Dyes removal from water using low cost absorbents

In this study, the removal capacity of low cost adsorbents during the adsorption of Methylene Blue (MB) and Congo Red (CR) at different concentrations (50 and 100mg•L-1) was evaluated. These adsorbents were produced from wood wastes (cedar and teak) by chemical activation (ZnCl2). Both studied materials, Activated Cedar (AC) and activated teak (AT) showed a good fit of their experimental data to the pseudo second order kinetic model and Langmuir isotherms. The maximum adsorption capacities for AC were 2000.0 and 444.4mg•g-1 for MB and CR, respectively, while for AT, maximum adsorption capacities of 1052.6 and 86.4mg•g-1 were found for MB and CR, respectively. © Published under licence by IOP Publishing Ltd

A possible signature of terrestrial planet formation in the chemical composition of solar analogs

Recent studies have shown that the elemental abundances in the Sun are anomalous when compared to most (about 85%) nearby solar twin stars. Compared to its twins, the Sun exhibits a deficiency of refractory elements (those with condensation temperatures Tc>900K) relative to volatiles (Tc<900K). This finding is speculated to be a signature of the planet formation that occurred more efficiently around the Sun compared with the majority of solar twins. Furthermore, within this scenario, it seems more likely that the abundance patterns found are specifically related to the formation of terrestrial planets. In this work we analyze abundance results from six large independent stellar abundance surveys to determine whether they confirm or reject this observational finding. We show that the elemental abundances derived for solar analogs in these six studies are consistent with the Tc trend suggested as a planet formation signature. The same conclusion is reached when those results are averaged heterogeneously. We also investigate the dependency of the abundances with first ionization potential (FIP), which correlates well with Tc. A trend with FIP would suggest a different origin for the abundance patterns found, but we show that the correlation with Tc is statistically more significant. We encourage similar investigations of metal-rich solar analogs and late F-type dwarf stars, for which the hypothesis of a planet formation signature in the elemental abundances makes very specific predictions. Finally, we examine a recent paper that claims that the abundance patterns of two stars hosting super-Earth like planets contradict the planet formation signature hypothesis. Instead, we find that the chemical compositions of these two stars are fully compatible with our hypothesis.Comment: To appear in Astronomy and Astrophysic

Stellar Chemical Abundances: In Pursuit of the Highest Achievable Precision

The achievable level of precision on photospheric abundances of stars is a major limiting factor on investigations of exoplanet host star characteristics, the chemical histories of star clusters, and the evolution of the Milky Way and other galaxies. While model-induced errors can be minimized through the differential analysis of spectrally similar stars, the maximum achievable precision of this technique has been debated. As a test, we derive differential abundances of 19 elements from high-quality asteroid-reflected solar spectra taken using a variety of instruments and conditions. We treat the solar spectra as being from unknown stars and use the resulting differential abundances, which are expected to be zero, as a diagnostic of the error in our measurements. Our results indicate that the relative resolution of the target and reference spectra is a major consideration, with use of different instruments to obtain the two spectra leading to errors up to 0.04 dex. Use of the same instrument at different epochs for the two spectra has a much smaller effect (~0.007 dex). The asteroid used to obtain the solar standard also has a negligible effect (~0.006 dex). Assuming that systematic errors from the stellar model atmospheres have been minimized, as in the case of solar twins, we confirm that differential chemical abundances can be obtained at sub-0.01 dex precision with due care in the observations, data reduction and abundance analysis.Comment: Accepted for publication in ApJ; 13 pages, 6 figures, 7 table

Prostaglandin E2 promotes features of replicative senescence in chronically activated human CD8+ T cells.

Prostaglandin E2 (PGE2), a pleiotropic immunomodulatory molecule, and its free radical catalyzed isoform, iso-PGE2, are frequently elevated in the context of cancer and chronic infection. Previous studies have documented the effects of PGE2 on the various CD4+ T cell functions, but little is known about its impact on cytotoxic CD8+ T lymphocytes, the immune cells responsible for eliminating virally infected and tumor cells. Here we provide the first demonstration of the dramatic effects of PGE2 on the progression of human CD8+ T cells toward replicative senescence, a terminal dysfunctional state associated multiple pathologies during aging and chronic HIV-1 infection. Our data show that exposure of chronically activated CD8+ T cells to physiological levels of PGE2 and iso-PGE2 promotes accelerated acquisition of markers of senescence, including loss of CD28 expression, increased expression of p16 cell cycle inhibitor, reduced telomerase activity, telomere shortening and diminished production of key cytotoxic and survival cytokines. Moreover, the CD8+ T cells also produced higher levels of reactive oxygen species, suggesting that the resultant oxidative stress may have further enhanced telomere loss. Interestingly, we observed that even chronic activation per se resulted in increased CD8+ T cell production of PGE2, mediated by higher COX-2 activity, thus inducing a negative feedback loop that further inhibits effector function. Collectively, our data suggest that the elevated levels of PGE2 and iso-PGE2, seen in various cancers and HIV-1 infection, may accelerate progression of CD8+ T cells towards replicative senescence in vivo. Inhibition of COX-2 activity may, therefore, provide a strategy to counteract this effect

Epitaxial Thin Films of the Giant-Dielectric-Constant Material CaCu_3Ti_4O_{12} Grown by Pulsed-laser Deposition

Pulsed-laser deposition has been used to grow epitaxial thin films of the giant-dielectric-constant material CaCu_3Ti_4O_{12} on LaAlO_3 and SrTiO_3 substrates with or without various conducting buffer layers. The latter include YBa_2Cu_3O_7, La_{1.85}Sr_{0.15}CuO_{4+\delta} and LaNiO_3. Above 100K - 150K the thin films have a temperature independent dielectric constant as do single crystals. The value of the dielectric constant is of the order of 1500 over a wide temperature region, potentially making it a good candidate for many applications. The frequency dependence of its dielectric properties below 100K - 150K indicates an activated relaxation process.Comment: 11 pages, 4 figure