Structure of cadmium sulfide nanoparticle micelle in aqueous solutions

The structure of cadmium sulfide (CdS) micelle in stable aqueous solution of ethylenediaminetetraacetic acid was determined by dynamic light scattering, small-angle X-ray scattering and neutron scattering. The micelle aggregate is a single CdS nanoparticle with an average size of about 3 nm, the nanoparticle organic shell and the solvation shell are about 1 nm and 5 nm thick, respectively. These parameters were confirmed by the scanning semi-contact atomic force microscopy and powder X-ray diffraction studies of dry micelle cores isolated by high-speed centrifugation. The CdS micelle was correctly described by a simple double-shell model and was found to possess the structure corresponding to CdS quantum dots. © 2013 Springer Science+Business Media New York

Sizes and fluorescence of cadmium sulfide quantum dots

Cadmium sulfide quantum dots have been synthesized by wet chemical deposition from an aqueous solution. The sizes of the quantum dots determined by dynamic light scattering directly in the colloidal solution and by intermittent-contact atomic force microscopy in the dry sediment agree with each other. It has been found that splitting of the fluorescence peaks of the quantum dots can be affected by the disorder of the atomic structure of cadmium sulfide quantum dots. © 2013 Pleiades Publishing, Ltd

Self-assembly of Ag2S colloidal nanoparticles stabilized by MPS in water solution

Self-assembly of colloidal Ag2S nanoparticles (NPs) was studied in the presence of (3-mercaptopropyl)trimethoxysilane (MPS). Solutions with different molar ratios of Ag2S/MPS were prepared. The appearance of nanoand microtubes was detected. Self-organized NPs were studied with optical microscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and high-resolution transmission electron microscopy (HRTEM). Silicon nuclear magnetic resonance spectroscopy (29Si NMR) was used to study polycondensation of MPS molecules. Geometrical parameters of the nano- and microtubes depended on the molar ratio of Ag2S/MPS. The scheme and mechanism of self-assembly of Ag2S NPs in nanotubes in the presence of MPS were proposed. The effect of MPS on the preservation of the initial stoichiometry of Ag2S NPs was discussed. © 2020 American Chemical Society.The authors are grateful to E. Y. Gerasimov, O. S. Eltsov, and I. D. Popov for their assistance. This work was supported by the RSF [project no. 19-73-20012]

In situ study of the temperature stability of TiO1.05 titanium monooxide using synchrotron radiation

The temperature stability of cubic TiO1.05 titanium monooxide is investigated. An in situ X-ray structural analysis is performed using synchrotron radiation in a high temperature vacuum chamber. It is found that under poor vacuum and at high heating rates of up to 1250 C, the structural transformations in TiO1.05 occur at 630 C. In particular, there is a phase transition from TiO1.05 (space group Fm-3m) to rhombohedraic Ti2O3 (space group R-3c) via Ti2.5O3 (space group Immm). © 2013 Allerton Press, Inc

Simulation of the short-range order in disordered cubic titanium monoxide TiO1.0

A model of the atomic structure with the short-range order in the vacancy distribution for the disordered cubic phase of titanium monoxide TiO1.0 has been proposed. The effect of the short-range order on the electronic structure and the stability of the compound has been studied by the supercell method within the DFT-GGA approximation with the use of pseudopotentials. It has been established that the appearance of the short-range order considerably decreases the total energy. The decrease in the energy is comparable with the energy gain during the ordering of the vacancies according to the type of monoclinic superstructure Ti5O5 to the long-range order parameter η = 0.7. It has been shown that the discrepancies between the theoretical and experimental electronic spectra of titanium monoxide can be explained by allowance for the short range order. © 2013 Pleiades Publishing, Ltd

Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy

The structure of titanium monoxide TiOy with different stoichiometries and long-range order degrees was studied by using X-ray diffraction, electron backscatter diffraction, Raman spectroscopy, and electron microscopy methods. It was established that the composition of the phases formed in annealed TiOy depends on the titanium monoxide stoichiometry. A new phase precipitation mechanism is proposed. The migration of vacancies in dislocations and their accumulation on grain boundaries play an important role in the formation of new phases. The stoichiometry of quenched titanium monoxide (TiOy) was found to affect the intensity of the peak associated with the vibrational mode of the Ti-O bond in Raman spectra. Copyright © 2020 American Chemical Society.The authors are grateful to M. V. Lukashova (Demonstration laboratory TESCAN, St. Petersburg) for her assistance in carrying out the research. The reported study was funded by RFBR according to the research project no. 19-03-00051a

Disintegration of microcrystalline Zn2SiO4:Mn phosphor powder

Zn2SiO4:Mn (willemite) nanoparticles ∼30 nm in size have been prepared by disintegrating microcrystalline willemite powder in a planetary ball mill. X-ray diffraction and scanning electron micros-copy characterization showed that ball milling of the Zn2SiO 4:Mn powder for 60 min or a longer time ensured complete disintegration of the microcrystalline material and that the crystal structure of the resultant nanoparticles was identical to that of the parent powder. © 2013 Pleiades Publishing, Ltd

Solar vortex tubes : vortex dynamics in the solar atmosphere

In this work, a state-of-the-art vortex detection method, Instantaneous Vorticity Deviation, is applied to locate three-dimensional vortex tube boundaries in numerical simulations of solar photospheric magnetoconvection performed by the MURaM code. We detected three-dimensional vortices distributed along intergranular regions and displaying coned shapes that extend from the photosphere to the low chromosphere. Based on a well-defined vortex center and boundary, we were able to determine averaged radial profiles and thereby investigate the dynamics across the vortical flows at different height levels. The solar vortex tubes present nonuniform angular rotational velocity, and, at all height levels, there are eddy viscosity effects within the vortices, which slow down the plasma as it moves toward the center. The vortices impact the magnetic field as they help to intensify the magnetic field at the sinking points, and in turn, the magnetic field ends up playing an essential role in the vortex dynamics. The magnetic field was found to be especially important to the vorticity evolution. On the other hand, it is shown that, in general, kinematic vortices do not give rise to magnetic vortices unless their tangential velocities at different height levels are high enough to overcome the magnetic tension

Hybrid nanoparticles based on sulfides, oxides, and carbides

The methods for synthesis of hybrid nanoparticles based on sulfides, oxides, and carbides of heavy and transition metals were considered. The problem of the influence of the method of synthesis of the hybrid nanoparticles on their atomic structure, morphology of the nanomaterials, and functional properties was analyzed. The areas of practical use of the hybrid nanoparticles were proposed. © 2013 Springer Science+Business Media New York

Transition to chaos in a reduced-order model of a shear layer

The present work studies the non-linear dynamics of a shear layer, driven by a body force and confined between parallel walls, a simplified setting to study transitional and turbulent shear layers. It was introduced by Nogueira \& Cavalieri (J. Fluid Mech. 907, A32, 2021), and is here studied using a reduced-order model based on a Galerkin projection of the Navier-Stokes system. By considering a confined shear layer with free-slip boundary conditions on the walls, periodic boundary conditions in streamwise and spanwise directions may be used, simplifying the system and enabling the use of methods of dynamical systems theory. A basis of eight modes is used in the Galerkin projection, representing the mean flow, Kelvin-Helmholtz vortices, rolls, streaks and oblique waves, structures observed in the cited work, and also present in shear layers and jets. A dynamical system is obtained, and its transition to chaos is studied. Increasing Reynolds number $Re$ leads to pitchfork and Hopf bifurcations, and the latter leads to a limit cycle with amplitude modulation of vortices, as in the DNS by Nogueira \& Cavalieri. Further increase of $Re$ leads to the appearance of a chaotic saddle, followed by the emergence of quasi-periodic and chaotic attractors. The chaotic attractors suffer a merging crisis for higher $Re$, leading to chaotic dynamics with amplitude modulation and phase jumps of vortices. This is reminiscent of observations of coherent structures in turbulent jets, suggesting that the model represents dynamics consistent with features of shear layers and jets.Comment: 28 pages, 18 figure