The Surface Electroclinic Effect near the First Order Smectic-A*--Smectic-C* transition

We analyze the surface electroclinic effect (SECE) in a material that exhibits a first order bulk smectic-$A^*$ (Sm-$A^*$) -- smectic-$C^*$ (Sm-$C^*$) transition. The effect of a continuously varying degree of enantiomeric excess on the SECE is also investigated. We show that due to the first order nature of the bulk Sm-$A^*$ -- Sm-$C^*$ transition, the SECE can be unusually strong and that as enantiomeric excess is varied, a jump in surface induced tilt is expected. A theoretical state map, in enantiomeric excess - temperature space, features a critical point which terminates a line of first order discontinuities in the surface induced tilt. This critical point is analogous to that found for the phase diagram (in electric field - temperature space) for the bulk electroclinic effect. Analysis of the decay of the surface induced tilt, as one moves from surface into bulk shows that for sufficiently high surface tilt the decay will exhibit a well defined spatial kink within which it becomes especially rapid. We also propose that the SECE is additionally enhanced by the de Vries nature (i.e. small layer shrinkage at the bulk Sm-A* -- Sm-C* transition) of the material. As such the SECE provides a new means to characterize the de Vries nature of a material. We discuss the implications for using these materials in device applications and propose ways to investigate the predicted features experimentally

De Vries Behavior in Smectics near a Biaxiality Induced Smectic A - Smectic C Tricritical Point

We show that a generalized Landau theory for the smectic A and C phases exhibits a biaxiality induced AC tricritical point. Proximity to this tricritical point depends on the degree of orientational order in the system; for sufficiently large orientational order the AC transition is 3D XY-like, while for sufficiently small orientational order, it is either tricritical or 1st order. We investigate each of the three types of AC transitions near tricriticality and show that for each type of transition, small orientational order implies de Vries behavior in the layer spacing, an unusually small layer contraction. This result is consistent with, and can be understood in terms of, the "diffuse cone" model of de Vries. Additionally, we show that birefringence grows upon entry to the C phase. For a continuous transition, this growth is more rapid the closer the transition is to tricriticality. Our model also predicts the possibility of a nonmontonic temperature dependence of birefringence

Elasticity, fluctuations and vortex pinning in ferromagnetic superconductors: A "columnar elastic glass"

We study the elasticity, fluctuations and pinning of a putative spontaneous vortex solid in ferromagnetic superconductors. Using a rigorous thermodynamic argument, we show that in the idealized case of vanishing crystalline pinning anisotropy the long-wavelength tilt modulus of such a vortex solid vanishes identically, as guaranteed by the underlying rotational invariance. The vanishing of the tilt modulus means that, to lowest order, the associated tension elasticity is replaced by the softer, curvature elasticity. The effect of this is to make the spontaneous vortex solid qualitatively more susceptible to the disordering effects of thermal fluctuations and random pinning. We study these effects, taking into account the nonlinear elasticity, that, in three dimensions, is important at sufficiently long length scales, and showing that a ``columnar elastic glass'' phase of vortices results. This phase is controlled by a previously unstudied zero-temperature fixed point and it is characterized by elastic moduli that have universal strong wave-vector dependence out to arbitrarily long length scales, leading to non-Hookean elasticity. We argue that, although translationally disordered for weak disorder, the columnar elastic glass is stable against the proliferation of dislocations and is therefore a topologically ordered {\em elastic} glass. As a result, the phenomenology of the spontaneous vortex state of isotropic magnetic superconductors differs qualitatively from a conventional, external-field-induced mixed state. For example, for weak external fields $H$, the magnetic induction scales {\em universally} like $B(H)\sim B(0)+ c H^{\alpha}$, with $\alpha\approx 0.72$.Comment: Minor editorial changes, version to be published in PRB, 39 pages, 7 figure

"Soft" Anharmonic Vortex Glass in Ferromagnetic Superconductors

Ferromagnetic order in superconductors can induce a {\em spontaneous} vortex (SV) state. For external field ${\bf H}=0$, rotational symmetry guarantees a vanishing tilt modulus of the SV solid, leading to drastically different behavior than that of a conventional, external-field-induced vortex solid. We show that quenched disorder and anharmonic effects lead to elastic moduli that are wavevector-dependent out to arbitrarily long length scales, and non-Hookean elasticity. The latter implies that for weak external fields $H$, the magnetic induction scales {\em universally} like $B(H)\sim B(0)+ c H^{\alpha}$, with $\alpha\approx 0.72$. For weak disorder, we predict the SV solid is a topologically ordered vortex glass, in the ``columnar elastic glass'' universality class.Comment: minor corrections; version published in PR

Pattern stabilization through parameter alternation in a nonlinear optical system

We report the first experimental realization of pattern formation in a spatially extended nonlinear system when the system is alternated between two states, neither of which exhibits patterning. Dynamical equations modeling the system are used for both numerical simulations and a weakly nonlinear analysis of the patterned states. The simulations show excellent agreement with the experiment. The nonlinear analysis provides an explanation of the patterning under alternation and accurately predicts both the observed dependence of the patterning on the frequency of alternation, and the measured spatial frequencies of the patterns.Comment: 12 pages, 5 figures. To appear in PR

Hydrodynamics of Polar Liquid Crystals

Starting from a microscopic definition of an alignment vector proportional to the polarization, we discuss the hydrodynamics of polar liquid crystals with local C1v-symmetry. The free energy for polar liquid crystals differs from that of nematic liquid crystals (D1h) in that it contains terms violating the n −n symmetry. First we show that these Z2-odd terms induce a general splay instability of a uniform polarized state in a range of parameters. Next we use the general Poissonbracket formalism to derive the hydrodynamic equations of the system in the polarized state. The structure of the linear hydrodynamic modes confirms the existence of the splay instability

A Discotic Disguised as a Smectic: A Hybrid Columnar Bragg Glass

We show that discotics, lying deep in the columnar phase, can exhibit an x-ray scattering pattern which mimics that of a somewhat unusual smectic liquid crystal. This exotic, new glassy phase of columnar liquid crystals, which we call a ``hybrid columnar Bragg glass'', can be achieved by confining a columnar liquid crystal in an anisotropic random environment of e.g., strained aerogel. Long-ranged orientational order in this phase makes {\em single domain} x-ray scattering possible, from which a wealth of information could be extracted. We give detailed quantitative predictions for the scattering pattern in addition to exponents characterizing anomalous elasticity of the system.Comment: 4 RevTeX pgs, 2 eps figures. To appear in PR

Viscoelasticity from a Microscopic Model of Dislocation Dynamics

It is shown that the dynamics of a two-dimensional crystal with a finite concentration of dislocations, as well as vacancy and interstitial defects, is governed by the hydrodynamic equations of a viscoelastic medium. At the longest length scales the viscoelasticity is described by the simplest Maxwell model, whose shear and compressional relaxation times are obtained in terms of microscopic quantities, including the density of free dislocations. At short length scales, bond orientational order effects become important and lead to wavevector dependent corrections to the relaxation times