Ultrafast Transient Dynamics of Adsorbates on Surfaces Deciphered: The Case of CO on Cu(100)

Time-resolved vibrational spectroscopy constitutes an invaluable experimental tool for monitoring hot-carrier induced surface reactions. However, the absence of a full understanding on the precise microscopic mechanisms causing the transient spectral changes has been limiting its applicability. Here we introduce a robust first-principles theoretical framework that successfully explains both the nonthermal frequency and linewidth changes of the CO internal stretch mode on Cu(100) induced by femtosecond laser pulses. Two distinct processes engender the changes: electron-hole pair excitations underlie the nonthermal frequency shifts, while electron-mediated vibrational mode coupling gives rise to linewidth changes. Furthermore, the origin and precise sequence of coupling events are finally identified.Comment: Article as accepted for publication in Physical Review Letters; 5 pages, 2 figures, 1 tabl

Frequency stability of maser oscillators operated with cavity Q

The short term frequency stability of masers equipped with an external feedback loop to increase the cavity quality factor was studied. The frequency stability of a hydrogen and a rubidium maser were measured and compared with theoretical evaluation. It is shown that the frequency stability passes through an optimum when the cavity Q is varied. Long term fluctuations are discussed and the optimum mid term frequency stability achievably by small size active and passive H-masers is considered

Superintegrability of the Tremblay-Turbiner-Winternitz quantum Hamiltonians on a plane for odd kk

In a recent FTC by Tremblay {\sl et al} (2009 {\sl J. Phys. A: Math. Theor.} {\bf 42} 205206), it has been conjectured that for any integer value of $k$, some novel exactly solvable and integrable quantum Hamiltonian $H_k$ on a plane is superintegrable and that the additional integral of motion is a $2k$th-order differential operator $Y_{2k}$. Here we demonstrate the conjecture for the infinite family of Hamiltonians $H_k$ with odd $k \ge 3$, whose first member corresponds to the three-body Calogero-Marchioro-Wolfes model after elimination of the centre-of-mass motion. Our approach is based on the construction of some $D_{2k}$-extended and invariant Hamiltonian \chh_k, which can be interpreted as a modified boson oscillator Hamiltonian. The latter is then shown to possess a $D_{2k}$-invariant integral of motion \cyy_{2k}, from which $Y_{2k}$ can be obtained by projection in the $D_{2k}$ identity representation space.Comment: 14 pages, no figure; change of title + important addition to sect. 4 + 2 more references + minor modifications; accepted by JPA as an FT

Spiral Magnets as Gapless Mott Insulators

In the large $U$ limit, the ground state of the half-filled, nearest-neighbor Hubbard model on the triangular lattice is the three-sublattice antiferromagnet. In sharp contrast with the square-lattice case, where transverse spin-waves and charge excitations remain decoupled to all orders in $t/U$, it is shown that beyond leading order in $t/U$ the three Goldstone modes on the triangular lattice are a linear combination of spin and charge. This leads to non-vanishing conductivity at any finite frequency, even though the magnet remains insulating at zero frequency. More generally, non-collinear spin order should lead to such gapless insulating behavior.Comment: 10 pages, REVTEX 3.0, 3 uuencoded postscript figures, CRPS-94-0

Water governance in two urban African contexts: agency and action through participatory video

This paper describes and critically examines the process and outcomes of a community-based participatory video (PV) research project on issues related to water governance with residents of underserved and informal settlements in Khayelitsha, South Africa and Accra, Ghana. Co-produced videos were used to facilitate communication and to open a dialogue between the participating communities and their respective local governments, with the aims of improving awareness of the issues, enhancing agency and enabling participation in the political and social debates about water governance. Analysing the approach, our research draws on two key principles of participatory governance – recognition and response – to evaluate the application of PV as a potential engagement tool for participatory water governance. We critically discuss the reality and tensions of PV in shifting deep-rooted inequities of power in decision making through two case studies, both of which involved residents and representatives from local governments in the research process

Spin susceptibility of interacting electrons in one dimension: Luttinger liquid and lattice effects

The temperature-dependent uniform magnetic susceptibility of interacting electrons in one dimension is calculated using several methods. At low temperature, the renormalization group reaveals that the Luttinger liquid spin susceptibility $\chi (T)$ approaches zero temperature with an infinite slope in striking contrast with the Fermi liquid result and with the behavior of the compressibility in the absence of umklapp scattering. This effect comes from the leading marginally irrelevant operator, in analogy with the Heisenberg spin 1/2 antiferromagnetic chain. Comparisons with Monte Carlo simulations at higher temperature reveal that non-logarithmic terms are important in that regime. These contributions are evaluated from an effective interaction that includes the same set of diagrams as those that give the leading logarithmic terms in the renormalization group approach. Comments on the third law of thermodynamics as well as reasons for the failure of approaches that work in higher dimensions are given.Comment: 21 pages, latex including 5 eps figure