Synthesis of aromatic secondary diamines

A series of N-methyl substituted aromatic polyamides derived from the secondary aromatic diamines, 4,4'-bis(methylamino)diphenylmethane, 3,3'-bis(methylamino) diphenylmethane, 4,4'-bis(methylamino)benzophenone or 3,3'-bis(methylamino)benzophenone and isophthaloyl dichloride, terphthaloyl dichloride or 3,3'diphenylmethane dicarboxylic acid dichloride was prepared by high temperature solution polymerization in s-tetrachloroethane. Compared to analogous unsubstituted and partially N-methylated aromatic polyamides, the full N-methylated polyamides exhibited significantly lower glass transition temperatures, reduced crystallinity, improved thermal stability and good solubility in chlorinated solvents

The Evolution of Luminous Compact Blue Galaxies: Disks or Spheroids?

Luminous compact blue galaxies (LCBGs) are a diverse class of galaxies characterized by high luminosities, blue colors, and high surface brightnesses. Residing at the high luminosity, high mass end of the blue sequence, LCBGs sit at the critical juncture of galaxies that are evolving from the blue to the red sequence. Yet we do not understand what drives the evolution of LCBGs, nor how they will evolve. Based on single-dish HI observations, we know that they have a diverse range of properties. LCBGs are HI-rich with M(HI)=10^{9-10.5} M(sun), have moderate M(dyn)=10^{10-12} M(sun), and 80% have gas depletion timescales less than 3 Gyr. These properties are consistent with LCBGs evolving into low-mass spirals or high mass dwarf ellipticals or dwarf irregulars. However, LCBGs do not follow the Tully-Fisher relation, nor can most evolve onto it, implying that many LCBGs are not smoothly rotating, virialized systems. GMRT and VLA HI maps confirm this conclusion revealing signatures of recent interactions and dynamically hot components in some local LCBGs, consistent with the formation of a thick disk or spheroid. Such signatures and the high incidence of close companions around LCBGs suggest that star formation in local LCBGs is likely triggered by interactions. The dynamical masses and apparent spheroid formation in LCBGs combined with previous results from optical spectroscopy are consistent with virial heating being the primary mechanism for quenching star formation in these galaxies.Comment: 4 pages, 1 figure, to appear in "Hunting for the Dark: The Hidden Side of Galaxy Formation", Malta, 19-23 Oct. 2009, eds. V.P. Debattista & C.C. Popescu, AIP Conf. Se

City main street networks show a drastic shift away from historic patterns of human-scale design

Have you ever wondered why some places seem built for automobiles as opposed to humans? In a recent study, J. Alexander Maxwell and fellow researchers from the University of Strathclyde’s Urban Design Studies Unit find evidence that before the rise of the automobile, cities developed on a walkable “human” scale, with main streets that rarely exceeded 400 meters (a little more than 437 yards). Along with Charles R. Wolfe, they argue that this uniformity reveals an underlying pattern to pedestrian city settings, which should be considered in contemporary urban design and policies

Methodology development for evaluation of selective-fidelity rotorcraft simulation

This paper addressed the initial step toward the goal of establishing performance and handling qualities acceptance criteria for realtime rotorcraft simulators through a planned research effort to quantify the system capabilities of 'selective fidelity' simulators. Within this framework the simulator is then classified based on the required task. The simulator is evaluated by separating the various subsystems (visual, motion, etc.) and applying corresponding fidelity constants based on the specific task. This methodology not only provides an assessment technique, but also provides a technique to determine the required levels of subsystem fidelity for a specific task

Preliminary catalog of pictures taken on the lunar surface during the Apollo 15 mission

Catalog of all pictures taken from lunar module or lunar surface during Apollo 15 missio