Albedo and flux extinction coefficient of impure snow for diffuse shortwave radiation

Impurities enter a snowpack as a result of fallout of scavenging by falling snow crystals. Albedo and flux extinction coefficient of soot contaminated snowcovers were studied using a two stream approximation of the radiative transfer equation. The effect of soot was calculated by two methods: independent scattering by ice grains and impurities and average refractive index for ice grains. Both methods predict a qualitatively similar effect of soot; the albedo is decreased and the extinction coefficient is increased compared to that for pure snow in the visible region; the infrared properties are largely unaffected. Quantitatively, however, the effect of soot is more pronounced in the average refractive index method. Soot contamination provides a qualitative explanation for several snow observations

The Far-Infrared Background Correlation with CMB Lensing

The intervening large--scale structure distorts cosmic microwave background (CMB) anisotropies via gravitational lensing. The same large--scale structure, traced by dusty star--forming galaxies, also induces anisotropies in the far--infrared background (FIRB). We investigate the resulting inter--dependence of the FIRB and CMB with a halo model for the FIRB. In particular, we calculate the cross--correlation between the lensing potential and the FIRB. The lensing potential can be quadratically estimated from CMB temperature and/or polarization maps. We show that the cross--correlation can be measured with high signal--to--noise with data from the Planck Surveyor. We discuss how such a measurement can be used to understand the nature of FIRB sources and their relation to the distribution of dark matter.Comment: 9 pages, 5 figures, submitted to Ap

Magnetic structure of the field-induced multiferroic GdFe3(BO3)4

We report a magnetic x-ray scattering study of the field-induced multiferroic GdFe3(BO3)4. Resonant x-ray magnetic scattering at the Gd LII,III edges indicates that the Gd moments order at TN ~ 37 K. The magnetic structure is incommensurate below TN, with the incommensurability decreasing monotonically with decreasing temperature until a transition to a commensurate magnetic phase is observed at T ~ 10 K. Both the Gd and Fe moments undergo a spin reorientation transition at TSR ~ 9 K such that the moments are oriented along the crystallographic c axis at low temperatures. With magnetic field applied along the a axis, our measurements suggest that the field-induced polarization phase has a commensurate magnetic structure with Gd moments rotated ~45 degrees toward the basal plane, which is similar to the magnetic structure of the Gd subsystem observed in zero field between 9 and 10 K, and the Fe subsystem has a ferromagnetic component in the basal plane.Comment: 27 pages, 7 figures, to appear in Phys. Rev.

Turmeric dyeing and chitosan/titanium dioxide nanoparticle colloid finishing of cotton fabric

The possibility of combining the finishing and natural dyeing of cotton fabric has been studied using a single-stage, paddry-cure technique, by treating it with chitosan/titanium dioxide nanoparticle colloids and turmeric dye. Differentparameters have been studied to optimise the process, such as the chitosan/TiO2 nanoparticle colloid concentration, citricacid crosslinker concentration, sodium pyrophosphate catalyst concentration, dye concentration, pH, curing time, andtemperature. To investigate the effects of combined treatment on the dyeing and functional properties of the treated cottonfabric, its ultraviolet protection factor, antibacterial activity, self-cleaning properties, rigidity, colour strength (K/S), fastnessbehaviour, nitrogen content, and wettability are determined. In addition, the cotton fabric surface is characterised usingscanning electron microscopy. The samples treated with chitosan/TiO2 in the presence of citric acid exhibit excellentprotection against ultraviolet radiation as well as antibacterial activity. The optimum conditions are 0.75% TiO2 (w/v), 10% dye (w/v), 2.5% chitosan (w/v), 30 g/L citric acid, 4 g/L sodium pyrophosphate, 70°C drying temp. and 5 min drying time,180°C curing temp. and 2 min curing time. The results also indicate the efficiency of the treatment in improving the selfcleaningproperties of the fabric. A significant improvement in the colour fastness is observed for the treated fabrics

Nonlinear Gravitational Clustering: dreams of a paradigm

We discuss the late time evolution of the gravitational clustering in an expanding universe, based on the nonlinear scaling relations (NSR) which connect the nonlinear and linear two point correlation functions. The existence of critical indices for the NSR suggests that the evolution may proceed towards a universal profile which does not change its shape at late times. We begin by clarifying the relation between the density profiles of the individual halo and the slope of the correlation function and discuss the conditions under which the slopes of the correlation function at the extreme nonlinear end can be independent of the initial power spectrum. If the evolution should lead to a profile which preserves the shape at late times, then the correlation function should grow as $a^2$ [in a $\Omega=1$ universe] een at nonlinear scales. We prove that such exact solutions do not exist; however, ther e exists a class of solutions (``psuedo-linear profiles'', PLP's for short) which evolve as $a^2$ to a good approximation. It turns out that the PLP's are the correlation functions which arise if the individual halos are assumed to be isothermal spheres. They are also configurations of mass in which the nonlinear effects of gravitational clustering is a minimum and hence can act as building blocks of the nonlinear universe. We discuss the implicatios of this result.Comment: 32 Pages, Submitted to Ap

An open and parallel multiresolution framework using block-based adaptive grids

A numerical approach for solving evolutionary partial differential equations in two and three space dimensions on block-based adaptive grids is presented. The numerical discretization is based on high-order, central finite-differences and explicit time integration. Grid refinement and coarsening are triggered by multiresolution analysis, i.e. thresholding of wavelet coefficients, which allow controlling the precision of the adaptive approximation of the solution with respect to uniform grid computations. The implementation of the scheme is fully parallel using MPI with a hybrid data structure. Load balancing relies on space filling curves techniques. Validation tests for 2D advection equations allow to assess the precision and performance of the developed code. Computations of the compressible Navier-Stokes equations for a temporally developing 2D mixing layer illustrate the properties of the code for nonlinear multi-scale problems. The code is open source

Liquefaction of H2 molecules upon exterior surfaces of carbon nanotube bundles

We have used molecular dynamics simulations to investigate interaction of H2 molecules on the exterior surfaces of carbon nanotubes (CNTs): single and bundle types. At 80 K and 10 MPa, it is found that charge transfer occurs from a low curvature region to a high curvature region of the deformed CNT bundle, which develops charge polarization only on the deformed structure. The long-range electrostatic interactions of polarized charges on the deformed CNT bundle with hydrogen molecules are observed to induce a high local-ordering of H2 gas that results in hydrogen liquefaction. Our predicted heat of hydrogen liquefaction on the CNT bundle is 97.6 kcal kg^-1. On the other hand, hydrogen liquefaction is not observed in the CNT of a single type. This is because charge polarization is not developed on the single CNT as it is symmetrically deformed under the same pressure. Consequently, the hydrogen storage capacity on the CNT bundle is much higher due to liquefaction than that on the single CNT. Additionally, our results indicate that it would also be possible to liquefy H2 gas on a more strongly polarized CNT bundle at temperatures higher than 80 K

The theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. I. The reactive force field ReaxFFHBN development

We present a new reactive force field ReaxFFHBN derived to accurately model large molecular and condensed phase systems of H, B, and N atoms. ReaxFFHBN has been tested against quantum calculation data for B–H, B–B, and B–N bond dissociations and for H–B–H, B–N–B, and N–B–N bond angle strain energies of various molecular clusters. The accuracy of the developed ReaxFFHBN for B–N–H systems is also tested for (i) H–B and H–B bond energies as a function of out of plane in H–B(NH2)3 and H–N(BH2)3, respectively, (ii) the reaction energy for the B3N3H6+H2-->B3N3H8, and (iii) crystal properties such as lattice parameters and equations of states for the hexagonal type (h-BN) with a graphite structure and for the cubic type (c-BN) with a zinc-blende structure. For all these systems, ReaxFFHBN gives reliable results consistent with those from quantum calculations as it describes well bond breaking and formation in chemical processes and physical properties. Consequently, the molecular-dynamics simulation based on ReaxFFHBN is expected to give a good description of large systems (>2000 atoms even on the one-CPU machine) with hydrogen, boron, and nitrogen atoms

Theoretical study on interaction of hydrogen with single-walled boron nitride nanotubes. II. Collision, storage, and adsorption

Collision and adsorption of hydrogen with high incident kinetic energies on a single-walled boron nitride (BN) nanotube have been investigated. Molecular-dynamics (MD) simulations indicate that at incident energies below 14 eV hydrogen bounces off the BN nanotube wall. On the other hand, at incident energies between 14 and 22 eV each hydrogen molecule is dissociated at the exterior wall to form two hydrogen atoms, but only one of them goes through the wall. However, at the incident energies between 23 and 26 eV all of the hydrogen atoms dissociated at the exterior wall are found to be capable of going inside the nanotube and then to recombine to form hydrogen molecules inside the nanotube. Consequently, it is determined that hydrogen should have the incident energy >22 eV to go inside the nanotube. On the other hand, we find that the collisions using the incident energies >26 eV could result in damaging the nanotube structures. In addition our MD simulations find that hydrogen atoms dissociated at the wall cannot bind to either boron or nitrogen atoms in the interior wall of the nanotube

Asymptotics for a special solution to the second member of the Painleve I hierarchy

We study the asymptotic behavior of a special smooth solution y(x,t) to the second member of the Painleve I hierarchy. This solution arises in random matrix theory and in the study of Hamiltonian perturbations of hyperbolic equations. The asymptotic behavior of y(x,t) if x\to \pm\infty (for fixed t) is known and relatively simple, but it turns out to be more subtle when x and t tend to infinity simultaneously. We distinguish a region of algebraic asymptotic behavior and a region of elliptic asymptotic behavior, and we obtain rigorous asymptotics in both regions. We also discuss two critical transitional asymptotic regimes.Comment: 19 page