Feasibility Analysis of Estrification Systems with Entrainers

(Ethyl Acetate) and IPA (Isopropyl Acetate) production systems are studied in terms of the feasibility analysis. It is not feasible to retrieve pure products by a simple reactive distillation for IPA production system because CCR (Critical Composition Region) covers the entire desired binary edge for IPA system. On the other hand, even though CCR does not cover the entire desired binary edge of the EA system completely, internal reflux ratio (IRR) analysis does not allow the production of the pure product via reactive distillation for EA production system. To overcome the restraints, external entrainers are utilized to take advantage of liquid-liquid split of the lowest boiling azeotrope between the entrainer and water, which is one of the desired products in esterification production systems. Dichloromethane and trichloromethane are the entrainers that are very toxic, yet still conventionally used for production of those esters mentioned above. In this paper, n-hexane and n-pentane are introduced as alternative entrainers because these are more environmentally benign chemicals and less toxic compared to dichloromethane and trichloromethane (chloroform)

Side-View Operando Optical Microscopy Analysis of a Graphite Anode to Study Its Kinetic Hysteresis

Operando analyses have provided several breakthroughs in the construction of high-performance materials and devices, including energy storage systems. However, despite the advances in electrode engineering, the formidable issues of lithium intercalation and deintercalation kinetics cannot be investigated by using planar observations. This study concerns side-view operando observation by optical microscopy of a graphite anode based on its color changes during electrochemical lithiation. Since the graphite color varies according to the optical energy gap during lithiation and delithiation, this technique can be used to study the corresponding charge-discharge kinetics. In addition, the cell configuration uses liquid electrolytes similar to commercial cells, allowing practical application. Furthermore, this side-view observation has shown that microscale spatial variations in rate and composition control the insertion and deinsertion, revealing the kinetics throughout the whole electrode. The results of this study could enhance the fundamental understanding of the kinetics of battery materials

Abstract Painting and the Aesthetics of Moderation

The journey of this research began with exploring the notion of invisible space which cannot be perceived by the human eye, and the process of image visualisation expressed through my abstract paintings, which is supported by my theoretical research. ‘Invisible Space’, the title of one of my recent paintings, evokes the notion of a very small space such as a cell or nerve tissues which form part of the human body and have the potential to simultaneously symbolise a cosmological space. In my practice, I adopt painting as a pertinent method to realise my subjects and motifs. I consider how my painting is situated in contemporary art theory and practice by exploring artists and writers relevant to my underlying concept. I explore how my subject is presented in painting and drawing, and how my research can be developed logically and systematically in response to my practice. In this report, I analyse the three key elements: 1) abstraction that explores macro & micro space; 2) colour experiments and 3) cultural traditions and gesture through Korean Monochrome painting

Early-type Host Galaxies of Type Ia Supernovae. I. Evidence for Downsizing

Type Ia supernova (SN Ia) cosmology provides the most direct evidence for the presence of dark energy. This result is based on the assumption that the look-back time evolution of SN Ia luminosity, after light-curve corrections, would be negligible. Recent studies show, however, that the Hubble residual (HR) of SN Ia is correlated with the mass and morphology of host galaxies, implying the possible dependence of SN Ia luminosity on host galaxy properties. In order to investigate this more directly, we have initiated spectroscopic survey for the early-type host galaxies, for which population age and metallicity can be more reliably determined from the absorption lines. As the first paper of the series, here we present the results from high signal-to-noise ratio (>100 per pixel) spectra for 27 nearby host galaxies in the southern hemisphere. For the first time in host galaxy studies, we find a significant (~3.9sigma) correlation between host galaxy mass (velocity dispersion) and population age, which is consistent with the "downsizing" trend among non-host early-type galaxies. This result is rather insensitive to the choice of population synthesis models. Since we find no correlation with metallicity, our result suggests that stellar population age is mainly responsible for the relation between host mass and HR. If confirmed, this would imply that the luminosity evolution plays a major role in the systematic uncertainties of SN Ia cosmology.Comment: Accepted for publication in ApJ

Mechanical rolling formation of interpenetrated lithium metal/lithium tin alloy foil for ultrahigh-rate battery anode

To achieve good rate capability of lithium metal anodes for high-energy-density batteries, one fundamental challenge is the slow lithium diffusion at the interface. Here we report an interpenetrated, three-dimensional lithium metal/lithium tin alloy nanocomposite foil realized by a simple calendering and folding process of lithium and tin foils, and spontaneous alloying reactions. The strong affinity between the metallic lithium and lithium tin alloy as mixed electronic and ionic conducting networks, and their abundant interfaces enable ultrafast charger diffusion across the entire electrode. We demonstrate that a lithium/lithium tin alloy foil electrode sustains stable lithium stripping/plating under 30mAcm(-2) and 5mAhcm(-2) with a very low overpotential of 20mV for 200 cycles in a commercial carbonate electrolyte. Cycled under 6C (6.6mAcm(-2)), a 1.0mAhcm(-2) LiNi0.6Co0.2Mn0.2O2 electrode maintains a substantial 74% of its capacity by pairing with such anode