342 research outputs found

    Evaluation of extractants for estimation of the phytoavailable trace metals in soils

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    Despite its environmental (and financial) importance, there is no agreement in the literature as to which extractant most accurately estimates the phytoavailability of trace metals in soils. A large dataset was taken from the literature, and the effectiveness of various extractants to predict the phytoavailability of Cd, Zn, Ni, Cu, and Pb examined across a range of soil types and contamination levels. The data suggest that generally, the total soil trace metal content, and trace metal concentrations determined by complexing agents (such as the widely used DTPA and EDTA extractants) or acid extractants (such as 0.1 M HCl and the Mehlich 1 extractant) are only poorly correlated to plant phytoavailability. Whilst there is no consensus, it would appear that neutral salt extractants (such as 0.01 M CaCl2 and 0.1 M NaNO3) provide the most useful indication of metal phytoavailability across a range of metals of interest, although further research is required

    Toxic effects of low concentrations of Cu on nodulation of cowpea (Vigna unguiculata)

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    Although Cu is phytotoxic at Cu(2+) activities as low as 1-2 mu M, the effect of Cu(2+) on the nodulation of legumes has received little attention. The effect of Cu(2+) on nodulation of cowpea (Vigna unguiculata (L.) Walp. cv. Caloona) was examined in a dilute solution culture system utilising a cation exchange resin to buffer solution Cu(2+). The nodulation process was more sensitive to increasing Cu(2+) activities than both shoot and root growth; whilst a Cu(2+) activity of 1.0 mu M corresponded to a 10% reduction in the relative yield of the shoots and roots, a Cu(2+) activity of 0.2 mu M corresponded to a 10% reduction in nodulation. This reduction in nodulation with increasing Cu(2+) activity was associated with an inhibition of root hair formation in treatments containing >= 0.77 mu M Cu(2+), rather than to a reduction in the size of the Rhizobium population. (c) 2006 Elsevier Ltd. All rights reserved

    In-situ Soil Solution Extraction with Polyacrylonitrile Hollow-Fibers

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    Hollow-fiber samplers permit the non-destructive extraction of the soil solution from the soil matrix. Samplers constructed from polyacrylonitrile filter elements were successfully used to extract solution from a range of soil types. Preliminary testing showed that the filter elements did not retain any of the major anions or cations present in soil solution. Inorganic ions capable of specific adsorption (PO₄ and Cu) were not retained, but phytate concentration was reduced by passage through the filter. Comparison with centrifuge drainage extraction showed that soil solution obtained from hollow-fiber samplers had a higher pH, as a result of CO₂ degassing, and lower elemental concentrations. It was concluded that the hollow-fiber samplers were preferentially extracting solution from the larger pores, and that this solution may better represent that extracted by plants

    Ιστορική και πολεοδομική εξέλιξη της πόλης του Βερολίνου - Συγκριτική μελέτη αναβάθμισης υποβαθμισμένων περιοχών σε Αθήνα και Βερολίνο

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    130 σ.Αντικείμενο της διπλωματικής εργασίας είναι η ιστορική αναδρομή και πολεοδομική εξέλιξη της πόλης του Βερολίνου από την ίδρυσή της μέχρι σήμερα, όπως και η σύγκριση δύο πρώην υποβαθμισμένων περιοχών που αναβαθμίστηκαν τις τελευταίες δύο δεκαετίες, σε Βερολίνο και Αθήνα αντίστοιχα. Η περιγραφή αυτή έχει ως σκοπό την παρουσίαση της σπουδαιότητας και του ρόλου του Βερολίνου δια μέσου των αιώνων, την επισήμανση των πολιτικών, νομοθετικών και πολεοδομικών γεγονότων και εξελίξεων που έπαιξαν σημαντικό ρόλο στην πορεία του, καθώς και τον εντοπισμό ομοιοτήτων και διαφορών από την ανάλυση της σύγκρισης των δύο περιοχών μελέτης. Η παρούσα διπλωματική εργασία αποτελείται από έξι κεφάλαια. Στο Κεφάλαιο 1 δίνονται γενικές πληροφορίες για το Βερολίνο, περιγράφοντας τη γεωγραφική θέση και έκταση, το κλίμα, τον πληθυσμό, τα δημογραφικά στοιχεία και την διοικητική διαίρεση της πόλης. Στο Κεφάλαιο 2 παρουσιάζεται η ιστορική αναδρομή του Βερολίνου από την ίδρυση του το 1237 μέχρι και σήμερα, επισημαίνοντας τα σημαντικότερα ιστορικά γεγονότα. Στο Κεφάλαιο 3 αναλύονται πολεοδομικά σχέδια (Σχέδια Χρήσης Γης), που έπαιξαν σημαντικό ρόλο στην εξέλιξη του Βερολίνου, ως προς τον σκοπό, το περιεχόμενο και τις επιπτώσεις τους, περιγράφοντας παράλληλα την πολιτική, νομοθετική και πολεοδομική εξέλιξη της πόλης. Στο Κεφάλαιο 4 εξετάζεται η αναβάθμιση της περιοχή μελέτης Warschauer Straße του Βερολίνου. Στο Κεφάλαιο 5 εξετάζεται η αναβάθμιση της περιοχής μελέτης του Γκαζιού της Αθήνας. Στο Κεφάλαιο 6 περιλαμβάνονται τα συμπεράσματα και τα αποτελέσματα της σύγκρισης των δύο περιοχών μελέτης.Subject of the thesis is the historical overview and urban development of the city of Berlin from its foundation until today, as well as the comparison of two formerly degraded areas that have been upgraded over the past two decades, in Berlin and Athens respectively. This description is intended to show the importance and role of Berlin through the ages, highlight political, legislative and planning events and developments that played an important role in its course, and identify similarities and differences from the comparison analysis of the two study areas. This thesis consists of six chapters. Chapter 1 contains general information about Berlin, describing the geographical location and area, climate, population, demographics and administrative division of the city. Chapter 2 presents the historical overview of Berlin from its founding in 1237 until today, highlighting the most important historical events. In Chapter 3 we continue with the analysis of the aim, the contents, and the impact of urban plans (Land Use Plans), which played an important role in the evolution of Berlin, while describing the political, legislative and urban development of the city. Chapter 4 examines the upgrade of the study area Warschauer Straße, Berlin. Chapter 5 examines the upgrade of the study area of Gazi, Athens. Chapter 6 gives the conclusions and results of the comparison of the two study areas.Βασίλειος Σ. Βλάχο

    Effect of cultivation on soil C contents and saturated hydraulic conductivity

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    Abstract The irrigation of pasture with saline, Na-contaminated industrial wastewater typically results in an increase in soil ESP. From current knowledge (derived largely from cultivated agricultural soils), although these sodic soils are likely to remain stable whilst irrigated with effluent (due to the effluent's large electrolyte concentration), during rainfall periods of low electrolyte concentration these soils would be expected to disperse. However, effluent irrigated pasture soils have been observed to maintain their structure even during intense rainfall events. Three soil types were collected (Sodosol, Vertosol and Dermosol), each with a cultivated/non-cultivated pair. The soils were equilibrated with various SAR solutions and then leached with deionised water to allow the measurement of saturated hydraulic conductivity (K sat ). At low SARs, K sat tended to be greater in non-cultivated than cultivated soils and is attributable to a loss of structure associated with cultivation. In addition, as SAR increased, the reduction in relative K sat tended to be significantly greater in cultivated than non-cultivated soils. The relatively rapid saturated hydraulic conductivity in the non-cultivated soils at large SARs is due to a greater aggregate stability due to greater soil C content. For the sustainable disposal of saline effluent, it is therefore necessary to ensure that soils remain undisturbed and preferably under pasture, thus maximising soil structural stability and hydraulic conductivity
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