Molecular ferroelectric contributions to anomalous hysteresis in hybrid perovskite solar cells

We report a model describing the molecular orientation disorder in CH3NH3PbI3, solving a classical Hamiltonian parametrised with electronic structure calculations, with the nature of the motions informed by ab-initio molecular dynamics. We investigate the temperature and static electric field dependence of the equilibrium ferroelectric (molecular) domain structure and resulting polarisability. A rich domain structure of twinned molecular dipoles is observed, strongly varying as a function of temperature and applied electric field. We propose that the internal electrical fields associated with microscopic polarisation domains contribute to hysteretic anomalies in the current--voltage response of hybrid organic-inorganic perovskite solar cells due to variations in electron-hole recombination in the bulk.Comment: 10 pages; 4 figures, 2 SI figure

The Carrington event not observed in most ice core nitrate records

The Carrington Event of 1859 is considered to be among the largest space weather events of the last 150 years. We show that only one out of 14 well-resolved ice core records from Greenland and Antarctica has a nitrate spike dated to 1859. No sharp spikes are observed in the Antarctic cores studied here. In Greenland numerous spikes are observed in the 40 years surrounding 1859, but where other chemistry was measured, all large spikes have the unequivocal signal, including co-located spikes in ammonium, formate, black carbon and vanillic acid, of biomass burning plumes. It seems certain that most spikes in an earlier core, including that claimed for 1859, are also due to biomass burning plumes, and not to solar energetic particle (SEP) events. We conclude that an event as large as the Carrington Event did not leave an observable, widespread imprint in nitrate in polar ice. Nitrate spikes cannot be used to derive the statistics of SEPs

Using aircraft measurements to determine the refractive index of Saharan dust during the DODO Experiments

Much uncertainty in the value of the imaginary part of the refractive index of mineral dust contributes to uncertainty in the radiative effect of mineral dust in the atmosphere. A synthesis of optical, chemical and physical in-situ aircraft measurements from the DODO experiments during February and August 2006 are used to calculate the refractive index mineral dust encountered over West Africa. Radiative transfer modeling and measurements of broadband shortwave irradiance at a range of altitudes are used to test and validate these calculations for a specific dust event on 23 August 2006 over Mauritania. Two techniques are used to determine the refractive index: firstly a method combining measurements of scattering, absorption, size distributions and Mie code simulations, and secondly a method using composition measured on filter samples to apportion the content of internally mixed quartz, calcite and iron oxide-clay aggregates, where the iron oxide is represented by either hematite or goethite and clay by either illite or kaolinite. The imaginary part of the refractive index at 550 nm (ni550) is found to range between 0.0001 i to 0.0046 i, and where filter samples are available, agreement between methods is found depending on mineral combination assumed. The refractive indices are also found to agree well with AERONET data where comparisons are possible. ni550 is found to vary with dust source, which is investigated with the NAME model for each case. The relationship between both size distribution and ni550 on the accumulation mode single scattering albedo at 550 nm (ω0550) are examined and size distribution is found to have no correlation to ω0550, while ni550 shows a strong linear relationship with ω0550. Radiative transfer modeling was performed with different models (Mie-derived refractive indices, but also filter sampling composition assuming both internal and external mixing). Our calculations indicate that Mie-derived values of ni550 and the externally mixed dust where the iron oxide-clay aggregate corresponds to the goethite-kaolinite combination result in the best agreement with irradiance measurements. The radiative effect of the dust is found to be very sensitive to the mineral combination (and hence refractive index) assumed, and to whether the dust is assumed to be internally or externally mixed

Comment on “Low time resolution analysis of ice cores cannot detect impulsive nitrate events” by D. F. Smart et al.

Smart et al. (2014) suggested that the detection of nitrate spikes in polar ice cores from solar energetic particle (SEP) events could be achieved if an analytical system with sufficiently high resolution was used. Here we show that the spikes they associate with SEP events are not reliably recorded in cores from the same location, even when the resolution is clearly adequate. We explain the processes that limit the effective resolution of ice cores. Liquid conductivity data suggest that the observed spikes are associated with sodium or another nonacidic cation, making it likely that they result from deposition of sea salt or similar aerosol that has scavenged nitrate, rather than from a primary input of nitrate in the troposphere. We consider that there is no evidence at present to support the identification of any spikes in nitrate as representing SEP events. Although such events undoubtedly create nitrate in the atmosphere, we see no plausible route to using nitrate spikes to document the statistics of such events

Polarized Diffuse Emission at 2.3 GHz in a High Galactic Latitude Area

Polarized diffuse emission observations at 2.3 GHz in a high Galactic latitude area are presented. The 2\degr X 2\degr field, centred in (\alpha=5^h,\delta=-49\degr), is located in the region observed by the BOOMERanG experiment. Our observations has been carried out with the Parkes Radio telescope and represent the highest frequency detection done to date in low emission areas. Because of a weaker Faraday rotation action, the high frequency allows an estimate of the Galactic synchrotron contamination of the Cosmic Microwave Background Polarization (CMBP) that is more reliable than that done at 1.4 GHz. We find that the angular power spectra of the E- and B-modes have slopes of \beta_E = -1.46 +/- 0.14 and \beta_B = -1.87 +/- 0.22, indicating a flattening with respect to 1.4 GHz. Extrapolated up to 32 GHz, the E-mode spectrum is about 3 orders of magnitude lower than that of the CMBP, allowing a clean detection even at this frequency. The best improvement concerns the B-mode, for which our single-dish observations provide the first estimate of the contamination on angular scales close to the CMBP peak (about 2 degrees). We find that the CMBP B-mode should be stronger than synchrotron contamination at 90 GHz for models with T/S > 0.01. This low level could move down to 60-70 GHz the optimal window for CMBP measures.Comment: 5 pages, 6 figures, accepted for publication in MNRAS Letter

Observations on groundwater recharge in the Westdale catchment

A study of the role of groundwater carriers and barriers in controlling salinity was carried out in the Westdale Catchment by Lewis and McConnell (in preparation). Although that study was primarily concerned with groundwater flow and discharge processes, the data collected also provided rudimentary information on the timing of groundwater recharge events and their distribution across the landscape

SONTRAC: an imaging spectrometer for solar neutrons

An instrument capable of unambiguously determining the energy and direction of incident neutrons has important applications in solar physics-as well as environmental monitoring and medical/radiological sciences. The SONTRAC (SOlar Neutron TRACking) instrument is designed to operate in the neutron energy range of 20-250 MeV. The measurement principle is based on non-relativistic double scatter of neutrons off ambient protons (n-p scattering) within a block of densely packed scintillating fibers. Using this double-scatter mode it is possible to uniquely determine neutron energy and direction on an event-by-event basis. A fully operational science model of such an instrument has been built using 300 μm (250 μm active) scintillating fibers. The science model consists of a 5×5×5 cm cube of orthogonal plastic scintillating fiber layers. Two orthogonal imaging chains, employing image intensifiers and CCD cameras, allow full 3-dimensional reconstruction of scattered proton particle tracks. We report the results of the science model instrument calibration using 35-65 MeV protons. The proton calibration is the first step toward understanding the instrument response to n-p scatter events. Preliminary results give proton energy resolution of 2% (6%) at 67.5 (35) MeV, and angular resolution of 2° (4.5°) at 67.5 (35) MeV. These measurements are being used to validate detailed instrument simulations that will be used to optimize the instrument design and develop quantitative estimates of science return. Based on the proton calibration, neutron energy and angular resolution for a 10×10×10 cm version of SONTRAC is expected to be ~5% an

Stability analysis of polarized domains

Polarized ferrofluids, lipid monolayers and magnetic bubbles form domains with deformable boundaries. Stability analysis of these domains depends on a family of nontrivial integrals. We present a closed form evaluation of these integrals as a combination of Legendre functions. This result allows exact and explicit formulae for stability thresholds and growth rates of individual modes. We also evaluate asymptotic behavior in several interesting limits.Comment: 12 pages, 3 figures, Late