Topography evolution of germanium thin films synthesized by pulsed laser deposition

Germanium thin films were deposited by Pulsed Laser Deposition (PLD) onto single crystal Ge (100) and Si (100) substrates with a native oxide film on the surface. The topography of the surface was investigated by Atomic Force Microscopy (AFM) to evaluate the scaling behavior of the surface roughness of amorphous and polycrystalline Ge films grown on substrates with different roughnesses. Roughness evolution was interpreted within the framework of stochastic rate equations for thin film growth. Here the Kardar-Parisi-Zhang equation was used to describe the smoothening process. Additionally, a roughening regime was observed in which 3-dimensional growth occurred. Diffusion of the deposited Ge adatoms controlled the growth of the amorphous Ge thin films. The growth of polycrystalline thin Ge films was dominated by diffusion processes only in the initial stage of the growth

Nutritional Consequences of Food Insecurity in a Rural New York State County

This study of women with children in a rural county of upstate New York examined the relationships of food insecurity and income with two nutritional consequences (adiposity and fruit and vegetables consumption), and assessed whether disordered eating patterns is a mediator for the effects of food insecurity and income on these nutritional consequences. Each of 193 respondents was interviewed twice in her home. Data were collected on household food stores, socioeconomic and demographic characteristics, methods of obtaining food, food program participation, household expenditures, food intake, the Radimer/Cornell hunger and food insecurity items, height, weight, frequency of fruit and vegetable consumption, and disordered eating patterns. Regression analysis was used to analyze the relationships of body mass index and an obesity classification with height, income, education, single parenthood, employment, food insecurity, disordered eating, and frequency of fruit and vegetable consumption. Regression analysis was also used to examine the relationships of disordered eating and frequency of fruit and vegetable consumption with the other variables. Lower income and unemployment were related to higher adiposity. The effects of income on adiposity were not mediated through disordered eating patterns or through fruit and vegetable consumption. Food insecurity was related to adiposity, and part of this effect of food insecurity was mediated through disordered eating. This mediating effect of disordered eating partially explained why those experiencing the least severe food insecurity were more likely to be overweight than those who were food secure, but those experiencing the most severe food insecurity were less likely to be overweight than those who were food secure. Food insecurity was related to lower fruit and vegetable consumption, but this did not translate into effects on adiposity.

Glancing angle deposition of sculptured thin metal films at room temperature

Metallic thin films consisting of separated nanostructures are fabricated by evaporative glancing angle deposition at room temperature. The columnar microstructure of the Ti and Cr columns is investigated by high resolution transmission electron microscopy and selective area electron diffraction. The morphology of the sculptured metallic films is studied by scanning electron microscopy. It is found that tilted Ti and Cr columns grow with a single crystalline morphology, while upright Cr columns are polycrystalline. Further, the influence of continuous substrate rotation on the shaping of Al, Ti, Cr and Mo nanostructures is studied with view to surface diffusion and the shadowing effect. It is observed that sculptured metallic thin films deposited without substrate rotation grow faster compared to those grown with continuous substrate rotation. A theoretical model is provided to describe this effect

Estimating the prevalence of hunger and food insecurity: The validity of questionnaire-based measures for the identification of households

This study had three objectives: (1) to assess the validity of questionnaire-based measures in identifying households experiencing hunger and food insecurity, (2) to examine the interrelationships of different questionnaire-based measures, and (3) to examine the construction of a continuous food insecurity scale intended to differentiate three levels of food insecurity within households. A 1993 survey of 193 randomly sampled rural households with women and children living at home provided data on demographics, risk factors for food insecurity, Radimer/Cornell, CCHIP, and NHANES III hunger and food insecurity items, coping strategies, fruit and vegetable consumption, disordered eating behaviors, height, weight, dietary recall, and household food-stores inventory. This information was used to develop a definitive criterion measure for hunger and food insecurity, against which the Radimer/Cornell and CCHIP questionnaire-based measures, the NHANES III item, and the continuous food insecurity scale were tested for their specificity and sensitivity in measuring levels of food insecurity.

Ripple coarsening on ion beam-eroded surfaces

Abstract: The temporal evolution of ripple pattern on Ge, Si, Al2O3, and SiO2 by low-energy ion beam erosion with Xe + ions is studied. The experiments focus on the ripple dynamics in a fluence range from 1.1 × 1017 cm-2 to 1.3 × 1019 cm-2 at ion incidence angles of 65° and 75° and ion energies of 600 and 1,200 eV. At low fluences a short-wavelength ripple structure emerges on the surface that is superimposed and later on dominated by long wavelength structures for increasing fluences. The coarsening of short wavelength ripples depends on the material system and angle of incidence. These observations are associated with the influence of reflected primary ions and gradient-dependent sputtering. The investigations reveal that coarsening of the pattern is a universal behavior for all investigated materials, just at the earliest accessible stage of surface evolution

Pattern formation on Ge by low energy ion beam erosion

Modification of nanoscale surface topography is inherent to low-energy ion beam erosion processes and is one of the most important fields of nanotechnology. In this report a comprehensive study of surface smoothing and self-organized pattern formation on Ge(100) by using different noble gases ion beam erosion is presented. The investigations focus on low ion energies ( 2000 eV) and include the entire range of ion incidence angles. It is found that for ions (Ne, Ar) with masses lower than the mass of the Ge target atoms, no pattern formation occurs and surface smoothing is observed for all angles of ion incidence. In contrast, for erosion with higher mass ions (Kr, Xe), ripple formation starts at incidence angles of about 65° depending on ion energy. At smaller incident angles surface smoothing occurs again. Investigations of the surface dynamics for specific ion incidence angles by changing the ion fluence over two orders of magnitude gives a clear evidence for coarsening and faceting of the surface pattern. Both observations indicate that gradient-dependent sputtering and reflection of primary ions play crucial role in the pattern evolution, just at the lowest accessible fluences. The results are discussed in relation to recently proposed redistributive or stress-induced models for pattern formation. In addition, it is argued that a large angular variation of the sputter yield and reflected primary ions can significantly contribute to pattern formation and evolution as nonlinear and non-local processes as supported by simulation of sputtering and ion reflection

Elucidating the effect of mass transport resistances on hydrogen crossover and cell performance in PEM water electrolyzers by varying the cathode ionomer content

An important challenge for polymer electrolyte membrane (PEM) water electrolysis is to reduce the permeation of the produced gases. This crossover affects the cell efficiency and causes safety issues. The crossover increases with current density, most probably due to mass transfer resistances. This work aims to investigate the influence of the cathode ionomer content on hydrogen crossover. Therefore, the ionomer content was varied between 10 and 40 wt% to clearly influence the mass transfer resistances. The best performance and lowest crossover was obtained for 10 wt% ionomer. However, within the observed ionomer range the mass transfer resistances increase with ionomer content that cause increases in hydrogen crossover and cell voltage. Both can be entirely explained by the same quantity of supersaturated dissolved hydrogen concentrations. These supersaturated concentrations cause higher cathode half-cell potentials, which explain the cell voltage increase and lead to higher concentration gradients across the membrane, which enhance the crossover. These findings highlight the importance of mass transfer resistances within catalyst layers in terms of crossover and performance. They constitute an important step in the clarification of the complex interplay between mass transport and voltage losses, enabling the development of novel electrode architectures for PEM water electrolyzers. © The Author(s) 2019

Understanding electrical under- and overshoots in proton exchange membrane water electrolysis cells

Ability of dynamic operation seems to be an important feature of proton exchange membrane water electrolyzers (PEMWE) to become a relevant part of the future energy system. However, only few fundamental analyzes of the dynamic behavior on short time scales are available in the literature. Therefore, this contribution aims to give insights into the most fundamental transient behavior of a PEMWE cell by an experimental analysis on the laboratory scale and a model based description of the ongoing phenomena. Experimental voltage and current controlled load step are carried out and analyzed by methods adapted from fuel cell characterization. The experimental analysis revealed that load steps are a combination of an instantaneous characteristic followed by dynamics of higher order dependent on activation, mass transfer and temperature effects. Potentiostatic downward steps to very low cell voltages can lead to current density reversal phenomena with highly negative peak current densities. By means of a simple prototype model analysis, these reversal processes are analyzed and the consequences of the phenomena are estimated. The simulation results indicate that a reversal of the cell current density can be attributed to a change of capacitive rather than faradaic currents, meaning that internal electrolysis processes are not involved. © The Author(s) 2019. Published by ECS

SERS analysis of Ag nanostructures produced by ion-beam deposition

This study deals with the development of a novel technique for formation of advanced Ag nanostructures (NSs) to be applied to high-resolution analyses based on surface enhanced Raman scattering (SERS). It has direct bearing on human health and food quality, e.g., monitoring small amount or traces of pollutants or undesirable additives. Three types of nanostructured Ag samples were produced using ion-beam deposition at glancing angle (GLAD) on quartz. All fabricated structures were covered with BI-58 pesticide (dimethoate) or Rhodamine 6G (R6G) for testing their potential for use as substrates for (SERS)