2,853 research outputs found
Mode-coupling theory for structural and conformational dynamics of polymer melts
A mode-coupling theory for dense polymeric systems is developed which
unifyingly incorporates the segmental cage effect relevant for structural
slowing down and polymer chain conformational degrees of freedom. An ideal
glass transition of polymer melts is predicted which becomes molecular-weight
independent for large molecules. The theory provides a microscopic
justification for the use of the Rouse theory in polymer melts, and the results
for Rouse-mode correlators and mean-squared displacements are in good agreement
with computer simulation results.Comment: 4 pages, 3 figures, Phys. Rev. Lett. in pres
Orbits in the H2O molecule
We study the forms of the orbits in a symmetric configuration of a realistic
model of the H2O molecule with particular emphasis on the periodic orbits. We
use an appropriate Poincar\'e surface of section (PSS) and study the
distribution of the orbits on this PSS for various energies. We find both
ordered and chaotic orbits. The proportion of ordered orbits is almost 100% for
small energies, but decreases abruptly beyond a critical energy. When the
energy exceeds the escape energy there are still non-escaping orbits around
stable periodic orbits. We study in detail the forms of the various periodic
orbits, and their connections, by providing appropriate stability and
bifurcation diagrams.Comment: 21 pages, 14 figures, accepted for publication in CHAO
Phase separation in suspensions of colloids, polymers and nanoparticles: Role of solvent quality, physical mesh, and nonlocal entropic repulsion
Structure and thermodynamics of colloid-polymer mixtures: a macromolecular approach
The change of the structure of concentrated colloidal suspensions upon
addition of non-adsorbing polymer is studied within a two-component,
Ornstein-Zernicke based liquid state approach. The polymers' conformational
degrees of freedom are considered and excluded volume is enforced at the
segment level. The polymer correlation hole, depletion layer, and excess
chemical potentials are described in agreement with polymer physics theory in
contrast to models treating the macromolecules as effective spheres. Known
depletion attraction effects are recovered for low particle density, while at
higher densities novel many-body effects emerge which become dominant for large
polymers.Comment: 7 pages, 4 figures; to be published in Europhys. Let
Composite fermions in periodic and random antidot lattices
The longitudinal and Hall magnetoresistance of random and periodic arrays of artificial scatterers, imposed on a high-mobility two-dimensional electron gas, were investigated in the vicinity of Landau level filling factor ν=1/2. In periodic arrays, commensurability effects between the period of the antidot array and the cyclotron radius of composite fermions are observed. In addition, the Hall resistance shows a deviation from the anticipated linear dependence, reminiscent of quenching around zero magnetic field. Both effects are absent for random antidot lattices. The relative amplitude of the geometric resonances for opposite signs of the effective magnetic field and its dependence on illumination illustrate enhanced soft wall effects for composite fermions
Phase-resolved far-ultraviolet HST spectroscopy of the peculiar magnetic white dwarf RE J0317-853
We present phase resolved FUV HST FOS spectra of the rapidly rotating, highly
magnetic white dwarf RE J0317-853. Using these data, we construct a new model
for the magnetic field morphology across the stellar surface. From an expansion
into spherical harmonics, we find the range of magnetic field strengths present
is 180-800MG. For the first time we could identify an absorption feature
present at certain phases at 1160A as a ``forbidden'' 1s_0 -> 2s_0 component,
due to the combined presence of an electric and magnetic field.Comment: 15 pages including 4 figures. Accepted for publication in ApJ Letter
Structure of Colloid-Polymer Suspensions
We discuss structural correlations in mixtures of free polymer and colloidal
particles based on a microscopic, 2-component liquid state integral equation
theory. Whereas in the case of polymers much smaller than the spherical
particles the relevant polymer degree of freedom is the center of mass, for
polymers larger than the (nano-) particles conformational rearrangements need
to be considered. They have the important consequence that the polymer
depletion layer exhibits two widely different length scales, one of the order
of the particle radius, the other of the order of the polymer radius or the
polymer density screening length in dilute or semidilute concentrations,
respectively. Their consequences on phase stability and structural correlations
are discussed extensively.Comment: 37 pages, 17 figures; topical feature articl
Assimilation Aborted:Henry Clerk and the Limits of Anglo-Scottish Integration in the Age of Union
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