102 research outputs found

    CHEM 452.01: Descriptive Inorganic Chemistry

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    Echo Behavior In Large Populations Of Chemical Oscillators

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    Experimental and theoretical studies are reported, for the first time, on the observation and characterization of echo phenomena in oscillatory chemical reactions. Populations of uncoupled and coupled oscillators are globally perturbed. The macroscopic response to this perturbation dies out with time: At some time Ï„ after the perturbation (where Ï„ is long enough that the response has died out), the system is again perturbed, and the initial response to this second perturbation again dies out. Echoes can potentially appear as responses that arise at 2Ï„,3Ï„,... after the first perturbation. The phase-resetting character of the chemical oscillators allows a detailed analysis, offering insights into the origin of the echo in terms of an intricate structure of phase relationships. Groups of oscillators experiencing different perturbations are analyzed with a geometric approach and in an analytical theory. The characterization of echo phenomena in populations of chemical oscillators reinforces recent theoretical studies of the behavior in populations of phase oscillators [E. Ott et al., Chaos 18, 037115 (2008)]. This indicates the generality of the behavior, including its likely occurrence in biological systems

    Link Weight Evolution In A Network Of Coupled Chemical Oscillators

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    Link weight evolution is studied in a network of coupled chemical oscillators. Oscillators are perturbed by adjustments in imposed light intensity based on excitatory or inhibitory links to other oscillators undergoing excitation. Experimental and modeling studies demonstrate that the network is capable of producing sustained coordinated activity. The individual nodes of the network exhibit incoherent firing events; however, a dominant frequency can be discerned within the collective signal by Fourier analysis. The introduction of spike-timingdependent plasticity yields a network that evolves to a stable unimodal link weight distribution

    Link weight evolution in a network of coupled chemical oscillators

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    Link weight evolution is studied in a network of coupled chemical oscillators. Oscillators are perturbed by adjustments in imposed light intensity based on excitatory or inhibitory links to other oscillators undergoing excitation. Experimental and modeling studies demonstrate that the network is capable of producing sustained coordinated activity. The individual nodes of the network exhibit incoherent firing events; however, a dominant frequency can be discerned within the collective signal by Fourier analysis. The introduction of spike-timingdependent plasticity yields a network that evolves to a stable unimodal link weight distribution
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