7,507 research outputs found
- and - Relaxation Dynamics of a fragile plastic crystal
We present a thorough dielectric investigation of the relaxation dynamics of
plastic crystalline Freon112, which exhibits freezing of the orientational
degrees of freedom into a glassy crystal below 90 K. Among other plastic
crystals, Freon112 stands out by being relatively fragile within Angell's
classification scheme and by showing an unusually strong -relaxation.
Comparing the results to those on Freon112a, having only a single molecular
conformation, points to the importance of the presence of two molecular
conformations in Freon112 for the explanation of its unusual properties.Comment: 17 pages, 6 figure
Dynamic heterogeneity in the glass-like monoclinic phases of some halogen methane compounds
In this work we study the heterogeneity of the dynamics on the low-temperature monoclinic phases of the simple molecular glassy systems CBrnCl4−nCBrnCl4−n, n = 0, 1, 2. In these systems the disorder comes exclusively from reorientational jumps mainly around the C3 molecular axes. The different time scales are determined by means of the analysis of the spin-lattice relaxation time obtained through Nuclear Quadrupole Resonance (NQR) technique. Results are compared with those obtained from dielectric spectroscopy, from which two α- and β-relaxation times appear. NQR results enable us to ascribe with no doubt that the existence of two relaxations is due to dynamical heterogeneities which are the consequence of the different molecular surroundings of the molecules in the asymmetric unit cell of systems here studied.Fil: Zuriaga, Mariano Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Perez, S. C.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Física Enrique Gaviola. Universidad Nacional de Córdoba. Instituto de Física Enrique Gaviola; ArgentinaFil: Pardo, L. C.. Universidad Politecnica de Catalunya; EspañaFil: Tamarit, J. L.. Universidad Politecnica de Catalunya; Españ
An exploratory canonical analysis approach for multinomial populations based on the -divergence measure
summary:In this paper we consider an exploratory canonical analysis approach for multinomial population based on the -divergence measure. We define the restricted minimum -divergence estimator, which is seen to be a generalization of the restricted maximum likelihood estimator. This estimator is then used in -divergence goodness-of-fit statistics which is the basis of two new families of statistics for solving the problem of selecting the number of significant correlations as well as the appropriateness of the model
New post processing method for interpretation of through casing resistivity (TCR) measurements
We propose a new iterative method for post processing through casing resistivity (TCR) measurements. This method can be seen as a correction or extension of Kaufman´s theory to more complex scenarios, in which the casing is no longer assumed to be uniform along the axis of the borehole. It can also be seen as a simplified inversion method based on the main physic al principles of TCR measurements. To derive our post processing method, we first use the method of images, which enable us to introduce all key factors involved on TCR measurements, including casing length, casing radius, casing thickness, formation resistivity, location of injected current and resistivity distribution of formation layers . Then, we design our iterative Post processing Method by simplifying the complex formulation resulting from using the method of images. Numerical results using goal oriented hp FEM simulations show that our correction method provides a more accurate approximation to the actual formation resistivity than that predicted by Kaufman´s theory. In addition, the new method is pr oven to be very efficient and robust, since it is independent of spatial resistivity variations in the formation.MTM2010 1651
Module identification in bipartite and directed networks
Modularity is one of the most prominent properties of real-world complex
networks. Here, we address the issue of module identification in two important
classes of networks: bipartite networks and directed unipartite networks. Nodes
in bipartite networks are divided into two non-overlapping sets, and the links
must have one end node from each set. Directed unipartite networks only have
one type of nodes, but links have an origin and an end. We show that directed
unipartite networks can be conviniently represented as bipartite networks for
module identification purposes. We report a novel approach especially suited
for module detection in bipartite networks, and define a set of random networks
that enable us to validate the new approach
Millimeter and sub-millimeter atmospheric performance at Dome C combining radiosoundings and ATM synthetic spectra
The reliability of astronomical observations at millimeter and sub-millimeter
wavelengths closely depends on a low vertical content of water vapor as well as
on high atmospheric emission stability. Although Concordia station at Dome C
(Antarctica) enjoys good observing conditions in this atmospheric spectral
windows, as shown by preliminary site-testing campaigns at different bands and
in, not always, time overlapped periods, a dedicated instrument able to
continuously determine atmospheric performance for a wide spectral range is not
yet planned. In the absence of such measurements, in this paper we suggest a
semi-empirical approach to perform an analysis of atmospheric transmission and
emission at Dome C to compare the performance for 7 photometric bands ranging
from 100 GHz to 2 THz. Radiosoundings data provided by the Routine
Meteorological Observations (RMO) Research Project at Concordia station are
corrected by temperature and humidity errors and dry biases and then employed
to feed ATM (Atmospheric Transmission at Microwaves) code to generate synthetic
spectra in the wide spectral range from 100 GHz to 2 THz. To quantify the
atmospheric contribution in millimeter and sub-millimeter observations we are
considering several photometric bands in which atmospheric quantities are
integrated. The observational capabilities of this site at all the selected
spectral bands are analyzed considering monthly averaged transmissions joined
to the corresponding fluctuations. Transmission and pwv statistics at Dome C
derived by our semi-empirical approach are consistent with previous works. It
is evident the decreasing of the performance at high frequencies. We propose to
introduce a new parameter to compare the quality of a site at different
spectral bands, in terms of high transmission and emission stability, the Site
Photometric Quality Factor.Comment: accepted to MNRAS with minor revision
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