Longitudinal friction forces in piping design

Scheme measures sliding support friction forces and incorporates them into software programs which are used to analyze piping flexibility

Inelastic neutron scattering studies of methyl chloride synthesis over alumina

Not only is alumina the most widely used catalyst support material in the world, it is also an important catalyst in its own right. One major chemical process that uses alumina in this respect is the industrial production of methyl chloride. This is a large scale process (650 000 metric tons in 2010 in the United States), and a key feedstock in the production of silicones that are widely used as household sealants. In this Account, we show how, in partnership with conventional spectroscopic and reaction testing methods, inelastic neutron scattering (INS) spectroscopy can provide additional insight into the active sites present on the catalyst, as well as the intermediates present on the catalyst surface.<p></p> INS spectroscopy is a form of vibrational spectroscopy, where the spectral features are dominated by modes involving hydrogen. Because of this, most materials including alumina are largely transparent to neutrons. Advantageously, in this technique, the entire “mid-infrared”, 0–4000 cm<sup>–1</sup>, range is accessible; there is no cut-off at 1400 cm<sup>–1</sup> as in infrared spectroscopy. It is also straightforward to distinguish fundamental modes from overtones and combinations. <p></p> A key parameter in the catalyst’s activity is the surface acidity. In infrared spectroscopy of adsorbed pyridine, the shifts in the ring stretching modes are dependent on the strength of the acid site. However, there is a very limited spectral range available. We discuss how we can observe the low energy ring deformation modes of adsorbed pyridine by INS spectroscopy. These modes can undergo shifts that are as large as those seen with infrared inspectroscopy, potentially enabling finer discrimination between acid sites. <p></p> Surface hydroxyls play a key role in alumina catalysis, but in infrared spectroscopy, the presence of electrical anharmonicity complicates the interpretation of the O–H stretch region. In addition, the deformations lie below the infrared cut-off. Both of these limitations are irrelevant to INS spectroscopy, and all the modes are readily observable. When we add HCl to the catalyst surface, the acid causes changes in the spectra. We can then deduce both that the surface chlorination leads to enhanced Lewis acidity and that the hydroxyl group must be threefold coordinated. <p></p> When we react η-alumina with methanol, the catalyst forms a chemisorbed methoxy species. Infrared spectroscopy clearly shows its presence but also indicates the possible coexistence of a second species. Because of INS spectroscopy’s ability to discriminate between fundamental modes and combinations, we were able to unambiguously show that there is a single intermediate present on the surface of the active catalyst. This work represents a clear example where an understanding of the chemistry at the molecular level can help rationalize improvements in a large scale industrial process with both financial and environmental benefits. <p></p&gt

p-Wave stabilization of three-dimensional Bose-Fermi solitons

We explore bright soliton solutions of ultracold Bose-Fermi gases, showing that the presence of p-wave interactions can remove the usual collapse instability and support stable soliton solutions that are global energy minima. A variational model that incorporates the relevant s- and p-wave interactions in the system is established analytically and solved numerically to probe the dependencies of the solitons on key experimental parameters. Under attractive s-wave interactions, bright solitons exist only as meta-stable states susceptible to collapse. Remarkably, the presence of repulsive p-wave interactions alleviates this collapse instability. This dramatically widens the range of experimentally-achievable soliton solutions and indicates greatly enhanced robustness. While we focus specifically on the boson-fermion pairing of 87Rb and 40K, the stabilization inferred by repulsive p-wave interactions should apply to the wider remit of ultracold Bose-Fermi mixtures.Comment: 9 pages, 6 figure

Quality of life and building design in residential and nursing homes for older people

Older people living in residential and nursing care homes spend a large proportion of their time within the boundaries of the home, and may depend on the environment to compensate for their physical or cognitive frailties. Regulations and guidelines on the design of care buildings have accumulated over time with little knowledge of their impact on the quality of life of building users. The Design in Caring Environments Study (DICE) collected cross-sectional data on building design and quality of life in 38 care homes in and near Sheffield, Yorkshire. Quality of life was assessed using methods which included all residents regardless of their frailty, and staff morale was also assessed. The physical environment was measured on 11 user-related domains using a new tool, the Sheffield Care Environment Assessment Matrix (SCEAM). Significant positive associations were found between several aspects of the built environment and the residents' quality of life. There was evidence that a focus on safety and health requirements could be creating risk-averse environments which act against quality of life, particularly for the least frail residents. Staff morale was associated with attributes of a non-institutional environment for residents rather than with the facilities provided for the staff. The new tool for assessing building design has potential applications in further research and for care providers

Properties of AGN coronae in the NuSTAR era

The focussing optics of NuSTAR have enabled high signal-to-noise spectra to be obtained from many X-ray bright Active Galactic Nuclei (AGN) and Galactic Black Hole Binaries (BHB). Spectral modelling then allows robust characterization of the spectral index and upper energy cutoff of the coronal power-law continuum, after accounting for reflection and absorption effects. Spectral-timing studies, such as reverberation and broad iron line fitting, of these sources yield coronal sizes, often showing them to be small and in the range of 3 to 10 gravitational radii in size. Our results indicate that coronae are hot and radiatively compact, lying close to the boundary of the region in the compactness - temperature diagram which is forbidden due to runaway pair production. The coincidence suggests that pair production and annihilation are essential ingredients in the coronae of AGN and BHB and that they control the shape of the observed spectra.Comment: 11 pages, 8 figures, accepted for publication in MNRA