr/CCl4 film. Finally, measurements at higher Kr coverages reveal evidence for a high temperature extension of the reentrant layering phenomena previously observed for Kr on graphite

    The Robber Flies (Diptera: Asilidae) of the Albany Pinebush

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    The Albany Pinebush, a pitch pine-scrub oak sand barrens, was examined for robber flies and the results compared to historical records found in the New York State Museum, Albany. Thirty-six species were recorded of which seventeen were new records. Two species, Cyrtopogon laphriformis and Promachus bastardii, last recorded in 1914 and 1931, respectively, were not located in the survey
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