Role of tephra in dating Polynesian settlement and impact, New Zealand

Tephrochronology in its original sense is the use of tephra layers as time-stratigraphic marker beds to establish numerical or relative ages (Lowe and Hunt, 2001). Tephra layers have been described and studied in New Zealand for more than 160 years (the German naturalist and surgeon Ernst Dieffenbach described ‘recognizable’ tephra sections in his 1843 book Travels in New Zealand), and the first isopach map, showing fallout from the deadly plinian basaltic eruption of Mt Tarawera on 10 June 1886, was published in 1888 (Lowe, 1990; Lowe et al., 2002). More recently, a wide range of tephra-related paleoenvironmental research has been undertaken (e.g., Lowe and Newnham, 1999; Newnham and Lowe, 1999; Newnham et al., 1999, 2004; Shane, 2000), including new advances in the role of tephra in linking and dating sites containing evidence for abrupt climatic change (e.g., Newnham and Lowe, 2000; Newnham et al., 2003). Here we focus on the use of tephrochronology in dating the arrival and impacts of the first humans in New Zealand, a difficult problem for which this technique has proven to be of critical importance

Some comments on embedding inflation in the AdS/CFT correspondence

The anti-de Sitter space/conformal field theory correspondence (AdS/CFT) can potentially provide a complete formulation of string theory on a landscape of stable and metastable vacua that naturally give rise to eternal inflation. As a model for this process, we consider bubble solutions with de Sitter interiors, obtained by patching together dS and Schwarzschild-AdS solutions along a bubble wall. For an interesting subclass of these solutions the bubble wall reaches spacelike infinity in the black hole interior. Including the effects of perturbations leads to a null singularity emanating from this point. Such solutions are interpreted as states in a single CFT, and are shown to be compatible with holographic entropy bounds. The construction suggests de Sitter entropy be interpreted as the total number of degrees of freedom in effective field theory, with a novel adaptive stepsize cutoff.Comment: 15 pages, 4 figures, revtex

Palynology, vegetation and climate of the Waikato lowlands, North Island, New Zealand, since c. 18,000 years ago

The vegetational and climatic history of the Waikato lowlands during the last c. 18,000 years is inferred from the palynology of sediment cores from Lakes Rotomanuka, Rotokauri, and Okoroire. Intra- and inter-lake correlations were aided by multiple tephra layers interbedded with the lake sediments. The detailed chronological resolution given by these tephra sequences shows that late glacial-post glacial vegetational and climatic changes were nearly simultaneous throughout the Waikato lowlands

Ages of the Pliocene-Pleistocene Alexandra and Ngatutura Volcanics, western North Island, New Zealand, and some geological implications

The Alexandra and Ngatutura Volcanics are the two southernmost of the Pliocene-Quaternary volcanic fields of western and northern North Island, New Zealand, northwest of Taupo Volcanic Zone TVZ. The Ngatutura Basalts are an alkalic basaltic field comprising monogenetic volcanoes. The Alexandra Volcanics consist of three basaltic magma series: an alkalic (Okete Volcanics), calcalkalic (Karioi, Pirongia, Kakepuku, and Te Kawa Volcanics), and a minor potassic series. Twenty new K-Arages are presented for the Alexandra Volcanics and 9 new ages for the Ngatutura Basalts. Ages of the Alexandra Volcanics range from 2.74 to 1 .60 Ma, and the ages of all three magma series overlap. Ages of the Ngatutura Basalts range from 1 .83 to 1.54 Ma. Each basaltic field has a restricted time range and there is a progressive younging in age of the basaltic fields of western North Island from the Alexandra Volcanics in the south, to Ngatutura, to South Auckland, and then to the Auckland field in the north. Neither of the Alexandra nor Ngatutura Volcanics shows any younging direction of their volcanic centres or any age pattern within their fields, and there is no systematic variation in age with rock composition. Any correlation of age with degree of erosion of volcanic cones is invalid for these basaltic fields; instead, the degree of erosion may be controlled by the lithology of the cones and possibly by the extent of preservation offered by the thick cover deposits of the Kauroa, Hamilton, and younger tephra beds. Stratigraphic relations have enabled the earliest member of the Kauroa Ash Formation to be dated at 2.3 Ma. This formation represents a series of widespread rhyolitic plinian and ignimbrite eruptions probably derived from TVZ and initiated during the Late Pliocene

Ages of 24 widespread tephras erupted since 30,000 years ago in New Zealand, with re-evaluation of the timing and palaeoclimatic implications of the Lateglacial cool episode recorded at Kaipo bog

Tephras are important for the NZ-INTIMATE project because they link all three records comprising the composite inter-regional stratotype developed for the New Zealand climate event stratigraphy (NZ-CES). Here we firstly report new calendar ages for 24 widespread marker tephras erupted since 30,000 calendar (cal.) years ago in New Zealand to help facilitate their use as chronostratigraphic dating tools for the NZ-CES and for other palaeoenvironmental and geological applications. The selected tephras comprise 12 rhyolitic tephras from Taupo, nine rhyolitic tephras from Okataina, one peralkaline rhyolitic tephra from Tuhua, and one andesitic tephra each from Tongariro and Egmont/Taranaki volcanic centres. Age models for the tephras were obtained using three methods: (i) 14C-based wiggle-match dating of wood from trees killed by volcanic eruptions (these dates published previously); (ii) flexible depositional modelling of a high-resolution 14C-dated age-depth sequence at Kaipo bog using two Bayesian-based modelling programs, Bacon and OxCal's P_Sequence function, and the IntCal09 data set (with SH offset correction -44 ± 17 yr); and (iii) calibration of 14C ages using OxCal's Tau_Boundary function and the SHCal04 and IntCal09 data sets. Our preferred dates or calibrated ages for the 24 tephras are as follows (youngest to oldest, all mid-point or mean ages of 95% probability ranges): Kaharoa AD 1314 ± 12; Taupo (Unit Y) AD 232 ± 10; Mapara (Unit X) 2059 ± 118 cal. yr BP; Whakaipo (Unit V) 2800 ± 60 cal. yr BP; Waimihia (Unit S) 3401 ± 108 cal. yr BP; Stent (Unit Q) 4322 ± 112 cal. yr BP; Unit K 5111 ± 210 cal. yr BP; Whakatane 5526 ± 145 cal. yr BP; Tuhua 6577 ± 547 cal. yr BP; Mamaku 7940 ± 257 cal. yr BP; Rotoma 9423 ± 120 cal. yr BP; Opepe (Unit E) 9991 ± 160 cal. yr BP; Poronui (Unit C) 11,170 ± 115 cal. yr BP; Karapiti (Unit B) 11,460 ± 172 cal. yr BP; Okupata 11,767 ± 192 cal. yr BP; Konini (bed b) 11,880 ± 183 cal. yr BP; Waiohau 14,009 ± 155 cal. yr BP; Rotorua 15,635 ± 412 cal. yr BP; Rerewhakaaitu 17,496 ± 462 cal. yr BP; Okareka 21,858 ± 290 cal. yr BP; Te Rere 25,171 ± 964 cal. yr BP; Kawakawa/Oruanui 25,358 ± 162 cal. yr BP; Poihipi 28,446 ± 670 cal. yr BP; and Okaia 28,621 ± 1428 cal. yr BP. Secondly, we have re-dated the start and end of the Lateglacial cool episode (climate event NZce-3 in the NZ-CES), previously referred to as the Lateglacial climate reversal, as defined at Kaipo bog in eastern North Island, New Zealand, using both Bacon and OxCal P_Sequence modelling with the IntCal09 data set. The ca 1200-yr-long cool episode, indicated by a lithostratigraphic change in the Kaipo peat sequence to grey mud with lowered carbon content, and a high-resolution pollen-derived cooling signal, began 13,739 ± 125 cal. yr BP and ended 12,550 ± 140 cal. yr BP (mid-point ages of the 95% highest posterior density regions, Bacon modelling). The OxCal modelling, generating almost identical ages, confirmed these ages. The Lateglacial cool episode (ca 13.8-12.6 cal. ka BP) thus overlaps a large part of the entire Antarctic Cold Reversal chronozone (ca 14.1-12.4 cal. ka BP or ca 14.6-12.8 cal. ka BP), and an early part of the Greenland Stadial-1 (Younger Dryas) chronozone (ca 12.9-11.7 cal. ka BP). The timing of the Lateglacial cool episode at Kaipo is broadly consistent with the latitudinal patterns in the Antarctic Cold Reversal signal suggested for the New Zealand archipelago from marine and terrestrial records, and with records from southern South America

A ship-based methodology for high precision atmospheric oxygen measurements and its application in the Southern Ocean region

A method for achieving continuous high precision measurements of atmospheric O-2 is presented based on a commercially available fuel-cell instrument, (Sable Systems, Oxzilla FC-II) with a precision of 7 per meg (approximately equivalent to 1.2 ppm) for a 6-min measurement. The Oxzilla was deployed on two voyages in the Western Pacific sector of the Southern Ocean, in February 2003 and in April 2004, making these the second set of continuous O-2 measurements ever made from a ship. The results show significant temporal variation in O-2, in the order of +/- 10 per meg over 6-hourly time intervals, and substantial spatial variation. Data from both voyages show an O-2 maximum centred on 50 degrees S, which is most likely to be the result of biologically driven O-2 outgassing in the region of subtropical convergence around New Zealand, and a decreasing O-2 trend towards Antarctica. O-2 from the ship-based measurements is elevated compared with measurements from the Scripps Institution of Oceanography flask-sampling network, and the O-2 maximum is also not captured in the network observations. This preliminary study shows that ship-based continuous measurements are a valuable addition to current fixed site sampling programmes for the understanding of ocean-atmosphere O-2 exchange processes. [References: 39

Advances in Quaternary tephrostratigraphy and tephrochronology in New Zealand

This paper summarises recent studies on Quaternary tephra deposits in New Zealand, and refers to a range of tephrochronological applications including sequence stratigraphy, palaeoclimatic reconstruction, and archaeology. Topics touched upon include tephrostratigraphy, geochronology, geochemical correlation techniques, volcanology, and volcanic hazards and impacts. Some key tephra marker beds, ranging in age from 0.65 ha to 1.63 Ma, are identified. Recently-acquired tephra-bearing cores from both terrestrial and deep-sea environments, extending through or beyond the Quaternary, provide great potential for detailed, fine-resolution volcanological and palaeoenvironmental studies. The tephra-based research in New Zealand demonstrates the importance of tephra deposits as stratigraphic markers, dating tools, and recorders of volcanic eruption history. An extensive reference list is provided

Analysis and clinical findings of cases positive for the novel synthetic cannabinoid receptor agonist MDMB-CHMICA

Context: MDMB-CHMICA is a synthetic cannabinoid receptor agonist which has caused concern due to its presence in cases of adverse reaction and death. Method: 43 cases of suspected synthetic cannabinoid ingestion were identified from patients presenting at an Emergency Department and from post-mortem casework. These were subjected to liquid-liquid extraction using tertiary-butyl methyl ether and quantitatively analysed by Electospray Ionisation Liquid Chromatography – tandem Mass Spectrometry. For positive samples, case and clinical details were sought and interrogated. Results: 11 samples were found positive for MDMB-CHMICA. Concentrations found ranged from <1 – 22 ng/mL (mean: 6 ng/mL, median: 3 ng/mL). The age range was 15 – 44 years (mean: 26 years, median: 21 years), with the majority (82%) of positive results found in males. Clinical presentations included hypothermia, hypoglycaemia, syncope, recurrent vomiting, altered mental state and serotonin toxicity, with corresponding concentrations of MDMB-CHMICA as low as <1 ng/mL. Duration of hospitalisation ranged from 3 – 24 hours (mean: 12 hours, median: 8 hours). Discussion: The concentration range presented in this case series is indicative of MDMB-CHMICA having a high potency, as is known to be the case for other synthetic cannabinoid receptor agonists. The age range and gender representation were consistent with that reported for users of other drugs of this type. The clinical presentations observed were typical of synthetic cannabinoid receptor agonists and show the difficulties in identifying reactions potentially associated with drugs of this type. Conclusion: The range of MDMB-CHMICA concentrations in Emergency Department presentations (n=9) and post-mortem cases (n=2) was reported. No correlation between the concentration of this drug and clinical presentation or cause of death was reported in this sample. However, the potential for harm associated with low concentrations of MDMB-CHMICA and the symptoms of toxicity being non-specific was highlighted

The roles of neutrophils in non-tuberculous mycobacterial pulmonary disease

Non-tuberculous Mycobacterial Pulmonary Disease (NTM-PD) is an increasingly recognised global health issue. Studies have suggested that neutrophils may play an important role in controlling NTM infection and contribute to protective immune responses within the early phase of infection. However, these cells are also adversely associated with disease progression and exacerbation and can contribute to pathology, for example in the development of bronchiectasis. In this review, we discuss the key findings and latest evidence regarding the diverse functions of neutrophils in NTM infection. First, we focus on studies that implicate neutrophils in the early response to NTM infection and the evidence reporting neutrophils' capability to kill NTM. Next, we present an overview of the positive and negative effects that characterise the bidirectional relationship between neutrophils and adaptive immunity. We consider the pathological role of neutrophils in driving the clinical phenotype of NTM-PD including bronchiectasis. Finally, we highlight the current promising treatments in development targeting neutrophils in airways diseases. Clearly, more insights on the roles of neutrophils in NTM-PD are needed in order to inform both preventative strategies and host-directed therapy for these important infections