Exploring the democratic potential of online social networking: The scope and limitations of e-participation

Copyright © 2012 by the Association for Information Systems.The availability and promise of social networking technologies with their perceived open philosophy has increasingly inspired citizens around the world to participate in political activity on the Web. Recent examples range from opposing public policies, such as government funding cuts, to organizing revolutionary social movements, such as those in the Middle East and North Africa. Although online spaces create remarkable opportunities for various forms of political action, there are concerns over the power of existing institutions to control and even censor such interaction spaces. The objective of this article is to draw together different insights on the online engagement phenomenon, highlighting both its potential and limitations as a mechanism for fostering democratic debate and influencing policy making. We examine recent examples from Europe, the Middle East and Latin America. Finally, we summarize the implications of our work and outline directions for further research

Structural and magnetic properties of Ru/Ni multilayers

International audienceRu/Ni multilayers of different Ni thickness have been fabricated using magnetron sputtering. The structure of the multilayers has been determined by grazing incidence X-ray diffraction and X-ray reflectivity and their magnetic properties by magnetization and polarized neutron reflectivity measurements. The presence of Ru leads to the formation of a hexagonal Ni structure within interfacial layer ~1 nm above each Ru layer, while the rest of the Ni layer relaxes to the equilibrium fcc structure. The hcp Ni interfacial layer has a substantially increased cell volume is ferromagnetic with an atomic magnetic moment that increases with Ni layer thickness but remains lower than the value predicted from ab initio calculations

Crowding of Polymer Coils and Demixing in Nanoparticle-Polymer Mixtures

The Asakura-Oosawa-Vrij (AOV) model of colloid-polymer mixtures idealizes nonadsorbing polymers as effective spheres that are fixed in size and impenetrable to hard particles. Real polymer coils, however, are intrinsically polydisperse in size (radius of gyration) and may be penetrated by smaller particles. Crowding by nanoparticles can affect the size distribution of polymer coils, thereby modifying effective depletion interactions and thermodynamic stability. To analyse the influence of crowding on polymer conformations and demixing phase behaviour, we adapt the AOV model to mixtures of nanoparticles and ideal, penetrable polymer coils that can vary in size. We perform Gibbs ensemble Monte Carlo simulations, including trial nanoparticle-polymer overlaps and variations in radius of gyration. Results are compared with predictions of free-volume theory. Simulation and theory consistently predict that ideal polymers are compressed by nanoparticles and that compressibility and penetrability stabilise nanoparticle-polymer mixtures.Comment: 18 pages, 4 figure

Maximum Valency Lattice Gas Models

We study lattice gas models with the imposition of a constraint on the maximum number of bonds (nearest neighbor interactions) that particles can participate in. The critical parameters, as well as the coexistence region are studied using the mean field approximation and the Bethe-Peierls approximation. We find that the reduction of the number of interactions suppresses the temperature-density region where the liquid and gas phases coexist. We confirm these results from simulations using the histogram reweighting method employing grand Canonical Monte Carlo simulations

Universality class of criticality in the restricted primitive model electrolyte

The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using temperature-density, (T, rho), loci of inflections, Q = ^2/ maxima, canonical and C_V criticality, yield estimates of (T_c, rho_c) to +- (0.04, 3)%. Extrapolated exponents and Q-ratio are (gamma, nu, Q_c) = [1.24(3), 0.63(3); 0.624(2)] which support Ising (n = 1) behavior with (1.23_9, 0.630_3; 0.623_6), but exclude classical, XY (n = 2), SAW (n = 0), and n = 1 criticality with potentials phi(r)>Phi/r^{4.9} when r \to \infty

Coexistence and Criticality in Size-Asymmetric Hard-Core Electrolytes

Liquid-vapor coexistence curves and critical parameters for hard-core 1:1 electrolyte models with diameter ratios lambda = sigma_{-}/\sigma_{+}=1 to 5.7 have been studied by fine-discretization Monte Carlo methods. Normalizing via the length scale sigma_{+-}=(sigma_{+} + sigma_{-})/2 relevant for the low densities in question, both Tc* (=kB Tc sigma_{+-}/q^2 and rhoc* (= rhoc sigma _{+-}^{3}) decrease rapidly (from ~ 0.05 to 0.03 and 0.08 to 0.04, respectively) as lambda increases. These trends, which unequivocally contradict current theories, are closely mirrored by results for tightly tethered dipolar dimers (with Tc* lower by ~ 0-11% and rhoc* greater by 37-12%).Comment: 4 pages, 5 figure

Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model

We present a systematic study of the effect of the ion pairing on the gas-liquid phase transition of hard-core 1:1 electrolyte models. We study a class of dipolar dimer models that depend on a parameter R_c, the maximum separation between the ions that compose the dimer. This parameter can vary from sigma_{+/-} that corresponds to the tightly tethered dipolar dimer model, to R_c --> infinity, that corresponds to the Stillinger-Lovett description of the free ion system. The coexistence curve and critical point parameters are obtained as a function of R_c by grand canonical Monte Carlo techniques. Our results show that this dependence is smooth but non-monotonic and converges asymptotically towards the free ion case for relatively small values of R_c. This fact allows us to describe the gas-liquid transition in the free ion model as a transition between two dimerized fluid phases. The role of the unpaired ions can be considered as a perturbation of this picture.Comment: 16 pages, 13 figures, submitted to Physical Review

Advanced ultra-light multifunctional metallic-glass wave springs

We show that, using thermo -elastic processing, metallic -glass foils can be shaped, without being embrittled, into linear and annular wave springs. These springs exhibit an undulatory behaviour, unique to metallic -glass foils, in which under compression the number of arcs in the spring increases, increasing the load -bearing capacity and the spring constant. We evaluate the performance limits of the metallic -glass wave springs, and consider how the undulatory behaviour can be exploited. The metallic -glass springs can operate over the same load -ranges as commercially available crystalline wave springs, but have material volumes (and therefore weights) that are one to two orders of magnitude less. Their energy storage per unit material volume is as high as 2600 kJ m – 3 . We suggest that the undulatory behaviour is important in rendering the springs fail -safe in case of overload. We discuss the range of applicability of thermo -elastic processing, the likely working limit of metallic -glass wave springs, and the potential for application of metallic -glass springs in MEMS devices