55 research outputs found
Ultraviolet and Infrared Spectra of Some p-Nitrobenzyl Phenyl Ethers
The UV-spectra of substituted p-nitrobenzyl phenyl ethers in
ethanol and carbon tetrachloride were recorded. The effect of
substitution on band position and intensity is correlated with the
electronic nature of the group. The IR-spectra are analysed and the
position of certain bands ii;; dis.cussed in terms of molecular structure
Antimicrobial Efficacy and Synergy of Metal Ions against Enterococcus faecium, Klebsiella pneumoniae and Acinetobacter baumannii in Planktonic and Biofilm Phenotypes
The effects of metal ion solutions (silver, copper, platinum, gold and palladium) were determined individually and in combination against Enterococcus faecium, Acinetobacter baumannii and Klebsiella pneumoniae. Platinum, gold and palladium showed the greatest antimicrobial efficacy in zone of inhibition (ZoI) assays. When tested in combinations using ZoI assays, gold/platinum, gold/palladium and platinum/palladium were indicative of synergy. Microbial inhibitory concentration demonstrated platinum and gold against Enterococcus faecium, platinum against Klebsiella pneumoniae and platinum and silver against Acinetobacter baumannii were optimal. Minimal bactericidal concentrations determined the greatest bactericidal activity was again platinum gold and palladium against all three bacteria. Fractional Inhibitory Concentration (FIC) studies demonstrated that the silver/platinum combination against Enterococcus faecium, and silver/copper combination against Acinetobacter baumannii demonstrated antimicrobial synergy. Following crystal violet biofilm assays for single metal ion solutions, antimicrobial efficacies were demonstrated for all the metals against all the bacteria Synergistic assays against biofilms demonstrated gold/palladium, gold/platinumand platinum/palladium resulted in the greatest antimicrobial efficacy. Overall, platinum, palladium and gold metal ion solutions in individual use or combination demonstrated the greatest antimicrobial efficacies against planktonic or biofilm bacteria. This work demonstrates the potential for using a range of metal ions, as biocidal formulations against both planktonic or biofilm bacteria
Studies on Azo Compounds: Part V-Spectrophotometric Studies on Some Quinoline Azo Dyes
19-23<span style="font-size:11.0pt;line-height:115%;
font-family:" calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:="" "times="" new="" roman";mso-fareast-theme-font:minor-fareast;mso-hansi-theme-font:="" minor-latin;mso-bidi-font-family:"times="" roman";mso-ansi-language:en-us;="" mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">The UV and visible spectra
of some azo dyes containing a quinoline nucleus have been studied in different
organic solvents, water and hydrochloric acid. The observed bands are assigned
to different <span style="font-size:11.0pt;line-height:115%;font-family:
" calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:="" "times="" new="" roman";mso-fareast-theme-font:minor-fareast;mso-hansi-theme-font:="" minor-latin;mso-bidi-font-family:mangal;mso-bidi-theme-font:minor-bidi;="" mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">Ï-<span style="font-size:11.0pt;
line-height:115%;font-family:" calibri","sans-serif";mso-ascii-theme-font:minor-latin;="" mso-fareast-font-family:"times="" new="" roman";mso-fareast-theme-font:minor-fareast;="" mso-hansi-theme-font:minor-latin;mso-bidi-font-family:mangal;mso-bidi-theme-font:="" minor-bidi;mso-ansi-language:en-us;mso-fareast-language:en-us;mso-bidi-language:="" ar-sa"="">Ï<span style="font-size:11.0pt;line-height:115%;font-family:
" calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:="" "times="" new="" roman";mso-fareast-theme-font:minor-fareast;mso-hansi-theme-font:="" minor-latin;mso-bidi-font-family:"times="" roman";mso-ansi-language:en-us;="" mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">* transitions and CT.
Spectra-structure correlations are considered. The IR spectra of the compounds
are discussed in relation to their molecular structures.</span
Sensing and photocatalytic properties of nanosized Cu(I)CN organotin supramolecular coordination polymer based on pyrazine
Spectral Behaviour of 2-(Arylsulphinyl)acctophenones & A Study of Their Substituent Effects &. Ionization Constants
480-48
Structure and characterization of organotin bimetallic supramolecular coordination polymers based on copper cyanide building blocks and pyrazine or pyrazineâ2âcarboxylic acid as new promising anticancer agents
Studies on Azo Compounds: Part VII-Protonation Constants and Kinetics of Some Thiazole Azo and Azomethine Dyes
143-147<span style="font-size:11.0pt;line-height:115%;
font-family:" calibri","sans-serif";mso-ascii-theme-font:minor-latin;mso-fareast-font-family:="" "times="" new="" roman";mso-fareast-theme-font:minor-fareast;mso-hansi-theme-font:="" minor-latin;mso-bidi-font-family:"times="" roman";mso-ansi-language:en-us;="" mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">The protonation (pkp)
and ionization (pka) constants of some thiazole
azo and azomethine dyes were determined in aqueous universal buffer solutions
of varying pH values at 25<span style="font-size:11.0pt;
line-height:115%;font-family:" calibri","sans-serif";mso-ascii-theme-font:minor-latin;="" mso-fareast-font-family:"times="" new="" roman";mso-fareast-theme-font:minor-fareast;="" mso-hansi-theme-font:minor-latin;mso-bidi-font-family:arial;mso-ansi-language:="" en-us;mso-fareast-language:en-us;mso-bidi-language:ar-sa"="">±0.1oC and at ion strength of 0.1
using the spectrophotometric method. Protonation occurs on the imino nitrogen
atom of the thiazole nucleus and it is affected by the nature of the substituents.
The rate of protonation of azomethine dyes is slower than that of thiazole azo
dyes; therefore, the rate constants of azomethine dyes were evaluated. The
order of protonation is 1.5.</span
Spectral Characteristics and Applications of MetalâOrganic Frameworks Based on Copper Cyanide and Quinoline Bases
Structure and Spectral Properties of Pyrazine Ligand Assisted Self-Assembly of a Coordination Polymer Containing Copper-Cyanide Building Blocks
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