Surfactant doped polyaniline coatings for functionalized gas diffusion layers in low temperature fuel cells

Gas diffusion layers (GDLs) are essential for the proper distribution of the reaction gases, the removal of excess water as well as electrical contact in polymer electrolyte fuel cells (PEFCs). The production of state-of-the-art GDLs consists of many steps such as graphitization at high temperatures and hydrophobic treatments with polytetrafluoroethylene (PTFE) which increase the cost. In this study, an electrically conductive and hydrophobic polyaniline (PANI) coating was deposited on carbon paper via dip-coating and electropolymerization to fabricate PTFE-free GDLs. As a proof-of-concept, PANI-coated GDLs were tested as a cathodic GDL in a single cell PEFC and achieved a 42% higher maximum power compared to the reference measurement with a commercial GDL. Furthermore, these PTFE-free GDLs achieved contact angles up to 144° which is in the range of commercial GDLs. The chemical composition of the PANI-coating was investigated via infrared spectroscopy and energy dispersive X-ray spectroscopy (EDX) and the morphology was examined via scanning electron microscopy (SEM). Hence, the proposed method emerges as a possible strategy to simultaneously substitute PTFE and apply a protective and durable coating.</p

Hydrogen for electromobility : a promising energy carrier

Electromobility has received important attention in the last few years, but its perception by the public and decision makers is often limited to battery powered vehicles. Alternatives such as hydrogen fuel cells should however be taken into account, as their specific advantages (in particular short refueling times) make electro-mobility as a whole acceptable by a much broader public. Within the SCCER Mobility, PSI and ZHAW work on a novel fuel cell concept aiming at reducing the major limitation to the deployment of fuel cells: their cost

An assessment of thermocline-control methods for packed-bed thermal-energy storage in CSP plants, Part 1: Method descriptions

Thermocline thermal-energy storage (TES) suffers from so-called thermocline degradation, which refers to the flattening of temperature gradients in the TES with successive charging-discharging cycles. Thermocline degradation increases the variations of the heat-transfer fluid (HTF) outflow temperatures, decreases storage utilization factors, and increases specific TES material costs. Methods that prevent or reduce thermocline degradation by changing the operation of the storage are called thermocline-control (TCC) methods. The assessment of TCC methods is the main objective of this work. Three TCC methods that were chosen for this assessment are described in this paper. Two methods, based on either extracting or injecting HTF through ports, were derived from previously published methods while the third method, based on mixing multiple HTF streams, one of which is extracted through a port, is novel. In a companion paper (Geissbühler et al., Solar Energy, submitted 2018), the three TCC methods are assessed for air and molten salt as HTF using simulations of stand-alone storages as well as storages integrated into a concentrated solar power plant.ISSN:0038-092XISSN:1471-125

An assessment of thermocline-control methods for packed-bed thermal-energy storage in CSP plants, Part 2: Assessment strategy and results

Three thermocline-control (TCC) methods are assessed through numerical simulations for a thermal-energy storage (TES) filled with a packed bed of rocks. Two previously suggested methods are based on extracting or injecting heat-transfer fluid (HTF) through ports, while the third is a novel method based on mixing HTF streams. The assessment was carried out using simulations with a model that resolves the packed bed in one dimension. Simulations of stand-alone TES with maximum allowed outflow temperature differences of 10% at quasi-steady conditions showed that the mixing method with three ports led to the largest utilization factors – the fraction of the maximum storage capacity that is actually utilized – of 90.8% and 85.1% for molten salt (MS) and compressed air (CA) as HTF, respectively. These represent relative improvements of 38.8% and 73.4% compared to the baseline configurations without TCC. The increased utilization factors come at the expense of small decreases in the cycle exergy efficiency. For the mixing method with three ports, the exergy efficiencies were 97.3% and 95.6% for MS and CA, respectively. Simulations of a TES with MS as HTF integrated into a CSP plant operating on a Rankine steam cycle showed that TCC increases the annually averaged plant efficiency and the annual net electricity generated solely from thermal energy supplied by the TES. These results suggest that the small decreases in the exergy efficiency of the TES are outweighed by the large increases in the utilization factor.ISSN:0038-092XISSN:1471-125

Manufacturing free-standing porous layers with dynamic hydrogen bubble templating

The three-dimensional structure – i.e. microstructure – of porous electrodes governs the performance of emerging electrochemical technologies such as fuel cells, electrolysis and batteries. Sustaining electrochemical reactions and convective-diffusive mass transport at high efficiency is complex and motivates the search for sophisticated microstructures with multimodal pore size distributions and pore size gradients. Drawing inspiration from porous metallic foams, here we engineer a novel method to manufacture free-standing, thin, porous foams via dynamic hydrogen bubble templating in an electrochemical flow cell, through the introduction of an intermediate layer and optimization of synthesis parameters (i.e. voltage, concentration and charge). We create mechanically stable foams with thicknesses ranging from ~50 µm to ~200 µm comprising porous, dendritic structures, arranged to form a vascular network of larger pores with a gradient in radii from ~5 µm at the bottom and up to ~36 µm at the top of the material. Using segmented X-ray tomographic data, we simulate the diffusive transport through the material as function of liquid filling and compare it to carbon fiber-based material. For all ranges of saturation, the metallic foams outperforms the fibrous structure, showcasing the potential of bimodal pore size architectures to improve two phase transport by optimizing the distribution of phases

Elucidating the nuanced effects of thermal pretreatment on carbon paper electrodes for vanadium Redox flow batteries

Sluggish vanadium reaction rates on the porous carbon electrodes typically used in redox flow batteries have prompted research into pretreatment strategies, most notably thermal oxidation, to improve performance. While effective, these approaches have nuanced and complex effects on electrode characteristics hampering the development of explicit structure–function relations that enable quantitative correlation between specific properties and overall electrochemical performance. Here, we seek to resolve these relationships through rigorous analysis of thermally pretreated SGL 29AA carbon paper electrodes using a suite of electrochemical, microscopic, and spectroscopic techniques and culminating in full cell testing. We systematically vary pretreatment temperature, from 400 to 500 °C, while holding pretreatment time constant at 30 h, and evaluate changes in the physical, chemical, and electrochemical properties of the electrodes. We find that several different parameters contribute to observed performance, including hydrophilicity, microstructure, electrochemical surface area, and surface chemistry, and it is important to note that not all of these properties improve with increasing pretreatment temperature. Consequently, while the best overall performance is achieved with a 475 °C pretreatment, this enhancement is achieved from a balance, rather than a maximization, of critical properties. A deeper understanding of the role each property plays in battery performance is the first step toward developing targeted pretreatment strategies that may enable transformative performance improvements