92 research outputs found
Synthesis and Antimicrobial Activity of New Dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)pentylphosphonium Salts
© 2018, Pleiades Publishing, Ltd. New dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)pentylphosphonium salts bearing various substituents at the phosphorus atom were synthesized. Antimicrobial activity of the salts obtained was estimated. Derivatives with 2-methoxyphenyl substituents at the phosphorus atom are most active against grampositive bacteria. Herewith, dibenzyl-substituted phosphonium derivatives possess the best antifungal activity
Synthesis of 2-(2-hydroxyaryl)alkenylphosphonium salts from phosphine oxides via ring-closing ring-opening approach and their antimicrobial evaluation
© 2016 Elsevier LtdA new two-step synthesis of phosphonium salts from phosphine oxides using Grignard reagents is reported. This approach involves a cyclization of Z-dialkyl-(diaryl)[2-(5-chloro-2-hydroxyphenyl)-2-phenylvinyl]phosphine oxides under the action of sulfinyl chloride with the formation of 2,2-dialkyl(diaryl)-6-chloro-4-phenyl-2H-1,2-benzoxaphosphinin-2-ium chlorides followed by ring opening under the action of organomagnesium compounds. The method was successfully applied to prepare a series of a new phosphonium salts bearing phenolic moiety with a wide range of substituents at phosphorus atom. Synthesized phosphonium salts shows high antibacterial and antifungal in vitro activity and low toxicity towards human red blood cell
Magneto-caloric effect in the pseudo-binary intermetallic YPrFe17 compound
We have synthesized the intermetallic YPrFe17 compound by arc-melting. X-ray
and neutron powder diffraction show that the crystal structure is rhombohedral
with View the MathML source space group (Th2Zn17-type). The investigated
compound exhibits a broad isothermal magnetic entropy change {\Delta}SM(T)
associated with the ferro-to-paramagnetic phase transition (TC \approx 290 K).
The |{\Delta}SM| (\approx 2.3 J kg-1 K-1) and the relative cooling power
(\approx 100 J kg-1) have been calculated for applied magnetic field changes up
to 1.5 T. A single master curve for {\Delta}SM under different values of the
magnetic field change can be obtained by a rescaling of the temperature axis.
The results are compared and discussed in terms of the magneto-caloric effect
in the isostructural R2Fe17 (R = Y, Pr and Nd) binary intermetallic alloys.Comment: Preprint, 5 pages (postprint), 4 figures, regular pape
Overview of the Characteristic Features of the Magnetic Phase Transition with Regards to the Magnetocaloric Effect: the Hidden Relationship Between Hysteresis and Latent Heat
This article was published in the journal, Metallurgical and Materials Transactions E [Springer / © The Minerals, Metals & Materials Society and ASM International]. The final publication is available at Springer via http://dx.doi.org/10.1007/s40553-014-0015-8The magnetocaloric effect has seen a resurgence in interest over the last 20 years as a means towards an alternative energy efficient cooling method. This has resulted in a concerted effort to develop the so-called âgiantâ magnetocaloric materials with large entropy changes that often come at the expense of hysteretic behavior. But do the gains offset the disadvantages? In this paper, we review the relationship between the latent heat of several giant magnetocaloric systems and the associated magnetic field hysteresis. We quantify this relationship by the parameter ÎÎŒ 0 H/ÎS L, which describes the linear relationship between field hysteresis, ÎÎŒ 0 H, and entropy change due to latent heat, ÎS L. The general trends observed in these systems suggest that itinerant magnets appear to consistently show large ÎS L accompanied by small ÎÎŒ 0 H (ÎÎŒ 0 H/ÎS L = 0.02 ± 0.01 T/(J Kâ1 kgâ1)), compared to local moment systems, which show significantly larger ÎÎŒ 0 H as ÎS L increases (ÎÎŒ 0 H/ÎS L = 0.14 ± 0.06 T/(J Kâ1 kgâ1))
Erratum to: Synthesis and Antimicrobial Activity of New Dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)-pentylphosphonium Salts (Russian Journal of General Chemistry, (2018), 88, 9, (1800-1805), 10.1134/S1070363218090062)
© 2019, Pleiades Publishing, Ltd. The row in the table on p. 1802 for compound 8a should be as follows
Erratum to: Synthesis and Antimicrobial Activity of New Dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)-pentylphosphonium Salts (Russian Journal of General Chemistry, (2018), 88, 9, (1800-1805), 10.1134/S1070363218090062)
© 2019, Pleiades Publishing, Ltd. The row in the table on p. 1802 for compound 8a should be as follows
Synthesis and Antimicrobial Activity of New Dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)pentylphosphonium Salts
© 2018, Pleiades Publishing, Ltd. New dialkyl(diaryl)-2-(5-chloro-2-hydroxyphenyl)-2-(phenylethenyl)pentylphosphonium salts bearing various substituents at the phosphorus atom were synthesized. Antimicrobial activity of the salts obtained was estimated. Derivatives with 2-methoxyphenyl substituents at the phosphorus atom are most active against grampositive bacteria. Herewith, dibenzyl-substituted phosphonium derivatives possess the best antifungal activity
Numerical modelling of heat transfer in plasma shaft electric furnace at utilization of anthropogenic waste
Synthesis of 2-(2-hydroxyaryl)alkenylphosphonium salts from phosphine oxides via ring-closing ring-opening approach and their antimicrobial evaluation
© 2016 Elsevier LtdA new two-step synthesis of phosphonium salts from phosphine oxides using Grignard reagents is reported. This approach involves a cyclization of Z-dialkyl-(diaryl)[2-(5-chloro-2-hydroxyphenyl)-2-phenylvinyl]phosphine oxides under the action of sulfinyl chloride with the formation of 2,2-dialkyl(diaryl)-6-chloro-4-phenyl-2H-1,2-benzoxaphosphinin-2-ium chlorides followed by ring opening under the action of organomagnesium compounds. The method was successfully applied to prepare a series of a new phosphonium salts bearing phenolic moiety with a wide range of substituents at phosphorus atom. Synthesized phosphonium salts shows high antibacterial and antifungal in vitro activity and low toxicity towards human red blood cell
Synthesis of 2-(2-hydroxyaryl)alkenylphosphonium salts from phosphine oxides via ring-closing ring-opening approach and their antimicrobial evaluation
© 2016 Elsevier LtdA new two-step synthesis of phosphonium salts from phosphine oxides using Grignard reagents is reported. This approach involves a cyclization of Z-dialkyl-(diaryl)[2-(5-chloro-2-hydroxyphenyl)-2-phenylvinyl]phosphine oxides under the action of sulfinyl chloride with the formation of 2,2-dialkyl(diaryl)-6-chloro-4-phenyl-2H-1,2-benzoxaphosphinin-2-ium chlorides followed by ring opening under the action of organomagnesium compounds. The method was successfully applied to prepare a series of a new phosphonium salts bearing phenolic moiety with a wide range of substituents at phosphorus atom. Synthesized phosphonium salts shows high antibacterial and antifungal in vitro activity and low toxicity towards human red blood cell
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