A wave-mechanical treatment of the Mills-Nixon effect

The Mills-Nixon effect has been examined by a very simple wave-mechanical treatment. This has led to the conclusion that the effect of saturated side rings upon the ratio of the coefficients of the wave-functions of the two Kekulé structures is relatively small, being not more than about 6 per cent., and that the benzene ring retains the greater part of its stabilising resonance energy. Nevertheless, making the reasonable assumption that the ratio of the activation energies, for reaction as either one of the two Kekulé structures, depends upon the square of the ratio of coefficients, it is possible to account for the experimental facts. The effect which bending two valencies has upon the angles between the other valencies projecting from the benzene ring is found to be very small

Comparison of Torpedograss and Pickerelweed Susceptibility to Glyphosate

Torpedograss (Panicum repens L.) is one of the most invasive exotic plants in aquatic systems. Repeat applications of (N-phosphonomethyl) glycine (glyphosate) herbicides provide limited control of torpedograss; unfortunately, glyphosate often negatively impacts most non-target native species that grow alongside the weed. This experiment studied the effect of glyphosate on pickerelweed (Pontederia cordata L.), a native plant that shares habitats with torpedograss. Actively growing plants of torpedograss and pickerelweed were cultured in 8-liter containers and sprayed to wet with one of four rates of glyphosate: 0%, 0.75%, 1.0%, or 1.5%. Each treatment included a surfactant to aid in herbicide uptake and a surface dye to verify uniform application of the treatments. All herbicide treatments were applied with a backpack sprayer to intact plants and to cut stubble of both species. Four replicates were treated for each species-rategrowth combination during each of two experiment periods. Plant dry weights 8 weeks after herbicide application suggest that torpedograss was effectively controlled by the highest rate of glyphosate applied to cut stubble. Pickerelweed was unaffected when the highest rate of glyphosate was applied as a cut-and-spray treatment. These data suggest that a cut-and-spray application of a 1.5% solution of glyphosate may be an effective strategy to control torpedograss without deleteriously affecting pickerelweed. (PDF contains 4 pages.

Navigating the challenges of professionalising sales careers: a case for degree apprenticeships in sales

This thesis presents the narrative of my navigation through factors, both actual and philosophical, which I encountered during the development of my public works (PWs) of two, sales degree apprenticeships. It weaves together themes of stigma, bureaucracy, employer culture and complexity whilst addressing what constitutes ‘professionalism’ within the new and emerging professions of this VUCA (volatile, uncertain, complex, and ambiguous) period of change in the business environment. The key methodologies which inform my approach to the critique of my works are autoethnography and reflective practice. These were achieved using a new coaching framework that I developed (C-E-D-A-R) specifically for this enquiry, recognising the complexity of the public works development ecosystem and the need for a framework to address all the dynamic elements and agencies within it. Enquiring into the ecosystem using C-E-D-A-R, I address the microsystem, mesosystem and macrosystem it supports, and identify the insights and outcomes emerging from the critique of the public works which expanded the possibilities for the ecosystem to maintain balance and relevance and to continue to thrive

The impact of resolution on the adjustment and decadal variability of the Atlantic Meridional Overturning Circulation in a coupled climate model

Variations in the Atlantic Meridional Overturning Circulation (MOC) exert an important influence on climate, particularly on decadal time scales. Simulation of the MOC in coupled climate models is compromised, to a degree that is unknown, by their lack of fidelity in resolving some of the key processes involved. There is an overarching need to increase the resolution and fidelity of climate models, but also to assess how increases in resolution influence the simulation of key phenomena such as the MOC. In this study we investigate the impact of significantly increasing the (ocean and atmosphere) resolution of a coupled climate model on the simulation of MOC variability by comparing high and low resolution versions of the same model. In both versions, decadal variability of the MOC is closely linked to density anomalies that propagate from the Labrador Sea southward along the deep western boundary. We demonstrate that the MOC adjustment proceeds more rapidly in the higher resolution model due the increased speed of western boundary waves. However, the response of the Atlantic Sea Surface Temperatures (SSTs) to MOC variations is relatively robust - in pattern if not in magnitude - across the two resolutions. The MOC also excites a coupled ocean-atmosphere response in the tropical Atlantic in both model versions. In the higher resolution model, but not the lower resolution model, there is evidence of a significant response in the extratropical atmosphere over the North Atlantic 6 years after a maximum in the MOC. In both models there is evidence of a weak negative feedback on deep density anomalies in the Labrador Sea, and hence on the MOC (with a time scale of approximately ten years). Our results highlight the need for further work to understand the decadal variability of the MOC and its simulation in climate models

Plants for predators - a participatory experiment

Encouraging natural enemies by growing attractant plants is a highly effective method of pest control in organic systems. However, it is important to establish which plants are most effective at attracting benefi cial insects. Experiments were carried out by 179 HDRA members, who grew four plant species (Coriander, Corn Marigold, Fennel and Phacelia) in their gardens and allotments. Over the course of the growing season, assessments were made on the growth and flowering of the plants and the presence of four key groups of beneficial insect (ladybirds, hoverflies, lacewings and parasitic wasps). Phacelia established quickly and its long flowering period meant it attracted insects throughout the summer. However, Phacelia was only the most attractive plant at the end of the season and insects preferred the other trial plants when they were in flower. Results highlight the importance of growing a range of flowering plants to provide resources for beneficials throughout their activity period

Hybrid mean field and real space model for vacancy diffusion-mediated annealing of radiation defects

In a fusion or advanced fission reactor, high energy neutrons induce the formation of extended defect clusters in structural component materials, degrading their properties over time. Such damage can be partially recovered via a thermal annealing treatment. Therefore, for the design and operation of fusion and advanced fission nuclear energy systems it is critical to estimate and predict the annealing timescales for arbitrary configurations of defect clusters. In our earlier paper [I. Rovelli, S. L. Dudarev, and A. P. Sutton, J. Mech. Phys. Solids 103, 121 (2017)] we extended the Green function formulation by Gu, Xiang et al. [Y. Gu, Y. Xiang, S. S. Quek, and D. J. Srolovitz, J. Mech. Phys. Solids 83, 319 (2015)] for the climb of curved dislocations, to include the evaporation and growth of cavities and vacancy clusters, and take into account the effect of free surfaces. In this work, we further develop this model to include the effect of radiation defects that are below the experimental detection limit, via a mean field approach coupled with an explicit treatment of the evolution of discrete defect clusters distributed in real space. We show that randomly distributed small defects screen diffusive interactions between larger discrete clusters. The evolution of the coupled system is modelled self-consistently. We also simulate the evolution of defects in an infinite laterally extended thin film, using the Ewald summation of screened Yukawa-type diffusive propagators

Current and Future Constraints on Primordial Magnetic Fields

We present new limits on the amplitude of potential primordial magnetic fields (PMFs) using temperature and polarization measurements of the cosmic microwave background (CMB) from Planck, BICEP2/Keck Array, POLARBEAR, and SPTpol. We reduce twofold the 95% CL upper limit on the CMB anisotropy power due to a nearly-scale-invariant PMF, with an allowed B-mode power at $\ell=1500$ of $D_{\ell=1500}^{BB} < 0.071 \mu K^2$ for Planck versus $D_{\ell=1500}^{BB} < 0.034 \mu K^2$ for the combined dataset. We also forecast the expected limits from soon-to-deploy CMB experiments (like SPT-3G, Adv. ACTpol, or the Simons Array) and the proposed CMB-S4 experiment. Future CMB experiments should dramatically reduce the current uncertainties, by one order of magnitude for the near-term experiments and two orders of magnitude for the CMB-S4 experiment. The constraints from CMB-S4 have the potential to rule out much of the parameter space for PMFs.Comment: Submitted to ApJ, 10 page

Species Composition and Diversity of Hawk Populations in Northeastern Arkansas

Species composition and diversity of hawk populations were analyzed for northeastern Arkansas by the use of roadside censuses conducted in September through April from 1974- 1977. Data from 10 years of Jonesboro Christmas Bird Counts were also analyzed. During the roadside survey 20,174 miles were driven and 1819 raptors were counted. Ten species were observed with the Red-tailed Hawk being most abundant followed by the Marsh Hawk and the American Kestrel. Eight species were recorded from the 10 years of Christmas Bird Counts. Annual breeding bird surveys and spot records turned up three additional species making a total of 14 species in 15 years of study. Although hawk populations fluctuate from year to year, the data do not reveal any downward trend in numbers in northeastern Arkansas. Large concentrations of hawks do not appear in this region of the state until after mid-September. Populations reach a peak in December after which they decline in January. A second peak is reached in February followed by a gradual decline such that in April the American Kestrel is the only species consistently seen from the roadside. After April only a few hawks remain to nest. Both Krider\u27s and melanistic Red-tails occur here but from a total of 864 Red-tailed Hawks observed only 26 Krider\u27s and 31 melanistic or Buteo iamaicensis harlanii were recorded