106 research outputs found
Managing Climatic Risks to Combat Land Degradation and Enhance Food security: Key Information Needs
This paper discusses the key information needs to reduce the negative impacts of weather variability and climate change on land degradation and food security, and identifies the opportunities and barriers between the information and services needed. It suggests that vulnerability assessments based on a livelihood concept that includes climate information and key socio-economic variables can overcome the narrow focus of common one-dimensional vulnerability studies. Both current and future climatic risks can be managed better if there is appropriate policy and institutional support together with technological interventions to address the complexities of multiple risks that agriculture has to face. This would require effective partnerships among agencies dealing with meteorological and hydrological services, agricultural research, land degradation and food security issues. In addition a state-of-the-art infrastructure to measure, record, store and disseminate data on weather variables, and access to weather and seasonal climate forecasts at desired spatial and temporal scales would be needed
Stochastic models of dense or hollow nanoparticles and their scattering properties
peer reviewedA family of stochastic models of disordered particles is proposed, obtained by clipping a Gaussian random field with a function that is space dependent. Depending on the shape of the clipping function, dense or hollow particles can be modelled. General expressions are derived for the form factor of the particles, for their average volume and surface area, and for their density and surface-area distributions against the distance to the particle centre. A general approximation for the form factor is also introduced, based on the density and surface-area distributions, which coincides with the Guinier and Porod expressions in the limits of low and high scattering vector magnitude q. The models are illustrated with the fitting of small-angle X-ray scattering (SAXS) data measured on Pt/Ni hollow nanoparticles. The SAXS analysis and modelling notably capture the collapse of the particles' porosity after being used as oxygen-reduction catalysts
Density of States for a Specified Correlation Function and the Energy Landscape
The degeneracy of two-phase disordered microstructures consistent with a
specified correlation function is analyzed by mapping it to a ground-state
degeneracy. We determine for the first time the associated density of states
via a Monte Carlo algorithm. Our results are described in terms of the
roughness of the energy landscape, defined on a hypercubic configuration space.
The use of a Hamming distance in this space enables us to define a roughness
metric, which is calculated from the correlation function alone and related
quantitatively to the structural degeneracy. This relation is validated for a
wide variety of disordered systems.Comment: Accepted for publication in Physical Review Letter
State legitimacy and famines in Sub-Saharan Africa
Political Economy of famines mainly focuses on political regimes to understand the role of institutions. In this paper, we investigate a broader concept, state legitimacy, and its role on one specific development outcome, famine management. State legitimacy refers to the political history of a country, meaning the embedding of state and society. Using a database of Sub-Saharan countries observed from 1980 to 2005, we use three empirical strategies: logit on famine occurrence, negative binomial regression and Arellano-Bond dynamic model on the number of years of famines. They all lead to the same results: there is room for a political economy of famine based on an analysis of state. State legitimacy prevents famines, controlling for shocks countries might go through, and controlling for the quality of government.
The main contributions of this paper are first to consider the role of state legitimacy in the political economy of famines and second to apply the concept in an empirical analysis, using for the first time a state legitimacy variable
Condensation-Induced Decrease of Small-Angle X-ray Scattering Intensity in Gelling Silica Solutions
peer reviewedWe propose a mathematical modeling of the total SAXS intensity in silica sol-gel processes in terms of hydrolysis and condensation reactions, as well as of microsyneresis. The results are used to rationalize previously published SAXS data of TEOS solutions reacting with organically modified trialkoxysilanes. We notably show that the decrease in SAXS intensity reported for these samples at the end of gelation is a consequence of condensation reactions. The water released by the latter reactions contributes to reduce the electron density difference between the silica and the solvent phases of the gel
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