Elektrisch aktive Sonden für die Anzeige von molekularen Transportvorgängen in porösen Festkörpern

Microcrystalline samples of SiO$_{2}$, Al$_{2}$O$_{3}$, MgO, NaCl, clay minerals and zeolites have been compacted between conducting electrodes. The porous solids under mechanical stress create an electrical power (EMF) of the order of magnitude $\mu$W/cm$^{3}$ if polar, dissociating molecules as e.g. H$_{2}$O, CH$_{3}$ OH, C$_{2}$H$_{5}$OH are adsorbed. The EMF of electrochemically symmetric solid cells with a large internal surface under stresswas measured as a function of time after changes of the partial pressure of water in the surroundings and after variation of the temperature. The oscillating reaction of the EMF indicates a nonlinear, coupled system of heat-, mass- and eletrical charge transport processes. The time averaged EMF in the stationary state is proposed to be used for the indication of the internal surface coverage with polar, dissociated molecules

A characterization of the power of vector machines

A new formal model of register machines is described. Registers contain bit vectorswhich are manipulated using bitwise Boolean operations and shifts. Our main results relate the language recognition power of such vector machines to that of Turing machines. A class of vector machines is exhibited for which time on a vector machine supplies, to within a polynomial, just as much power as space on a Turing machine. Moreover, this is true regardless of whether the machines are deterministic or non-deterministic

Descriptive Complexity of Deterministic Polylogarithmic Time and Space

We propose logical characterizations of problems solvable in deterministic polylogarithmic time (PolylogTime) and polylogarithmic space (PolylogSpace). We introduce a novel two-sorted logic that separates the elements of the input domain from the bit positions needed to address these elements. We prove that the inflationary and partial fixed point vartiants of this logic capture PolylogTime and PolylogSpace, respectively. In the course of proving that our logic indeed captures PolylogTime on finite ordered structures, we introduce a variant of random-access Turing machines that can access the relations and functions of a structure directly. We investigate whether an explicit predicate for the ordering of the domain is needed in our PolylogTime logic. Finally, we present the open problem of finding an exact characterization of order-invariant queries in PolylogTime.Comment: Submitted to the Journal of Computer and System Science

Composition with Target Constraints

It is known that the composition of schema mappings, each specified by source-to-target tgds (st-tgds), can be specified by a second-order tgd (SO tgd). We consider the question of what happens when target constraints are allowed. Specifically, we consider the question of specifying the composition of standard schema mappings (those specified by st-tgds, target egds, and a weakly acyclic set of target tgds). We show that SO tgds, even with the assistance of arbitrary source constraints and target constraints, cannot specify in general the composition of two standard schema mappings. Therefore, we introduce source-to-target second-order dependencies (st-SO dependencies), which are similar to SO tgds, but allow equations in the conclusion. We show that st-SO dependencies (along with target egds and target tgds) are sufficient to express the composition of every finite sequence of standard schema mappings, and further, every st-SO dependency specifies such a composition. In addition to this expressive power, we show that st-SO dependencies enjoy other desirable properties. In particular, they have a polynomial-time chase that generates a universal solution. This universal solution can be used to find the certain answers to unions of conjunctive queries in polynomial time. It is easy to show that the composition of an arbitrary number of standard schema mappings is equivalent to the composition of only two standard schema mappings. We show that surprisingly, the analogous result holds also for schema mappings specified by just st-tgds (no target constraints). This is proven by showing that every SO tgd is equivalent to an unnested SO tgd (one where there is no nesting of function symbols). Similarly, we prove unnesting results for st-SO dependencies, with the same types of consequences.Comment: This paper is an extended version of: M. Arenas, R. Fagin, and A. Nash. Composition with Target Constraints. In 13th International Conference on Database Theory (ICDT), pages 129-142, 201

Randomisation and Derandomisation in Descriptive Complexity Theory

We study probabilistic complexity classes and questions of derandomisation from a logical point of view. For each logic L we introduce a new logic BPL, bounded error probabilistic L, which is defined from L in a similar way as the complexity class BPP, bounded error probabilistic polynomial time, is defined from PTIME. Our main focus lies on questions of derandomisation, and we prove that there is a query which is definable in BPFO, the probabilistic version of first-order logic, but not in Cinf, finite variable infinitary logic with counting. This implies that many of the standard logics of finite model theory, like transitive closure logic and fixed-point logic, both with and without counting, cannot be derandomised. Similarly, we present a query on ordered structures which is definable in BPFO but not in monadic second-order logic, and a query on additive structures which is definable in BPFO but not in FO. The latter of these queries shows that certain uniform variants of AC0 (bounded-depth polynomial sized circuits) cannot be derandomised. These results are in contrast to the general belief that most standard complexity classes can be derandomised. Finally, we note that BPIFP+C, the probabilistic version of fixed-point logic with counting, captures the complexity class BPP, even on unordered structures

An operator representation for Matsubara sums

In the context of the imaginary-time formalism for a scalar thermal field theory, it is shown that the result of performing the sums over Matsubara frequencies associated with loop Feynman diagrams can be written, for some classes of diagrams, in terms of the action of a simple linear operator on the corresponding energy integrals of the Euclidean theory at T=0. In its simplest form the referred operator depends only on the number of internal propagators of the graph. More precisely, it is shown explicitly that this \emph{thermal operator representation} holds for two generic classes of diagrams, namely, the two-vertex diagram with an arbitrary number of internal propagators, and the one-loop diagram with an arbitrary number of vertices. The validity of the thermal operator representation for diagrams of more complicated topologies remains an open problem. Its correctness is shown to be equivalent to the correctness of some diagrammatic rules proposed a few years ago.Comment: 4 figures; references added, minor changes in notation, final version accepted for publicatio

Evaluating QBF Solvers: Quantifier Alternations Matter

We present an experimental study of the effects of quantifier alternations on the evaluation of quantified Boolean formula (QBF) solvers. The number of quantifier alternations in a QBF in prenex conjunctive normal form (PCNF) is directly related to the theoretical hardness of the respective QBF satisfiability problem in the polynomial hierarchy. We show empirically that the performance of solvers based on different solving paradigms substantially varies depending on the numbers of alternations in PCNFs. In related theoretical work, quantifier alternations have become the focus of understanding the strengths and weaknesses of various QBF proof systems implemented in solvers. Our results motivate the development of methods to evaluate orthogonal solving paradigms by taking quantifier alternations into account. This is necessary to showcase the broad range of existing QBF solving paradigms for practical QBF applications. Moreover, we highlight the potential of combining different approaches and QBF proof systems in solvers.Comment: preprint of a paper to be published at CP 2018, LNCS, Springer, including appendi

Improving Strategies via SMT Solving

We consider the problem of computing numerical invariants of programs by abstract interpretation. Our method eschews two traditional sources of imprecision: (i) the use of widening operators for enforcing convergence within a finite number of iterations (ii) the use of merge operations (often, convex hulls) at the merge points of the control flow graph. It instead computes the least inductive invariant expressible in the domain at a restricted set of program points, and analyzes the rest of the code en bloc. We emphasize that we compute this inductive invariant precisely. For that we extend the strategy improvement algorithm of [Gawlitza and Seidl, 2007]. If we applied their method directly, we would have to solve an exponentially sized system of abstract semantic equations, resulting in memory exhaustion. Instead, we keep the system implicit and discover strategy improvements using SAT modulo real linear arithmetic (SMT). For evaluating strategies we use linear programming. Our algorithm has low polynomial space complexity and performs for contrived examples in the worst case exponentially many strategy improvement steps; this is unsurprising, since we show that the associated abstract reachability problem is Pi-p-2-complete