Specific heat study of the Na(0.3)CoO(2).1.3H(2)O superconductor: influence of the complex chemistry

We report results of specific heat measurements on polycrystalline samples of the layered superconductor, Na(0.3)CoO(2).1.3H(2)O. The electronic contribution to the specific heat, gamma, is found to be 12.2 mJ/mol-K2. The feature at the superconducting transition is rather sharp, becoming broad and strongly suppressed in an applied magnetic field. The data indicate a residual normal state electronic specific heat at low temperatures, implying that there is a sizable population of normal state electrons in the samples even below Tc. Inhomogeneity in the Na content, to which the superconducting state is exquisitely sensitive, appears to be the most likely explanation for these results. These results further indicate that special sample handling is required for an accurate characterization of the superconducting state in this material.Comment: publication information adde

Carrier Tuning of Stoner Ferromagnetism in ThCr2Si2-Structure Cobalt Arsenides

CaCo2-yAs2 is an unusual itinerant magnet with signatures of extreme magnetic frustration. The conditions for establishing magnetic order in such itinerant frustrated magnets, either by reducing frustration or increasing electronic correlations, is an open question. Here, we use results from inelastic neutron scattering and magnetic susceptibility measurements and density functional theory calculations to show that hole doping in Ca(Co1-xFex)(2-y)As-2 suppresses magnetic order by quenching the magnetic moment while maintaining the same level of magnetic frustration. The suppression is due to tuning the Fermi energy away from a peak in the electronic density of states originating from a flat conduction band. This results in the complete elimination of the magnetic moment by x approximate to 0.25, providing a clear example of a Stoner-type transition.This article is published as Ueland, B. G., Santanu Pakhira, Bing Li, A. Sapkota, N. S. Sangeetha, T. G. Perring, Y. Lee, Liqin Ke, D. C. Johnston, and R. J. McQueeney. "Carrier tuning of Stoner ferromagnetism in ThCr 2 Si 2-structure cobalt arsenides." Physical Review B 104, no. 22 (2021): L220410. DOI: 10.1103/PhysRevB.104.L220410. Copyright 2021 American Physical Society. DOE Contract Number(s): AC02-07CH11358. Posted with permission

Structural disorder and properties of the stuffed pyrochlore Ho2TiO5

Applied Science

Magnetization dynamics and frustration in the multiferroic double perovskite Lu2MnCoO6

We investigate the magnetic ordering and the magnetization dynamics (from kHz to THz time scales) of the double perovskite Lu2MnCoO6 using elastic neutron diffraction, muon spin relaxation, and micro-Hall magnetization measurements. This compound is known to be a type II multiferroic with the interesting feature that a ferromagneticlike magnetization hysteresis loop couples to an equally hysteretic electric polarization in the bulk of the material despite a zero-field magnetic ordering of the type ↑↑↓↓ along Co-Mn spin chains. Here we explore the unusual dynamics of this compound and find extremely strong fluctuations, consistent with the axial next-nearest-neighbor Ising (ANNNI) model for frustrated spin chains. We identify three temperature scales in Lu2MnCoO6 corresponding to the onset of highly fluctuating long-range order below TN=50±3 K identified from neutron scattering, the onset of magnetic and electric hysteresis, with change in kHz magnetic and electric dynamics below a 30 K temperature scale, and partial freezing of ∼MHz spin fluctuations in the muon spin relaxation data below 12±3 K. Our results provide a framework for understanding the multiferroic behavior of this compound and its hysteresis and dynamics