A period of calm in Scottish seas: a comprehensive study of ΔR values for the northern British Isles coast and the consequent implications for archaeology and oceanography

The Marine Radiocarbon Reservoir Effect (MRE) is a 14C age offset between contemporaneous marine- and terrestrially-derived carbon. In Northern Hemisphere surface waters it is of the order of 400 years but temporal and spatial deviations, known as ΔR, occur. This study provides a comprehensive dataset of 21 ΔR and MRE values for the east coast of Scotland and 21 recalculated values for the west coast of Scotland and Ireland, for the period c. 3500 BC to 1450 AD. They are presented as mean, site-specific ΔR and MRE values, together with their associated uncertainties, calculated as standard errors for predicted values. The ΔR values range from -320 ± 35 to +150 ± 28 14C years and show no spatial or temporal trends. The MRE values range from 59 ± 40 to 531 ± 26, show an almost identical distribution pattern to the ΔR values and again show no spatial or temporal trends. Results show that ΔR values calculated for a single site using statistically indistinguishable groups of terrestrial and marine radiocarbon age measurements can produce variability of up to 225 14C years. ΔR is an important factor in the accurate calibration of samples containing marine-derived carbon for archaeological interpretation but is often also used as an indicator of changes in 14C specific activity of the oceans, and therefore a proxy for changes in ocean circulation and/or climate. Using the methods outlined in this paper, it is apparent that ΔR values for the northern part of the British Isles have been relatively stable, within our ability to quantify non-random variation in the data. The fact that significant climatic shifts have been recorded during this time, yet these are not visible in the ΔR data, presents a cautionary tale regarding the use of ΔR to infer large-scale oceanographic or climatic changes. Upon the exclusion of 5 outliers from the 42 values, the remaining ΔR values are statistically indistinguishable from one another and range from -142 ± 61 to +40 ± 47 14C years. 34 of these values are from Scottish archaeological sites and can be combined to produce a mean value for Scotland of -47 ± 52 14C years for the period 3500 BC to 1450 AD, to be used only in the absence of site- and period-specific data

Ecohydrologic significance of hydraulic redistribution in a semiarid savanna

Journal ArticleRecent studies have illuminated the process of hydraulic redistribution, defined as the translocation of soil moisture via plant root systems, but the long-term ecohydrologic significance of this process is poorly understood. Copyright [year] American Geophysical Union. Reproduced by permission of American Geophysical Union. Further reproduction or electronic distribution is not permitted

Predicted growth of through-thickness stress corrosion cracks in anhydrous ammonia nurse tanks

Anhydrous ammonia is a toxic material that is transported from distribution centers to farm fields in steel pressure vessels called nurse tanks. Numerous accidents have occurred in which nurse tanks failed and ammonia was released, often with explosive force. The majority of such accidents are caused by stress corrosion cracking of the tank steel. Stress corrosion cracking is caused by the combination of stress in the tank\u27s steel and the corrosive effect of ammonia. Neutron diffraction analysis was used to map the residual stress state in and near circumferential welds from two used anhydrous ammonia nurse tanks, one manufactured in 1966 and the other manufactured in 1986. Notched SA455 steel test specimens were held under tensile load (stress concentration factors of 40 to 80 MPam) while immersed in NH3 for seven months to generate crack propagation rate data. The results from these measurements were then used to predict stress corrosion crack growth rates for various pre-existing crack sizes at various temperatures. These data may be useful for estimating safe service lifetimes of nurse tanks that contain cracks

Partitioning of evapotranspiration and its relation to carbon dioxide exchange in a Chihuahuan Desert shrubland

Key to evaluating the consequences of woody plant encroachment on water and carbon cycling in semiarid ecosystems is a mechanistic understanding of how biological and non-biological processes influence water loss to the atmosphere. To better understand how precipitation is partitioned into the components of evapotranspiration (bare-soil evaporation and plant transpiration) and their relationship to plant uptake of carbon dioxide (CO2) as well as ecosystem respiratory efflux, we measured whole plant transpiration, evapotranspiration, and CO2 fluxes over the course of a growing season at a semiarid Chihuahuan Desert shrubland site in south-eastern Arizona. Whole plant transpiration was measured using the heat balance sap-flow method, while evapotranspiration and net ecosystem exchange (NEE) of CO2 were quantified using the Bowen ratio technique

Dynamical two electron states in a Hubbard-Davydov model

We study a model in which a Hubbard Hamiltonian is coupled to the dispersive phonons in a classical nonlinear lattice. Our calculations are restricted to the case where we have only two quasi-particles of opposite spins, and we investigate the dynamics when the second quasi-particle is added to a state corresponding to a minimal energy single quasi-particle state. Depending on the parameter values, we find a number of interesting regimes. In many of these, discrete breathers (DBs) play a prominent role with a localized lattice mode coupled to the quasiparticles. Simulations with a purely harmonic lattice show much weaker localization effects. Our results support the possibility that DBs are important in HTSC.Comment: 14 pages, 12 fig

A new method for strengthening gold

Metal-metal composites were first produced in a copper matrix in the 1970’s, and they have since been produced in several other binary metal systems. This strengthening technique reinforces a ductile metal matrix with a ductile metal second phase. In some binary systems, this technique confers extraordinarily high strength and hardness while still maintaining low electrical resistivity. This article reports on the first gold matrix metal-metal composite, which was produced by deformation processing a 90%Au-10%Ag powder compact. The Au-Ag specimen studied had an ultimate tensile strength of 550 MPa and an electrical resistivity only 8% higher than that of pure Au at a deformation processing true strain of 5.6. The 590 nm average Ag filament thickness in this composite was relatively coarse compared to other deformation processed composites, which suggests that substantially higher strengths would be possible in a gold matrix metal-metal composite using deformation processing to higher true strains to reduce the filament thickness

Ground Snow Loads for ASCE 7-22 – What Has Changed and Why?

The changes to the ASCE 7 ground snow load maps proposed for the 2022 edition target a uniform reliability rather than a uniform hazard – an important distinction – and are the first of their kind in ASCE 7. Previously, the ASCE 7 snow loads used a uniform-hazard 50-year mean recurrence interval (MRI) with a 1.6 load factor. The newly proposed loads directly target the safety levels stipulated in Chapter 1 of ASCE 7, resulting in a strength design level load that is to be used with a load factor of 1.0. This paper describes changes in design provisions that result from this transition to reliability-targeted loads and provides reasons for some of these differences