Study of the applicability of fe nanotubes as an anode material of lithium-ion batteries

The paper presents the results of the use of iron nanotubes as the anode material of lithiumion batteries. To assess the degradation of the morphology of nanostructures after different numbers of cycles of life tests, the method of scanning electron microscopy, Mossbauer spectroscopy, and X-ray diffraction analysis were applied. It is shown that the decrease in discharge capacity starts at the 380th cycle and is caused by the onset of degradation processes of nanostructures due to the formation of amorphous inclusions and an increase in macrostresses and distortions in the structure. The complete degradation of the structure is observed after the 492nd life cycle test. According to the data obtained by Mossbauer spectroscopy, it has been established that an increase in life cycles leads to an increase in contribution of partial spectrum characteristic of a paramagnetic state. That indicates an increase in degradation rate of nanostructures and an increase in the content of impurity inclusions and amorphous formations in the crystal structure. © 2019, Electromagnetics Academy. All rights reserved

The world market of services: features and trends of development

The global market of services is one of the fundamental aspects of modern international financial relations, despite the fact that it is still in a period of intense development, which is occurring at a rapid pace

Localizing and Quantifying Carotenoids in Intact Cells and Tissues

Raman spectroscopy provides detailed information about the molecular structure of carotenoids. Advances in detector sensitivity and acquisition speed have driven the expansion of Raman spectroscopy from a bulk analytical tool to a powerful method for mapping carotenoid abundance in cells and tissues. In many applications, the technique is compatible with living organisms, providing highly specific molecular structure information in intact cells and tissues with subcellular spatial resolution. This leads to spatial-temporal-chemical resolution critical to understanding the complex processes in the life cycle of carotenoids and other biomolecules

Evaluation of the Efficiency of Detection and Capture of Manganese in Aqueous Solutions of FeCeOx Nanocomposites Doped with Nb2O5

: The main purpose of this work is to study the effectiveness of using FeCeOx nanocomposites doped with Nb2O5 for the purification of aqueous solutions from manganese. X-ray diffraction, energy-dispersive analysis, scanning electron microscopy, vibrational magnetic spectroscopy, and mössbauer spectroscopy were used as research methods. It is shown that an increase in the dopant concentration leads to the transformation of the shape of nanoparticles from spherical to cubic and rhombic, followed by an increase in the size of the nanoparticles. The spherical shape of the nanoparticles is characteristic of a structure consisting of a mixture of two phases of hematite (Fe2O3) and cerium oxide CeO2. The cubic shape of nanoparticles is typical for spinel-type FeNbO4 structures, the phase contribution of which increases with increasing dopant concentration. It is shown that doping leads not only to a decrease in the concentration of manganese in model solutions, but also to an increase in the efficiency of adsorption from 11% to 75%

Template synthesis and magnetic characterization of FeNi nanotubes

Iron-nickel nanotubes consisting of 20% Ni and 80% Fe with an aspect ratio of about 100 were synthesized by electrochemical deposition in the pores of polyethylene terephthalate ion-track membranes. The main morphological parameters such as composition, wall thickness and structural characteristics were defined. Macro- and micromagnetic parameters of FeNi nanotubes were determined. © 2017, Electromagnetics Academy. All rights reserved

Structural and magnetic studies of FE100–xCox nanotubes obtaine by template method

Hollow nanostructures based on the Fe100–xCox alloy were synthesized in the pores of polymer template matrices based on PET using the electrochemical deposition method. Morphology, elemental composition, and structural features were characterized by scanning electron microscopy, energy dispersive analysis, and X-ray diffractometry. The study of the internal magnetic texture was carried out using Mossbauer spectroscopy. The dependence of the change in structural and magnetic properties from the atomic content of components in nanotube structure is revealed. It is established that the synthesized nanostructures are hollow Fe100–xCox nanotubes with a body-centered cubic crystal structure. The decrease in the unit cell parameter with increasing cobalt concentration is due to the difference in the radii of Fe (1.227 Å) and Co (1.191 Å) atoms. It is established that a random distribution of magnetic moments directions of Fe atoms is observed for Fe100Co0 nanotubes. And magnetic texture along the nanotube axis is observed for Fe100–xCox nanotubes, with an increase in Co atoms concentration. The average angle between the direction of the magnetic moment of iron atoms and the nanotube axis decreases from v = 54:6° to v = 24:5°. © 2018, Electromagnetics Academy. All rights reserved

Catalytic Activity of Ni Nanotubes Covered with Nanostructured Gold

Ni nanotubes (NTs) were produced by the template method in the pores of ion-track membranes and then were successfully functionalized with gold nanoparticles (Ni@Au NTs) using electroless wet-chemical deposition with the aim to demonstrate their high catalytic activity. The fab-ricated NTs were characterized using a variety of techniques in order to determine their morphology and dimensions, crystalline structure, and magnetic properties. The morphology of Au coating de-pended on the concentration of gold chloride aqueous solution used for Au deposition. The catalytic activity was evaluated by a model reaction of the reduction of 4-nitrophenol by borohydride ions in the presence of Ni and Ni@Au NTs. The reaction was monitored spectrophotometrically in real time by detecting the decrease in the absorption peaks. It was found that gold coating with needle-like structure formed at a higher Au-ions concentration had the strongest catalytic effect, while bare Ni NTs had little effect. The presence of a magnetic core allowed the extraction of the catalyst with the help of a magnetic field for reusable applications. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.Funding: The work was carried out with the support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the State Task (project code 0718-2020-0037)

Mechanical Activation of Al-Oxyhydroxide Minerals – Physicochemical Changes, Reactivity and Relevance to Bayer Process

Overview of our research on ‘structure and reactivity’ of gibbsite and boehmite under varied conditions of mechanical activation, e.g. milling energy and presence of a second phase is presented. Bulk and surface changes induced in the solids by milling are characterized in terms of morphology, particle size distribution, specific surface area and nature of porosity, crystallite size and zeta potential. Results on enhanced amorphisation of gibbsite in presence of a second phase (quartz, hematite etc), changes in zeta potential of gibbsite due to loss of texture during milling and anomalous decrease in surface area of boehmite during milling are reported. Reactivity of the activated solids in sodium hydroxide and variation in thermal transformation temperatures is correlated with physicochemical characteristics of the samples and plausible explanation for the observed correlations presented. Significance of the results with specific reference to bauxite and alumina processing in Bayer process is highlighted